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The influence of a carbon support on the catalytic properties of Pd/Sibunit and Pd-Ga/Sibunit catalysts for liquid-phase acetylene hydrogenation

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Abstract

The Pd/Sibunit and Pd-Ga/Sibunit catalysts, which were supported on Sibunit with different textural characteristics, for liquid-phase acetylene hydrogenation were investigated. It was shown that the use of the support with a large surface area leads to an increase in catalytic activity and selectivity due to the increased dispersion of the active component. The promoting effect of gallium correlates with the probability of contact between the supported Pd and Ga components.

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References

  1. Eliseev, O.L., Ross. Khim. Zh., 2008, vol. 52, no. 6, p. 53.

    CAS  Google Scholar 

  2. Zhu, Y., Wang, S., Ge, X., et al., Fuel Proc. Tech., 2010, vol. 91, no. 4, p. 424.

    Article  CAS  Google Scholar 

  3. Zonetti, P.C., Gaspar, A.B., Mendes, F.M.T., et al., Fuel Proc. Tech., 2010, vol. 91, no. 5, p. 469.

    Article  CAS  Google Scholar 

  4. http://www.synfuels.com.

  5. Johnson, M.M., Peterson, E.R., and Gattis, S.C., The ECLAIRS Process for Converting Natural Gas to Hydrocarbon Liquids, Dallas, 2004.

    Google Scholar 

  6. Temkin, O.N., Atsetilen-khimiya, mekhanizmy reaktsii, tekhnologiya (Acetylene-Chemistry, Reaction Mechanisms, and Technology), Moscow: Khimiya, 1991.

