Abstract
Oxide catalysts Ni-Co-Al-Mg-O, Ni-Al-Mg-O, Co-Al-O, and Co-Mg-O have been prepared by combustion synthesis and characterized by XRD, Fourier transform IR spectroscopy (FTIR), SEM/EDS, TEM, and nitrogen porosimetry. Their catalytic activity in the process of dry (carbon dioxide) reforming of methane was studied by gas chromatography at different temperatures. Feed gas contained equal amounts of methane, carbon dioxide, and nitrogen and the effect of catalyst composition and temperature on the catalytic activity, selectivity, and product yields were recorded.
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Yang, L., Tao, K., Yoneyama, Y., Tan, Y., and Tsubaki, N., An introduction of CO2 conversion by dry reforming with methane and new route of low-temperature methanol synthesis, Acc. Chem. Res., 2013, vol. 46, no. 8, pp. 1838–1847.
Ruckenstein, E. and Hu, Y.H., Methane partial oxidation over NiO/MgO solid solution catalysts, Appl. Catal. A, 1999, vol. 183, no. 1, pp. 85–92.
Roh, H.S., Jun, K.W., Dong, W.S., Chang, J.S., Park, S.E., and Joe, Y., Highly active and stable Ni/Ce-ZrO2 catalyst for H2 production from methane, J. Mol. Catal., Ser. A, 2002, vol. 181, nos. 1–2, pp. 137–142.
Xu, S. and Wang, X., Highly active and coking resistant Ni/CeO2-ZrO2 catalyst for partial oxidation of methane, Fuel, 2005, vol. 84, no. 5, pp. 563–567.
Pengpanich, S., Meeyoo, V., and Riksomboon, T., Methane partial oxidation over Ni/CeO2-ZrO2 mixed oxide solid solution catalysts, Catal. Today, 2004, vols. 93–95, pp. 95–105.
Larimi, S. and Alavi, S.M., Partial oxidation of methane over Ni/CeZrO2 mixed oxide solid solution catalysts, Int. J. Chem. Eng. Appl., 2012, vol. 3, no. 1, pp. 6–9.
Soloviev, S.O., Kapran, A.Yu., Orlyk, S.N., and Gubareni, E.V., Carbon dioxide reforming of methane on monolithic Ni/Al2O3-based catalysts, J. Natur. Gas Chem., 2011, vol. 20, no. 2, pp. 184–190.
Fidalgo, B., Arenillas, A., and Menindez, J.A., Synergetic effect of a mixture of activated carbon + Ni/Al2O3 used as catalysts for the CO2 reforming of CH4, Appl. Catal., Ser. A, 2010, vol. 390, nos. 1–2, pp. 78–83.
Moniri, A., Alavi, S.M., and Rezaei, M., Syngas production by combined carbon dioxide reforming and partial oxidation of methane over Ni/α-Al2O3 catalysts, J. Natur. Gas Chem., 2010, vol. 19, no. 6, pp. 638–641.
Castro Luna, A.E. and Iriarte, M.E., Carbon dioxide reforming of methane over a metal modified Ni-Al2O3 catalyst, Appl. Catal., Ser. A, 2008, vol. 343, nos. 1–2, pp. 10–15.
Meshkani, F. and Rezaei, M., Nanocrystalline MgO supported nickel-based bimetallic catalysts for carbon dioxide reforming of methane, Int. J. Hydrogen Energ., 2010, vol. 35, no. 19, pp. 10295–10301.
Wang, N., Chu, W., Zhang, T., and Zhao, X.S., Manganese promoting effects on the Co-Ce-Zr-Ox nano catalysts for methane dry reforming with carbon dioxide to hydrogen and carbon monoxide, Chem. Eng. J., 2011, vol. 170, nos. 2–3, pp. 457–463.
Özkara-Aydinoğlu, S. and Aksoylu, A.E., Carbon dioxide reforming of methane over Co-X/ZrO2 catalysts (X = La, Ce, Mn, Mg, K), Catal. Commun., 2010, vol. 11, no. 15, pp. 1165–1170.
