Skip to main content
SpringerLink
Log in

Oxidation of the aniline–styrene epoxide-p-toluenesulfonic acid ternary system in polar solvents: Trends and mechanism

  • Kinetics and Mechanism of Chemical Reactions. Catalysis
  • Published:
Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

Investigation of the kinetics of oxygen absorption by the aniline–styrene epoxide-p-toluenesulfonic acid ternary system (TS) in an acetonitrile solution led to a simple equation for the oxidation rate: V TS = k[aniline]0 • [epoxide]0[acid]1 at [aniline], [epoxide] ≫ [acid], k = 0.77 × 10–3s–1, and 343 K. The data obtained indicated that a complex of the three starting reagents formed before oxidation. In a mixed solvent containing tert-butanol, the dependence of V TS on its composition was extremum. A scheme was suggested that explained the change in the dependence V TS = k′[aniline]–0.63[epoxide]0.86[acid]1 in the mixed solvent by the decomposition of the complex in the presence of alcohol.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. E. Parker and N. S. Isaacs, Chem. Rev. 59, 737 (1959).

    Article  CAS  Google Scholar 

  2. L. V. Petrov and V. M. Solyanikov, Dokl. Akad. Nauk 350, 357 (1996).

    CAS  Google Scholar 

  3. L. V. Petrov and V. M. Solyanikov, Pet. Chem. 51, 458 (2011).

    Article  CAS  Google Scholar 

  4. L. V. Petrov and V. M. Solyanikov, Pet. Chem. 38, 117 (1998).

    Google Scholar 

  5. L. V. Petrov and V. M. Solyanikov, Pet. Chem. 45, 202 (2005).

    Google Scholar 

  6. M. G. Spirin, S. B. Brichkin, and L. V. Petrov, Dokl. Phys. Chem. 465, 301 (2015).

    Article  CAS  Google Scholar 

  7. L. V. Petrov and V. M. Solyanikov, Dokl. Chem. 458, 169 (2014).

    Article  CAS  Google Scholar 

  8. Organic Solvents. Physical Properties and Methods of Purification, Ed. by A. Weisberger (Interscience, New York, 1955).

  9. L. V. Petrov, B. L. Psikha, and V. M. Solyanikov, Pet. Chem. 47, 348 (2007).

    Article  Google Scholar 

  10. L. V. Petrov and V. M. Solyanikov, Pet. Chem. 39, 89 (1999).

    Google Scholar 

  11. L. V. Petrov and V. M. Solyanikov, Russ. Chem. Bull. 61, 40 (2012).

    Article  CAS  Google Scholar 

  12. L. V. Petrov and V. M. Solyanikov, Russ. Chem. Bull. 64, 107 (2015).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    L. V. Petrov & V. M. Solyanikov

Authors
  1. L. V. Petrov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. M. Solyanikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. V. Petrov.

Additional information

Original Russian Text © L.V. Petrov, V.M. Solyanikov, 2016, published in Khimicheskaya Fizika, 2016, Vol. 35, No. 10, pp. 21–26.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Petrov, L.V., Solyanikov, V.M. Oxidation of the aniline–styrene epoxide-p-toluenesulfonic acid ternary system in polar solvents: Trends and mechanism. Russ. J. Phys. Chem. B 10, 764–768 (2016). https://doi.org/10.1134/S1990793116050225

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1990793116050225

Keywords

Search

Navigation