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Thermochemical analysis of intermolecular interaction of aliphatic amino acids with propanediol-1,3 in aqueous media

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Abstract

Integral enthalpy of dissolution of L-alanine, D,L-alanine, and D,L-valine in aqueous propanediol-1,3 (the diol molar fraction 0.26) has been determined. Standard enthalpies of the amino acids dissolution and transfer from water into the mixed solvent have been calculated. Influence of the interaction types and structural features of the amino acids and organic cosolvent on the enthalpies have been analyzed.

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Authors and Affiliations

  1. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    I. N. Mezhevoi & V. G. Badelin

Authors
  1. I. N. Mezhevoi
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  2. V. G. Badelin
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Correspondence to I. N. Mezhevoi.

Additional information

Original Russian Text © I.N. Mezhevoi, V.G. Badelin, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 2, pp. 229–233.

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Mezhevoi, I.N., Badelin, V.G. Thermochemical analysis of intermolecular interaction of aliphatic amino acids with propanediol-1,3 in aqueous media. Russ J Gen Chem 84, 223–226 (2014). https://doi.org/10.1134/S107036321402011X

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  • DOI: https://doi.org/10.1134/S107036321402011X

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