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Local coordination of Co2+ and Ni2+ cations in polyacrylate matrices

  • Proceedings of the 19th National Conference on the Application of Synchrotron Radiation “SR-2012” and National Youth Conference “Application of Synchrotron Radiation”
  • Section of Spectroscopy
  • Published:
Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

Parameters of the local coordination of Co2+ and Ni2+ cations in polymer matrices are determined by XAFS spectroscopy at the K edges of the corresponding elements. Ion-exchange complexes of Ni2+ and polymethacrylate, low-molecular acrylamide complexes [M(CH2=CHC(O)NH2)6](NO3)2 (M = Co or Ni), and products of their thermal polymerization are investigated. The final results are in agreement with the octahedral coordination of M atoms (average distances, 2.10–2.11 (Co-O) and 2.05–2.06 Å (Ni-O).

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References

  1. Ding, Y.S. and Cooper, S.L., in Structure and Properties of Ionomers, Pineri, M. and Eisenberg, A., Eds., Dordrecht: D. Reidel Publ., 1982, pp. 73–86.

  2. Grady, B.P., Polym. Eng. Sci., 2008, vol. 48, p. 1029.

    Article  Google Scholar 

  3. Grady, B.P., Polymer, 2000, vol. 41, pp. 2325–2328.

    Article  Google Scholar 

  4. Allender, C.J., et al., Chem. Commun., 2009, issue 2, pp. 165–167.

    Google Scholar 

  5. Zhao, H., et al., Polymer Sci., 2006, vol. 100, pp. 1294–1298.

    Google Scholar 

  6. O’Day, P.A., Parks, G.A., and Brown, G.E., Jr., Clays Clay Minerals, 1994, vol. 42, no. 3, pp. 337–355.

    Article  Google Scholar 

  7. Ewecharoen, A., Thiravetyan, P., Wendel, E., and Bertagnolli, H., J. Hazard. Mater., 2009, vol. 171, pp. 335–339.

    Article  Google Scholar 

  8. Golub’, A.S., Zubavichus, Ya.V., Slovokhotov, Yu.L., and Novikov, Yu.N., Usp. Khim., 2003, vol. 72, p. 138.

    Google Scholar 

  9. Karpyuk, E.A., Korotkikh, O.I., Gavlina, O.T., and Ivanov, V.A., Russ. J. Phys. Chem., 2011, vol. 85, no. 3, pp. 486.

    Article  Google Scholar 

  10. Pomogailo, S.I., et al., Macromol. Symp., 2002, vol. 186, pp. 161–164.

    Article  Google Scholar 

  11. Pomogailo, A.D., Dzhadimalieva, G.I., and Slovokhotov, Yu.L., Proc. Int. Conf. “Current Status of SR in the World”, Moscow, March 2000, p. 98.

    Google Scholar 

  12. Newville, M., J. Synchrotron. Rad., 2001, vol. 8, pp. 322–324.

    Article  Google Scholar 

  13. Treushnikov, E.N., Kuskov, V.I., Aslanov, L.A., and Soboleva, L.V., Kristallografiya, 1980, vol. 25, pp. 287–293.

    Google Scholar 

  14. Girma, K.B., Lorenz, V., Blaurock, S., and Edelmann, F.T., Z. Anorg. Allg. Chem., 2005, vol. 631, pp. 1843–1848.

    Article  Google Scholar 

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Authors and Affiliations

  1. Moscow State University, Moscow, 119991, Russia

    N. N. Trofimova, O. I. Titova, E. A. Karpyuk, V. A. Ivanov & Yu. L. Slovokhotov

  2. National Research Center Kurchatov Institute, Moscow, 123182, Russia

    Ya. V. Zubavichus

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

    Ya. V. Zubavichus & Yu. L. Slovokhotov

  4. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    A. D. Pomogailo

Authors
  1. N. N. Trofimova
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  2. Ya. V. Zubavichus
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  3. O. I. Titova
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  4. E. A. Karpyuk
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  5. V. A. Ivanov
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  6. A. D. Pomogailo
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  7. Yu. L. Slovokhotov
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Corresponding author

Correspondence to Yu. L. Slovokhotov.

Additional information

Original Russian Text © N.N. Trofimova, Ya.V. Zubavichus, O.I. Titova, E.A. Karpyuk, V.A. Ivanov, A.D. Pomogailo, Yu.L. Slovokhotov, 2013, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2013, Vol. 77, No. 9, pp. 1286–1289.

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Trofimova, N.N., Zubavichus, Y.V., Titova, O.I. et al. Local coordination of Co2+ and Ni2+ cations in polyacrylate matrices. Bull. Russ. Acad. Sci. Phys. 77, 1127–1130 (2013). https://doi.org/10.3103/S1062873813090463

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  • DOI: https://doi.org/10.3103/S1062873813090463

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