Skip to main content
SpringerLink
Log in

Structures and chemical reactions of SO2 adsorbates studied by surface XAFS

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

Adsorption and surface chemical reactions of SO2 on Ni, Cu and Pd metal surfaces are studied by using surface XAFS, as well as XPS and STM. It has turned out that SO2 lies flat on the Ni(100), Ni(110) and Ni(111) surfaces, while it stands on Pd(100) and Pd(111). By raising the temperature, surface reactions occur on these metal surfaces. Typical reactions on Ni and Cu are 3SO2 → S+2SO3, while those on Pd are 2SO2 → S+SO4. The structures of the adsorbate species are elucidated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J.L. Solomon, R.J. Madix, W. Wurth and J. Stöhr, J. Phys. Chem. 85, 4835 (1991).

    Google Scholar 

  2. D.A. Outka, R.J. Madix, G.B. Fisher and C. DiMaggio, J. Am. Chem. Soc. 90, 4051 (1986).

    CAS  Google Scholar 

  3. M.L. Burke and R.J. Madix, Surf. Sci. 194, 223 (1988).

    Article  CAS  Google Scholar 

  4. K.T. Leung, X.S. Zhang and D.A. Shirley, J. Phys. Chem. 93, 6164 (1989).

    Article  CAS  Google Scholar 

  5. P. Zebisch, M. Weinelt and H.-P. Steinrück, Surf. Sci. 295, 295 (1993).

    Article  CAS  Google Scholar 

  6. J. Stöhr, NEXAFS Spectroscopy, Springer, Berlin, 1992.

    Google Scholar 

  7. J. Stöhr, in D.C. Koningsberger and P. Prins (Eds.), X-ray Absorption Principles Applications Techniques of EXAFS, SEXAFS and XANES, Wiley, New York, 1988.

    Google Scholar 

  8. T. Ohta, Physica B 208 & 209, 427 (1995).

    Article  CAS  Google Scholar 

  9. T. Ohta, J. Electron. Spectrosc. 92, 131 (1998).

    Article  CAS  Google Scholar 

  10. T. Ohta, P.M. Stefan, M. Nomura, and H. Sekiyama, Nucl. Instr. & Methods A246, 373 (1986).

    Article  CAS  Google Scholar 

  11. M. Funabashi, T. Ohta, T. Yokoyama, Y. Kitajima and H. Kuroda, Rev. Sci. Instr. 60, 2505 (1989).

    Article  CAS  Google Scholar 

  12. T. Yokoyama, S. Terada, S. Yagi, A. Imanishi, S. Takenaka, Y. Kitajima and T. Ohta, Surf. Sci. 324, 25 (1995).

    Article  CAS  Google Scholar 

  13. T. Yokoyama, A. Imanishi, S. Terada, H. Namba, Y. Kitajimaa and T. Ohta, Surf. Sci. 334, 88 (1995).

    Article  CAS  Google Scholar 

  14. S. Terada, A. Imanishi, T. Yokoyama, Y. Kitajima and T. Ohta, Surf. Sci. 334, 88 (1995).

    Article  Google Scholar 

  15. S. Terada, M. Sakano, Y. Kitajima, T. Yokoyama and T. Ohta, J. Phys. IV France 7-C2, 703 (1997).

    Google Scholar 

  16. S. Terada, T. Yokoyama, M. Sakano, M. Kiguchi, Y. Kitajima and T. Ohta, Chem. Phys. Lett., in press.

  17. P.J. Hay and W.R. Wadt, J. Chem. Phys. 82, 270 (1985).

    Article  CAS  Google Scholar 

  18. P.J. Hay and W.R. Wadt, J. Chem. Phys. 82, 284 (1985).

    Article  Google Scholar 

  19. P.J. Hay and W.R. Wadt, J. Chem. Phys. 82, 299 (1985).

    Article  CAS  Google Scholar 

  20. S.F. Boys and F. Bernardi, Mol. Phys. 19, 553 (1970).

    Article  CAS  Google Scholar 

  21. M. Pangher, L. Wilde, M. Polcik and J. Haase, Surf. Sci. 372, 211 (1997).

    Article  CAS  Google Scholar 

  22. M. Polcik, L. Wilde and J. Haase, Phys. Rev. B57, 1868 (1998-I).

    Google Scholar 

  23. S. Takenaka, A. Imanishi, S. Terada, T. Yokoyama and T. Ohta, unpublished.

  24. M. Polcik, L. Wilde, J. Haase, B. Brena, D. Cocco, G. Comelli, and G. Paolucci, Phys. Rev. B53, 13720 (1996-II).

    Google Scholar 

  25. K.R. Lawless, Reo. Prog. Phys. 37, 231 (1974).

    Article  CAS  Google Scholar 

  26. T. Nakahashi, S. Terada, T. Yokoyama, H. Hamamatsu, Y. Kitajima, M. Sakano, F. Matsui, and T. Ohta, Surf. Sci. 373, 1 (1997).

    Article  CAS  Google Scholar 

  27. T. Nakahashi, H. Hamamatsu, S. Terada, M. Sakano, F. Matsui, T. Yokoyama, Y. Kitajima and T. Ohta, J. Phys. IV France 7-C2, 679 (1997).

    Google Scholar 

  28. J.J. Rehr, J. Mustre de Leon, S.I. Zabinsky, and R.C. Albers, J. Am. Chem. Soc. 113, 5135 (1991).

    Article  CAS  Google Scholar 

  29. I. Zabinsky, J.J. Rehr, A. Ankdinov, R.C. Albers and M.J. Eller, Phys. Rev. B52, 2995 (1995).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-0033, Tokyo, Japan

    T. Ohta, T. Yokoyama & S. Terada

  2. Department of Chemistry, Faculty of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, 560-8531, Osaka, Japan

    A. Imanishi

  3. Photon Factory, Institute of Materials Structure Science, High Energy Accelerator Research Organization, Oho, Tsukuba, 305-0801, Ibaraki, Japan

    Y. Kitajima

Authors
  1. T. Ohta
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. Yokoyama
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Terada
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Imanishi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Y. Kitajima
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ohta, T., Yokoyama, T., Terada, S. et al. Structures and chemical reactions of SO2 adsorbates studied by surface XAFS. Res. Chem. Intermed. 26, 29–43 (2000). https://doi.org/10.1163/156856700X00066

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1163/156856700X00066

Keywords

Search

Navigation