Skip to main content
Log in

REE in fluid inclusions of quartz from gold deposits of north-eastern Russia

  • Research Article
  • Published:
Central European Journal of Geosciences

Abstract

Inductively coupled plasma-mass spectrometry (ICP-MS) has been used to determine rare earth element concentrations in aqueous solutions extracted from fluid inclusions. Quartz has been sampled from ores of three major types of polygenic gold hydrothermal systems of North-Eastern Russia: (1) gold-quartz-sulphide (Au-Q, Nezhdaninsk); (2) gold-antimony (Au-Sb, Sarylakh) and (3) intrusion-related gold-bismuth-siderite-polysulphide (Au-Bi-Sid, Arkachan) large deposits located in terrigenous rocks of the Verkhoyansk fold belt. The total concentration of REE in the fluid inclusions is not high (up to 52 ppm). The contribution of LREE dominates in REE balance (ΣLREE/ΣHREE=7.4–112.1). The chondrite-normalized REE patterns of inclusion fluids for the Au-Q and Au-Bi-Sid deposits are characterized by LREE enrichment with a positive or negative Eu anomaly. REE patterns for the regenerated quartz from Au-Sb deposits are characterized by pronounced differentiation between light and heavy lanthanides in fluid inclusions. Significant total REE concentration decreasing (on 1–2 order) from early to late stages of Nezhdaninsk and Arkachan deposits is revealed. The positive correlations of total REE concentrations with Rb, Cs, Li and B contents in fluid inclusions are shown. The REE distribution in fluid inclusions can be used as indicators of the contribution of magmatic fluid in the hydrothermal system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Norman D.I., Kyle P.R., Baron C., Analysis of trace elements including rare earth elements in fluid inclusion liquids. Econ. Geol., 1989, 84, 162–166

    Article  Google Scholar 

  2. Salvi S., Williams-Jones A., The role of hydrothermal processes in the granite-hosted Zr, Y, REE deposit at Strange Lake, Quebec/Labrador. Evidence from fluid inclusions. Geochim. Cosmochim. Acta, 1990, 54, 2403–2418

    Article  Google Scholar 

  3. Kwak T.A.P., Aveysinghe P.B., Rare earth and uranium minerals present as daughter crystals in fluid inclusions, Mary Kathleen U-REE skarn, Queensland, Australia. Mineral. Mag., 1987, 51, 556–670

    Article  Google Scholar 

  4. Ghazi A.M., Vanko D.A., Roedder E., Seeley R.C., Determination of rare earth elements in fluid inclusions by inductively coupled plasma-mass spectrometry (ICP-MS). Geochim. Cosmochim. Acta, 1993, 57, 4513–4516

    Article  Google Scholar 

  5. Su W., Qi L., Hu R., Zhang G., Analysis of rareearth elements in fluid inclusions by inductively coupled plasma-mass spectrometry (ICP-MS). Chinese science Bulletin, 1998, 43, 1922–1927

    Article  Google Scholar 

  6. Potseluev A.A., Babkin D.I., Kozmenko O.A., Metals in fluid inclusions from greisen deposits (the Kalgutinsky deposit). Izvestiya of Tomsk polytechnical university, 2006, 309, 26–32 [in Russian]

    Google Scholar 

  7. Habler S., Kempe U., Monecke T., Götze J., Trace element content of quartz from the Ehrenfriedersdorf Sn-W deposit, Germany: Result of an acid-wash procedure. In: Mineral deposit reseach: Meetig the global challenge, 2005, 397–400

  8. Ghazi A.M., Roedder E., Vanko D.A., Rare earth elements (REE) in fluid inclusions from the Butte Cu-Mo deposit: An application of flow injection ICP-MS. PACROFI V, Mexico, 1994, 22–23

  9. Xu J.H., Xie Y.L., Liu J.M., Zhu H.P., Trace elements in fluid inclusions of Wenyu-Dongchuang gold deposits in the Xiaoqinling area, China. Geology and Prospecting, 2004, 40, 1–6

