Abstract
Fragment composition of humic acids isolated from solid caustobioliths of varied genesis and from soil was subjected to a comparative analysis. It was found that the composition of these humic acids is affected by the mechanochemical treatment conditions. It was shown that a mechanochemical treatment leads to a decrease in the molecular mass of humic acids to a varied extent for all caustobioliths and to an increase in the content of aromatic fragments in their structure and in the degree of their oxidation.
Similar content being viewed by others
References
Kashinskaya, T.Ya., Shevchenko, N.V., Tsynkalova, L.Yu., et al., Vestsi Akad. Nauk Belarusi, Ser. Khim. Navuk, 2001, no. 1, pp. 89–92.
Gontsov, A.A., Gontsova, S.A., and Pakhomova, O.V., Khim. Tverd. Tela, 1992, no. 4, pp. 11–17.
Griffith, S.M. and Schnitzer, M., Humic Substances II, In Search of Structure, Hayes, M.H.B., Ed, MacCarthy, P., Malcolm, R.L., and Swift, R.S., Eds., Chichester: John Wiley & Sons, 1989, p. 69.
Perednikova, Z.M., Rumyantseva, Z.A., and Gartsman, B.B., Khim. Tverd. Tela, 1992, no. 1, pp. 36–39.
Pompe, S., Bubner, M., Denecke, M.A., et al., Radiochim. Acta, 1996, vol. 74, p. 135.
USSR Inventor’s Certificate, no.1460036.
Tarnovskaya, L.I. and Maslov, S.G., Khim. Tverd. Tela, 1994, nos. 4–5, pp. 33–39.
Bambalov, N.N., Smirnova, V.V., Navosha, Yu.Yu., et al., Prirodopol’zovanie, 2009, no. 15, pp. 222–225.
Yudina, N.V., Zvereva, A.V., and Lomovskii, O.I., Khim. Tverd. Tela, 2002, no. 5, pp. 3–10.
Savel’eva, A.V., Ivanov, A.A., Lomovskii, O.I., and Dugarzhav, Russ. J. Appl. Chem., 2013, vol. 86, no. 4, pp. 552–557.
Kalabin, G.A., Chechenina, T.E., Paramonova, T.G., et al., Khim. Tverd. Tela, 1997, no. 2, pp. 19–24.
Sachs, S., Bubner, M., Schmeide, K., et al., Talanta, 2002, vol. 57, p. 999.
Orlov, D.S., Praktikum po khimii gumusa: Uchebnoe posobie (Practical Course of Humus Chemistry: Textbook), Moscow: Mosk. Gos. Univ., 1981.
Aleksandrova, L.N., Organicheskoe veshchestvo pochvy i protsessy ego transformatsii (Organic Substance of Soil and Processes for Its Transformation), Leningrad: Nauka, 1980.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.V. Maltseva, A.V. Savel’eva, A.A. Ivanov, N.V. Yudina, O.I. Lomovskii, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 8, pp. 1085–1091.
Rights and permissions
About this article
Cite this article
Maltseva, E.V., Savel’eva, A.V., Ivanov, A.A. et al. Comparative study of the fragment composition of humic acids isolated from caustobioliths and soil by the mechanochemical method. Russ J Appl Chem 87, 1070–1076 (2014). https://doi.org/10.1134/S1070427214080114
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427214080114