On the 100th anniversary of V.V. Perekalin
Abstract
The interaction of 1-methyl-1-nitroso-2-nitroguanidine with carboxylic acid hydrazides results in formation of N-(2-nitroguanidino)amides that easily give 3(5)-nitroamino-5(3)-alkyl(aryl)-1,2,4-triazoles under refluxing in aqueous alkaline medium. We have developed a one-pot method to prepare such heterocyclic structures; the synthesis of one of the sample compound has given an example of the method applicability. The compounds structures have been confirmed by UV, IR, 1H, and 13C-{1H} NMR spectroscopy.
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Original Russian Text © T.P. Efimova, O.Yu. Ozerova, T.A. Novikova, I.V. Belik, V.M. Berestovitskaya, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 9, pp. 1564–1571.
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Efimova, T.P., Ozerova, O.Y., Novikova, T.A. et al. New representatives of nitroamine-containing 1,2,4-triazoles: Synthesis and structure. Russ J Gen Chem 83, 1779–1786 (2013). https://doi.org/10.1134/S1070363213090259
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DOI: https://doi.org/10.1134/S1070363213090259