Skip to main content
Log in

Hydrogeochemical characteristics and genetic implications of Edipsos thermal springs, north Euboea, Greece

  • Research Article
  • Published:
Central European Journal of Geosciences

Abstract

Edipsos area, situated in northern Euboea, has been well known since ancient times for the existence of thermal springs. In order to assess the hydrogeochemical conditions, thermal and cold water samples were collected and analyzed by ICP method for major and trace elements. The results revealed the direct impact of seawater, a process which is strongly related to the major tectonic structures of the area. Seawater impact was confirmed by the Cl/Br and Na/Cl ionic ratios, as well as from statistical processing and graphical interpretation of the analytical results, which classified the sampled waters into three groups (two for cold waters and one for the thermal ones). Trace element ranges for thermal waters are: As (44–84 ppb), Pb (23–154 ppb), Ag (1–2 ppb), Mn (31–680 ppb), Cu (61–97 ppb), Cs (66–244 ppb), Se (0–76 ppb), Li (732–3269 ppb), Fe (0–1126 ppb), Sr (14000–34100 ppb), B (4300–9600 ppb).

Compared with the chemical composition of other thermal springs from the Hellenic Volcanic Arc, Edipsos thermal waters are enriched in Ca2+, Na+, Cl, SO4 2−, Li, B and K+, reflecting the influence from seawater. Cold waters are free of heavy metals compared with other natural waters and are characterized by good quality based on the major element chemistry. Finally, several geothermometers were applied in order to assess the reservoir temperatures, but none of them appear to be applicable, mainly due to the impact of seawater on the initial hydrogeochemistry of the geothermal fluids.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Fytikas M., Innocenti F., Manetti P., Mazzuoli R., Peccerillo A. and Villari L., Tertiary to Quarternary evolution of volcanism in the Aegean region, Geological Society of London, Special Publications, 1984, 17, 68–699

    Article  Google Scholar 

  2. Pe-Piper G., Piper D.J.W., Spatial and temporal variation in Late Cenozoic Back-arc volcanic rocks, Aegean Sea region., Tectonophysics, 1989, 169, 113–134

    Article  Google Scholar 

  3. Katsikatsos G., Les formations triassiques de l’Eubée centrale, Annales Géologiques des Pays Helléniques, 1970, 22, 62–76

    Google Scholar 

  4. Katsikatsos A.G., La structure tectonique d’Attlque et de l’lle d’Eubée, Proceedings of the 6th Colloquium of the Geology of the Aegean Region, 1977, 1, 211–228

    Google Scholar 

  5. Katsikatsos A.G., Fytikas M., Koukis G., Geological map of Greece, Kymi sheet, 1:50000, IGME, Athens, 1981

    Google Scholar 

  6. Katsikatsos A.G., Mettos A., Vidakis M., Geological map of Greece, Istiea sheet, 1:50000, IGME Athens, 1984

    Google Scholar 

  7. Vardaki C., Kelepertis A., Environmental impact of heavy metals (Fe, Ni, Cr, Co) in soils, waters and plants of Triada Euboea from ultrabasic rocks and nickeliferous mineralisation, Environ. Geochem. Hlth., 1999, 21, 221–226

    Article  Google Scholar 

  8. Danelian T., Robertson A., Neotethyan evolution of eastern Greece (Pagondas Melange, Evia Island) inferred from radiolarian biostratigraphy and the geochemistry of associated extrusive rocks, Geol. Mag, 2001, 138, 345–363

    Article  Google Scholar 

  9. Christodoulou G., Tsaila-Monopolis S., Contribution to the knowledge of the stratigraphy of Triassic in the Eastern Hellenic zone, Bulletin of the Geological Society of Greece, 1972, 9, 109–118

    Google Scholar 

  10. De Bono A., Cirilli S., Vachard D., Vavassis I., Stamplfli G.M., The Liri unit: an external unit at the base of Pelagonia terrane in central Evia Island. Evidence for a Paleotethyan suture in the Hellenides, Symposium DO6, Inter-Relations between Paleotehys and Neotethys in Eurasia, Journal of Conference Abstracts, 1999, 4

  11. Vavasis I., De Bono A., Valloton A., Stampfli G., Gosca M., Amelin Y., Geochronological data from the Pelagonian basement in Evia Island (Greece): Geodynamic implications for the evolution of Paleotethys, Symposium DO6, Inter-Relations between Paleotehys and Neotethys in Eurasia, Journal of Conference abstracts, 1999, 4

  12. Guernet C., Etudes géologiques en Eubée et dans les régions voisines (Grece) 1971, These Doctoral, Faculte de Sciences, Universite de Paris

  13. Katsikatsos G., Migiros M., Mettos A., Geological structure of internal Hellenides (E. Thessaly-SW Macedonia, Euboea-Attica-northern Cyclades Island and Lesvos), Geological and Geophysical Research, Special Issue, IGME, Athens, 1986, 191–212

    Google Scholar 

  14. Scherreiks R., Platform margin and oceanic sedimentation in a divergent and convergent plate setting (Jurassic, Pelagonian Zone, NE Evvoia, Greece), Int. J. Earth Sci., 2000, 89, 90–107

    Article  Google Scholar 

  15. Palyvos N., Bantekas I., Kranis H., Transverse fault zones of subtle geomorphic signature in northern Evia Island (central Greece extensional province): An introductlon to Quaternary Nileas graben, Geomorphology, 2006, 76, 363–374