    Google Scholar 

  7. Johnson, M.M., Peterson, E.R., and Gattis, S.C., US Patent 0021638A1, 2007.

  8. Johnson, M.M., Peterson, E.R., and Gattis, S.C., US Patent 7408091B2, 2008.

  9. Johnson, M.M., Peterson, E.R., and Gattis, S.C., US Patent 7692051B2, 2010.

  10. Johnson, M.M., Peterson, E.R., and Gattis, S.C., US Patent 0217781A1, 2011.

  11. Busygin, V.M., Lamberov, A.A., Egorova, S.R., et al., Kat. Pprom-st., 2003, no. 3, p. 34.

    Google Scholar 

  12. Khan, N., Shaikhutdinov, S., and Freund, H., Catal. Lett., 2006, vol. 108, no. 3, p. 159.

    Article  CAS  Google Scholar 

  13. Lamberov, A.A., Egorova, S.R., Il’yasov, I.R., et al., Kinet. Katal., 2007, vol. 48, no. 1, p. 143.

    Article  Google Scholar 

  14. Sarkany, A., Horvath, A., and Beck, A., App. Catal. A: Gen., 2002, vol. 229, nos. 1–2, p. 117.

    Article  CAS  Google Scholar 

  15. Chinayon, S., Mekasuwandumrong, O., Praserthdam, P., et al., Catal. Comm., 2008, vol. 9, no. 14, p. 2297.

    Article  CAS  Google Scholar 

  16. Mashkovskii, I.S., Tkachenko, O.P., Baeva, G.N., et al., Kinet. Katal., 2009, vol. 50, no. 5, p. 798.

    Article  Google Scholar 

  17. Borodzinski, A. and Bond, G.C., Catal. Rev., 2008, vol. 50, no. 3, p. 379.

    Article  CAS  Google Scholar 

  18. Bonivardi, A.L., Chiavassa, D.L., Querini, C.A., et al., Stud. Surf. Sci. Catal., 2000, vol. 130, p. 3747.

    Article  Google Scholar 

  19. Rodriguez, L., Romero, D., Rodriguez, D., et al., Appl. Catal. A: Gen., 2010, vol. 373, nos. 1–2, p. 66.

    Article  CAS  Google Scholar 

  20. Shao, L., Zhang, W., Armbruster, M., et al., Angew. Chem., Int. Ed. Engl., 2011, vol. 50, no. 43, p. 10231.

    Article  CAS  Google Scholar 

  21. Penner, S., Lorenz, H., Jochum, W., et al., App. Catal. A: Gen., 2009, vol. 358, no. 2, p. 193.

    Article  CAS  Google Scholar 

  22. Iwasa, N. and Takezawa, N., Top. Catal., 2003, vol. 22, no. 3, p. 215.

    Article  CAS  Google Scholar 

  23. Chiavassa, D.L., Barrandeguy, J., Bonivardi, A.L., et al., Catal. Today, 2008, vol. 133–135, p. 780.

    Article  Google Scholar 

  24. Osswald, J., Kovnir, K., Armbruster, M., et al., J. Catal., 2008, vol. 258, no. 1, p. 219.

    Article  CAS  Google Scholar 

  25. Kovnir, K., Osswald, J., Armbruster, M., et al., J. Catal., 2009, vol. 264, no. 2, p. 93.

    Article  CAS  Google Scholar 

  26. Ota, A., Armbruster, M., Behrens, M., et al., J. Phys. Chem., 2010, vol. 115, no. 4, p. 1368.

    Google Scholar 

  27. Li, L., Zhang, B., Kunkes, E., et al., Chem. Cat. Chem., 2012, vol. 4, no. 11, p. 1764.

    CAS  Google Scholar 

  28. Romanenko, A.V., Doctoral (Chem.) Dissertation, Novosibirsk: Inst. Catal., Sib. Branch, Russ. Acad. Sci., 2001.

    Google Scholar 

  29. Shitova, N.B., Shlyapin, D.A., Afonasenko, T.N., et al., Kinet. Katal., 2011, vol. 52, no. 2, p. 259.

    Article  Google Scholar 

  30. Surovikin, V.F., Surovikin, Yu.V., and Tsekhanovich, M.S., Ross. Khim. Zh., 2007, vol. 51, no. 4, p. 111.

    CAS  Google Scholar 

  31. Sadezky, A., Muckenhuber, H., Grothe, H., et al., Carbon, 2005, vol. 43, no. 8, p. 1731.

    Article  CAS  Google Scholar 

  32. Cuesta, A., Dhamelincourt, P., Laureyns, J., et al., Carbon, 1994, vol. 32, no. 8, p. 1523.

    Article  CAS  Google Scholar 

  33. Simonov, P.A., Troitskii, S.Yu., and Likholobov, V.A., Kinet. Katal., 2000, vol. 41, no. 2, p. 281.

    Article  Google Scholar 

  34. Al’-Vadkhav, Kh.A., Vestn. MITKhT, 2012, vol. 7, no. 1, p. 3.

    Google Scholar 

  35. Chesnokov, V.V., Prosvirin, I.P., Zaitseva, N.A., et al., Kinet. Catal., vol. 43, no. 6, p. 838.

  36. Smirnova, N.S., Mironenko, O.O., Anoshkina, E.A., et al., Abstracts of Papers, 5th Int. Symp. on Carbon for Catal. Carbocat-V, Bressanone, 2012, p. 128.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    N. S. Smirnova, D. A. Shlyapin, Yu. V. Surovikin, E. A. Anoshkina, V. L. Temerev, N. B. Shitova & P. G. Tsyrul’nikov

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  1. N. S. Smirnova
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  2. D. A. Shlyapin
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  3. Yu. V. Surovikin
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  4. E. A. Anoshkina
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  5. V. L. Temerev
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  6. N. B. Shitova
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  7. P. G. Tsyrul’nikov
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Corresponding author

Correspondence to N. S. Smirnova.

Additional information

Original Russian Text © N.S. Smirnova, D.A. Shlyapin, Yu.V. Surovikin, E.A. Anoshkina, V.L. Temerev, N.B. Shitova, P.G. Tsyrul’nikov, 2015, published in Khimiya Tverdogo Topliva, 2015, No. 1, pp. 17–22.

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Smirnova, N.S., Shlyapin, D.A., Surovikin, Y.V. et al. The influence of a carbon support on the catalytic properties of Pd/Sibunit and Pd-Ga/Sibunit catalysts for liquid-phase acetylene hydrogenation. Solid Fuel Chem. 49, 14–19 (2015). https://doi.org/10.3103/S0361521915010103

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  • DOI: https://doi.org/10.3103/S0361521915010103

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