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Synthesis and physicochemical properties of Di- and trivalent metal-ammonium phosphates

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Abstract

Data on the influence exerted by the synthesis conditions and by the nature and relative amounts of precursor reagents on the properties of metal-ammonium phosphates, promising as components of fire-retardant and fire-extinguishing additives, are summarized and analyzed. The manner in which the solution pH and nature and relative amounts of the reacting metal-, nitrogen-, and phosphorus-containing compounds affect the phase composition, solubility, aggregative state, and fundamental aspects of thermal transformations of products being synthesized on the basis of di- and trivalent metal-ammonium phosphates in a wide temperature range is determined.

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  1. Research Institute for Physical Chemical Problems, Belarusian State University, Leningradskaya ul. 14, Minsk, 220030, Belarus

    V. V. Bogdanova & O. I. Kobets

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  1. V. V. Bogdanova
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Original Russian Text © V.V. Bogdanova, O.I. Kobets, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 10, pp. 1385–1399.

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Bogdanova, V.V., Kobets, O.I. Synthesis and physicochemical properties of Di- and trivalent metal-ammonium phosphates. Russ J Appl Chem 87, 1387–1401 (2014). https://doi.org/10.1134/S1070427214100012

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