    Article  Google Scholar 

  16. Tsikouras B., Pe-Piper G., Piper D.J.W., Hatzipanagiotou K., Triassic rift-related komatiite, picrite and basalt, Pelagonian continental margin, Greece, Lithos, 2008, 104, 199–215

    Article  Google Scholar 

  17. Mettos A., Rondogianni T., Ioakim C., Papadakis I. Evolution, géodynamique et reconstruction paleoenvironnmentale des Basins Neogenes-Quaternaires de la Grece centrale, Paleontologia i Evolucio, 1992, 24–25, 393–402

    Google Scholar 

  18. Philip H., Etude néotectonique des rivages égéens en Locride et en Eubée nord orientale, These de 3eme cycle, Acad de Montpellier, Univ. De Languedoc, 1974 [19] Lemeille F., Etudes néotectoniques en Grece central nord-orientale (Eubée centrale, Attique, Béotie, Locride), These de 3eme cycle, XI-Centre d’Orsay, Universite de Paris, 1977 [20] Rondogianni T., Etude néotectonique des rivages occidentaux du canal d’Atalanti (Grece central), These 3eme cycle, Universite Paris XI, 1984

  19. Roberts S., Jackson J., Active normal faulting in central Greece: an overview. In: Roberts A.M., Yielding G., Freeman B. (Eds), The geometry of normal faults, Geological Society, London, Special Publication, 1991, 56, 125–142

    Google Scholar 

  20. Orfanos G., Hydrogeological reconnaissance of the thermometallic springs of Killini, Kaifa, dipsos, Thermopylae, Ypati, I.G.M.E., technical report, 1976 (in Greek)

    Google Scholar 

  21. Kallergis N., Lambrakis G., Contribution to the study of greek thermal springs: hydrogeological and hydrochemical characteristics and origin of thermal waters, Hydrogeol. J., 2005, 13, 506–521

    Article  Google Scholar 

  22. Alcala F., Custodio E., Using the Cl/Br ratio as a tracer to identify the origin of salinity in aquifers in Spain and Portugal, Journal of Hydrology, 2008, 359, 189–207

    Article  Google Scholar 

  23. Hem J., Study and interpretation of the chemical characteristics of natural water, U.S. Geological Survey, Water Supply Paper 2254, 1985

  24. Minissale A., Duchi V., Kolios N., Totaro G., Geochemical characteristics of Greek thermal springs, J. Volcanol. Geoth. Res., 1989, 39, 1–16

    Article  Google Scholar 

  25. Gill R., Chemical fundamentals of Geology, Unwin Hyman, London, 1989

    Google Scholar 

  26. Minissale A., Duchi V., Kolios N., Nocenti M., Verrucchi C., Chemical patterns of thermal aquifers in the volcanic islands of the Aegean arc, Greece, Geothermics, 1997, 26, 501–518

    Article  Google Scholar 

  27. European Water Directive. Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 establishing a framework for community action in the field of water policy, European Union, 2000

  28. Fournier R.O., Application of water geochemistry to geothermal exploration and reservoir engineering. In: Rybach L., Muffer L.J.P. (Eds.), Geothermal Systems: Principles and Case Histories, J.Wiley, New York, 1981, 109–143

    Google Scholar 

  29. Arnorsson S., Gunnlaugsson E., Svavarson H., The chemistry of geothermal waters in Iceland: III. Chemical geothermometry in geothermal investigations, Geochim. Cosmochim. Ac., 1983, 47, 567–577

    Article  Google Scholar 

  30. Fournier R.O., Truesdell A.H., An empirical Na-K-Ca geothermometer for natural waters, Geochim. Cosmochim. Ac., 1973, 37, 515–525

    Article  Google Scholar 

  31. Fouillac C., Michard G., Sodium/lithium ratios in water applied to geothermometry of geothermal reservoirs, Geothermics, 1981, 10, 55–70

    Article  Google Scholar 

  32. Kharaka Y.K., Lico M.S., Law L.M., Chemical geothermometers applied to formation waters, Gulf of Mexico and California basins (sbs), Am. Assoc. Pet. Geol. B., 1982, 66, 588

    Google Scholar 

  33. Giggenbach W.F., Confiantini R., Jangi B.L., Truesdell A.H., Isotopic and chemical composition of Parbati valley geothermal discharges, north-west Himalaya, India, Geothermics, 1983, 12, 199–222

    Article  Google Scholar 

  34. Kharaka Y.K., Mariner R.H., Chemical geothermometers and their application to formation waters from sedimentary basins. In: Naeser N.D., Mc Collon T.H. (Eds.), Thermal History of Sedimentary Basins, Springer-Verlag, New-York, 1989, 99–117

    Google Scholar 

  35. Mutlu H., Gulec N., Hydrogeochemical outline of thermal waters and geothermometry applications in Anatolia (Turkey), J. Volcanol. Geoth. Res., 1998, 85, 495–515

    Article  Google Scholar 

  36. Dotsika E., Leontiadis I., Poutoukis D., Cioni R., Raco B., Fluid geochemistry of the Chios geothermal area, Chios Island, Greece, J. Volcanol. Geoth. Res., 2006, 154, 237–250

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

About this article

Cite this article

Kelepertsis, A., Tziritis, E., Kelepertzis, E. et al. Hydrogeochemical characteristics and genetic implications of Edipsos thermal springs, north Euboea, Greece. Cent. Eur. J. Geosci. 1, 241–250 (2009). https://doi.org/10.2478/v10085-009-0019-2

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.2478/v10085-009-0019-2

Keywords

Navigation