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γ-Fe2O3 modified with C-18 carboxylic acids: A magnetic carrier for immobilized organic compounds

  • Molecular and Supramolecular Structures at the Interfaces
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Abstract

Ferromagnetic γ-Fe2O3 was modified with stearic and oleic acids. Diffuse reflection spectra show that modification occurs both via the interaction with free surface hydroxyl groups and by forming bidentate carboxylates with iron atoms. Surface modification enhances adsorption of water-soluble organic dyes (orange acid and methylene blue dyes, cytochrome C enzyme) due to contribution of hydrophobic interaction to adsorption. Differences in adsorption of dyes onto the modified γ-Fe2O3 caused by different structures of hydrocarbon chains in stearic and oleic acids were revealed. The effect of electrolyte concentration and pH of a solution on adsorption of cytochrome C was studied. The activated iron(III) oxide can be used as a magnetic carrier for immobilized enzymes in bioreactors and for targeted drug delivery.

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References

  1. Gupta, A. and Gupta, M., Biomaterials, 2005, vol. 26, p. 3995.

    Article  Google Scholar 

  2. Mingalyov, P.G. and Lisichkin, G.V., Russ. Chem. Rev., 2006, vol. 75, no. 6, p. 541.

    Article  Google Scholar 

  3. Petrova, O.S., Gudilin, E.A., Chekanova, A.E., et al., Dokl. Chem., 2006, vol. 410, no. 2, p. 174.

    Article  Google Scholar 

  4. Ikaev, A.M., Mingalyov, P.G., and Lisichkin, G.V., Colloid J., 2007, vol. 69, no. 6, p. 741.

    Article  Google Scholar 

  5. White, M.A., Johnson, J.A., Koberstein, J.T., et al., J. Am. Chem. Soc., 2006, vol. 128, p. 11356.

    Article  Google Scholar 

  6. Khokhlova, T.D. and Zubareva, N.A., in Tr. Vseross. nauchn. konf. po fundamental’nym voprosam adsorbtsii s uchastiem inostrannykh uchenykh (Trans. All-Russian Sci. Conf. with International Participation on Fundamental Researches of Adsorption), Tver, 2013, p. 140.

    Google Scholar 

  7. Suzdalev, I.P., Maksimov, Yu.V., Imshennik, V.K., et al., Ross. Nanotekhnol., 2007, vol. 2, nos. 5–6, p. 73.

    Google Scholar 

  8. Laurent, S., Forge, D., and Port, M., Chem. Rev., 2008, vol. 108, p. 2064.

    Article  Google Scholar 

  9. Pankhurst, Q.A, Connolly, J., Jones, S.K., and Dobson, J., J. Phys. D: Appl. Phys., 2003, vol. 36, p. 167.

    Article  Google Scholar 

  10. Galanov, A.I., Yurmazova, T.A., Savel’ev, G.G., et al., Sib. Onkol. Zh., 2008, vol. 27, no. 3, p. 50.

    Google Scholar 

  11. Pershina, A.G., Sazonov, A.E., and Mil’to, I.V., Byull. Sib. Med., 2008, no. 2, p. 70.

    Google Scholar 

  12. Galanov, A.I., Yurmazova, T.A., Mit’kina, V.A., et al., Perspekt. Mater., 2010, no. 4. C. 49.

    Google Scholar 

  13. Gubin, S.P., Yurkov, G.Yu., Koksharov, Yu.A., and Khomutov, G.B., Russ. Chem. Rev., 2005, vol. 74, no. 6, p. 489.

    Article  Google Scholar 

  14. Matrosova, G.S., Bobkov, A.A., Sosnina, S.A., and Polunina, I.A., Sorbtsionnye Khromatogr. Protsessy, 2010, vol. 10, p. 93.

    Google Scholar 

  15. Kazakov, V.G., Soros. Obraz. Zh., 1997, no. 11, p. 99.

    Google Scholar 

  16. Khokhlova, T.D., Moscow Univ. Chem. Bull., 2006, vol. 61, no. 5, p. 32.

    Google Scholar 

  17. Khokhlova, T.D., Moscow Univ. Chem. Bull., 2008, vol. 63, no. 4, p. 188.

    Article  Google Scholar 

  18. Kuznetsov, B.V., Rakhmanova, T.A., and Simanovich, E.A., Zh. Fiz. Khim., 1994, vol. 68, p. 1635.

    Google Scholar 

  19. Kuznetsov, B.V. and Rakhmanova, T.A., Zh. Fiz. Khim., 1994, vol. 68, p. 759.

    Google Scholar 

  20. Eksperimental’nye metody v adsorptsii i molekulyarnoi khromatografii (Experimental Approach to Adsorption and Molecular Chromatography), Nikitin, Yu.S. and Petrov, R.S., Eds., Moscow: Mosk. Gos. Univ., 1990.

    Google Scholar 

  21. Khokhlova, T.D., Kuznetsov, B.V., and Shoniya, N.K., in Tr. Vseross. simp. “Kinetika i dinamika obmennykh protsessov” (Trans. All-Russian Symp. “Kinetics and Dynamics of Exchange Processes”), Krasnodar krai, 2013, p. 93.

    Google Scholar 

  22. Vasilevskii, Yu.A., Nositeli magnitnoi zapisi (Magnetic Records), Moscow: Iskusstvo, 1989, p. 172.

    Google Scholar 

  23. Davydov, A.A., IK-spektroskopiya v khimii poverkhnosti okislov (Infrared Spectroscopy Applied in Chemistry of the Oxide Surfaces), Novosibirsk: Nauka, 1984.

    Google Scholar 

  24. Baltrusaitis, J., Jensen, J.H., and Grassian, V.H., J. Phys. Chem., 2006, vol. 110, p. 12005.

    Article  Google Scholar 

  25. Bellamy, L., The Infrared Spectra of Complex Molecules, London: Chapman and Hall, 1980, 2nd ed.

    Book  Google Scholar 

  26. Zhang, T., Ge, J., Hu, Y., and Yin, Y., Nano Lett., 2007, vol. 7, p. 3203.

    Article  Google Scholar 

  27. Bronstein, L.M., Huang, X., Retrum, J., et al., Chem. Mater., 2007, vol. 19, p. 3624.

    Article  Google Scholar 

  28. Mahmood, I., Guo, C., Xia, H. et al., Ind. Eng. Chem Res., 2008, vol. 47, p. 6379.

    Article  Google Scholar 

  29. Willis, A.L., Turro, N.J., and O’Brien, S., Chem. Mater., 2005, vol. 17, p. 5970.

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    T. D. Khokhlova & N. A. Zubareva

Authors
  1. T. D. Khokhlova
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  2. N. A. Zubareva
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Correspondence to T. D. Khokhlova.

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Original Russian Text © T.D. Khokhlova, N.A. Zubareva, 2015, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2015, Vol. 51, No. 2, pp. 170–175.

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Khokhlova, T.D., Zubareva, N.A. γ-Fe2O3 modified with C-18 carboxylic acids: A magnetic carrier for immobilized organic compounds. Prot Met Phys Chem Surf 51, 221–225 (2015). https://doi.org/10.1134/S2070205115020094

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  • DOI: https://doi.org/10.1134/S2070205115020094

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