Abstract
[Co(S2CNRR’)2] complexes [R = R’ = CH3, C2H5, C3H7, C4H9, or CH2C6H5; RR’ = (CH2)5, (CH2)6, or (CH2)2O(CH2)2] were prepared via interaction of CoCl2 with sodium dithiocarbamates in aqueous medium (pH 6–7). [Co(S2CNRR’)2] are low-spin compounds (μeff 2.19–2.45 μB) with distorted square-planar geometry of the CoS4 coordination node. The Co-S bonds length is 2.22–2.26 Å, and the distance between cobalt and carbon atoms is 2.73–2.74 Å.
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Original Russian Text © N.V. Khitrich, V.G. Vlasenko, I.I. Seifullina, Ya.V. Zubavichus, S.I. Levchenkov, L.S. Skorokhod, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 3, pp. 500–507.
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Khitrich, N.V., Vlasenko, V.G., Seifullina, I.I. et al. Local surrounding of cobalt(II) in dithiocarbamate complexes, their magnetic and spectral properties. Russ J Gen Chem 84, 555–561 (2014). https://doi.org/10.1134/S1070363214030256
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DOI: https://doi.org/10.1134/S1070363214030256