Ruckenstein, E. and Wang, H.Y., Carbon dioxide reforming of methane to synthesis gas over supported cobalt catalysts, Appl. Catal., Ser. A, 2000, vol. 204, no. 2, pp. 257–263.
Bouarab, R., Akdim, O., Auroux, A., Cherifi, O., and Mirodatos, C., Effect of MgO additive on catalytic properties of Co/SiO2 in the dry reforming of methane, Appl. Catal., Ser. A, 2004, vol. 264, no. 2, pp. 161–168.
Fan, M.S., Abdullah, A.Z., and Bhatia, S., Hydrogen production from carbon dioxide reforming of methane over Ni-Co/MgOeZrO2 catalyst: Process optimization, Int. J. Hydrogen Energ., 2011, vol. 36, no. 8, pp. 4875–4886.
Choudhary, V.R., Mondal, K.C., and Mamman, A.S., High-temperature stable and highly active/selective supported NiCoMgCeOx catalyst suitable for autothermal reforming of methane to syngas, J. Catal., 2005, vol. 233, no. 1, pp. 36–40.
Merzhanov, A.G., Worldwide evolution and present status of SHS as a branch of modern R & D, Int. J. Self-Prop. High-Temp. Synth., 1997, vol. 6, no. 2, pp. 119–163.
Xanthopoulou, G., Catalytic properties of SHS products: Review, Adv. Sci. Technol., 2010, vol. 63, pp. 287–296.
Xanthopoulou, G. and Vekinis, G., Catalytic oxidation of CO over a Cu-Cr-oxide catalyst made by self-propagating high-temperature synthesis, Appl. Catal., Ser. B, 1998, vol. 19, no. 1, pp. 37–44.
Xanthopoulou, G., Oxidative dehydrodimerization of methane using manganese based catalysts made by self-propagating high-temperature synthesis, Chem. Eng. Technol., 2001, vol. 24, no. 10, pp. 1025–1034.
Xanthopoulou, G., Oxide catalysts for pyrolysis of diesel fuel made by self-propagating high-temperature synthesis. I: Cobalt-modified Mg-Al spinel catalysts, Appl. Catal., Ser. A, 1999, vol. 182, no. 2, pp. 285–295.
Xanthopoulou, G., Oxide catalysts for pyrolysis of diesel fuel made by self-propagating high-temperature synthesis. II: Fe-Cr oxide catalysts based on chromite concentrates, 1999, vol. 187, no. 1, pp. 79–88.
Xanthopoulou, G., Oxidative dehydrodimerization of methane using lead and samarium based catalysts made by self-propagating high-temperature synthesis, Appl. Catal., Ser. A, 1999, vol. 185, pp. L185–L192.
Xanthopoulou, G.G. and Vekinis, G.A., Catalytic pyrolysis of naphtha over SHS-produced catalysts, Eurasian Chem.-Technol. J., 2010, vol. 12, no. 1, pp.17–21.
Xanthopoulou, G. and Vekinis, G., Deep oxidation of methane using catalysts and carriers produced by self-propagating high temperature synthesis, App. Catal., Ser. A, 2000, vol. 199, no. 2, pp. 227–238.
Xanthopoulou, G. and Vekinis, G., An overview of some environmental applications of self-propagating high-temperature synthesis, Adv. Environ. Res., 2001, vol. 5, no. 2, pp. 117–128.
Xanthopoulou, G., Some advanced applications of SHS: An overview, Int. J. Self-Prop. High-Temp. Synth., 2011, vol. 20, no. 4, pp. 269–272.
Xanthopoulou, G., Self-propagating high-temperature synthesis as a method of catalysts production, Sci. Centr. Asia, 2010, no. 4, pp. 35–55.
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Xanthopoulou, G., Varitis, S., Karanasios, K. et al. SHS-produced Ni-Co-Al-Mg-O catalysts for dry reforming of methane. Int. J Self-Propag. High-Temp. Synth. 23, 92–100 (2014). https://doi.org/10.3103/S1061386214020125
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DOI: https://doi.org/10.3103/S1061386214020125