    Google Scholar 

  10. Xu J.H., Xie Y.L., Liu J.M., Zhu H.P., Jia C.S., Trace elements in fluid inclusions of Linglong-Jiaojia type gold deposits. Acta Petrologica Sinica, 2005, 21, 1389–1394

    Google Scholar 

  11. Xu J., Ding R., Xie Y., Zhong C., Shan L., The source of hydrothermal fluids for the Sarekoubu gold deposit in the southern Altai, Xinjiang, China: Evidence from fluid inclusions and geochemistry. Journal of Asian Earth Sciences, 2008, 32, 247–258

    Article  Google Scholar 

  12. Prokofiev V., Baksheev I., Zorina L., Belyatsky B., Ustinov V., Krivitskaya N. Tourmalinization at the Darasun goldfield, Eastern Transbaikalia: Compositional, fluid inclusion and isotopic constraints. Geoscience frontiers, 2012, 3, 59–71

    Article  Google Scholar 

  13. Gu X., Schultz O., Vavtar F., Liu J., Zheng M., Fu S., Rare earth element geohemistry of the Woxi W-Sb-Au deposit, Hunan Province, South China. Ore Geology Reviews, 2007, 31, 319–336

    Article  Google Scholar 

  14. Nokleberg W.J., Parfenov L.M., Monger J.W., Norton I.O., Khanchuk A.I., Stone D.B. et al., Phanerozoic tectonic evolution of the Circum-North Pacific. Openfile report 98-754, USGS, USA, 1998.

  15. Prokopiev A.V., Toro J., Hourigan J.K., Bakharev A.G., Miller E.L., Middle Paleozoic-Mesozoic boundary of the North Asian craton and the Okhotsk terrane: new geochemical and geochronological data and their geodynamic interpretation. Stephan Mueller Spec. Publ. Ser., 2009, 4, 71–84

    Article  Google Scholar 

  16. Parfenov L.M., Berzin N.A., Badarch G., Belichenko V.G., Bulgatov A.N., Dril S.I. et al., Tectonic and Metallogenic Model for Northeast Asia. In: Nokleberg W. J. (Ed.). Metallogenesis and tectonics of northeast Asia. U.S. Geological Survey Professional Paper 1765, 2010, 9-1–9-55

  17. Bortnikov N.S., Gamyanin G.N., Vikent’eva O.V., Prokof’ev V.Yu., Alpatov V.A., Bakharev A.G., Fluid composition and origin in the hydrothermal system of the Nezhdaninsky gold deposit, Sakha (Yakutia), Russia. Geol. Ore Deposits, 2007, 49, 87–128

    Article  Google Scholar 

  18. Gamyanin G.N., Bortnikov N.S., Alpatov V.V., The Nezhdaninsky Gold Deposit-a Unique Deposit in the Northeastern Russia. GEOS, Moscow, 2000 [in Russian]

    Google Scholar 

  19. Genkin A.D., Bortnikov N.S., Cabri L., Wagner F.E., Stanley C.J., Safonov Yu.G. et al. A multilevel study of invisible gold in arsenopyrite from four mesothermal gold deposits in Siberia, Russian Federation. Econ. Geol., 1998, 93, 463–487

    Article  Google Scholar 

  20. Bortnikov N.S., Gamyanin G.N., Vikent’eva O.V., Prokof’ev V.Yu., Prokop’ev A.V., The Sarylakh and Sentachan gold-antimony deposits, Sakha-Yakutia: a case of combined mesothermal gold-quartz and epithermal stibnite ores. Geol. Ore Deposits, 2010, 52, 339–372

    Article  Google Scholar 

  21. Bortnikov N.S., Gamyanin G.N., Vikent’eva O.V., Prokof’ev V.Yu, The Arkachan World-Class Intrusion-Related Gold Deposit, Eastern Yakutia, Russia: REE, Fluid Inclusion and Stable Isotope Studies. In: Barra F., Reich M., Campos E., Tornos F. (ed.), Let’s talk ore deposits. Proceedings of the 11th Biennial Meeting SGA 2011, Antofagasta (Chile), 2011, 580–582

  22. Kryazhev S.G., Prokof’ev V.Yu., Vasyuta Y.V., Use of method ICP MS at the analysis of composition of ore-forming fluids of hydrothermal ore deposits. Vestnik MSU, Geolog., 2006, 4, 30–36 [in Russian]

    Google Scholar 

  23. Bodnar R.J. Vityk M.O., Interpretation of microthermometric data for H2O-NaCl fluid inclusions. In: Fluid Inclusions in Minerals: Methods and Applications. Siena, Pontignano, 1994, 117–130

  24. Brown, P., FlInco R: a computer program for the reduction and investigation of fluid inclusion data. Am. Mineral., 1989, 74, 1390–1393

    Google Scholar 

  25. Borisenko A.S., Cryometric Analysis of Salt Composition from Fluid Inclusions in Minerals. Geol. Geofiz., 1977, 18, 16–27

    Google Scholar 

  26. Brown, P.E., Lamb, W.M., P-V-T properties of fluids in the system H2O-CO2-NaCl: New graphical representations and implications for fluid inclusion studies. Geochim. Cosmochim. Acta, 1989, 53, 1209–1221

    Article  Google Scholar 

  27. Taylor S.R., McLennan S.M., The continental crust: its composition and evolution. Blackwell, Oxford, 1985

    Google Scholar 

  28. Giere R., Formation of rare earth minerals in hydrothermal system. In: Rare earth minerals: chemistry, origin and ore deposits, 1996, 105–150

  29. Wang L., Wang J., Wang Y., Zhu H., Ore-forming fluid and mineralization of Caijiaying and Dajing polymetallic ore deposits. Science in China, 2004, 47, 97–107

    Google Scholar 

  30. Banks D.A., Yardley B.W.D., Campbell A.R., Jarvis K.E., REE composition of an aqueous magmatic fluid: a fluid inclusion study from the Capitan Pluton, New Mexico, USA. Chem. Geol., 1994, 113, 259–272

    Article  Google Scholar 

  31. Lukanin O.A., Dernov-Pegarev V.F., REE in magmatic fluids formed during ascent of granitic melts to the earth’s surface. Electron. Scien. Inform. Journal — Vestn. Otd. Nauk Zem RAN, 2008, 1(26). http://www.scgis.ru/russian/cp1251/h_dgggms/1-2008/informbul-1_2008/magm-21e.pdf

  32. Tomilenko A.A., Gibsher N.A., Koz’menko O.A., Palesskii S.V., Nikolaeva I.V., Lanthanides in fluid inclusions, quartz, and greenschists from auriferous and barren quartz-vein zones of the Sovetskoe quartz-gold deposit, Yenisei Range, Russia. Geochemistry International, 2008, 46, 402–408

    Article  Google Scholar 

  33. Löders V., Moller P., Dulskl P., REE fractionation in carbonates and fluorite. In: Moller, P., Löders, V. (Eds.), Monograph Series on Mineral Deposits, 1993, 30, 133–150

  34. Haas J.R., Shock E.L., Sassani D.C., Rare earth elements in hydrothermal systems: Estimates of standard partial molal thermodynamic properties of aqueous complexes of the rare earth elements at high pressures and temperatures. Geochim. Cosmochim. Acta, 1995, 59, 4329–4350

    Article  Google Scholar 

  35. Wood S.A., The aqueous geochemistry of the rare-earth elements and yttrium. 2. Theoretical predictions of the speciation in hydrothermal solutions to 350°C at saturation water vapour pressure. Chem. Geol., 1990, 88, 99–125

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Olga V. Vikent’eva.

About this article

Cite this article

Vikent’eva, O.V., Gamyanin, G.N. & Bortnikov, N.S. REE in fluid inclusions of quartz from gold deposits of north-eastern Russia. cent.eur.j.geo. 4, 310–323 (2012). https://doi.org/10.2478/s13533-011-0070-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2478/s13533-011-0070-y

Keywords

Navigation