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Structure of the Planar Acetate-Bridged Binuclear Copper(II) Complex Based on 1,3-Bis(3-Formyl-5-tert-Butylsalicylidenimino)propanol-2

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Abstract

The X-ray diffraction and magnetochemical studies of the acetate-bridged binuclear copper(II) complex with 1,3-bis(3-formyl-5-tert-butylsalicylidenimino)propanol-2 with a nearly planar structure of the exchange fragment are carried out (СIF file CCDC 940849). The assumption that the magnetic exchange in the complexes with the anticomplementary carboxylate exogenic bridges 1,3-O,O' is determined only by the structural factors and the bridging coordination of the solvent molecule changes the type of the exchange interaction between the copper(II) ions is proved to be true.

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Authors and Affiliations

  1. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    S. I. Levchenkov

  2. Southern Federal University, Rostov-on-Don, 344104, Russia

    S. I. Levchenkov, L. D. Popov, Yu. P. Tupolova, A. N. Morozov, E. A. Raspopova & I. N. Shcherbakov

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

    Z. A. Starikova

Authors
  1. S. I. Levchenkov
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  2. L. D. Popov
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  3. Yu. P. Tupolova
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  4. A. N. Morozov
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  5. E. A. Raspopova
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  6. Z. A. Starikova
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  7. I. N. Shcherbakov
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Corresponding author

Correspondence to S. I. Levchenkov.

Additional information

Original Russian Text © S.I. Levchenkov, L.D. Popov, Yu.P. Tupolova, A.N. Morozov, E.A. Raspopova, Z.A. Starikova, I.N. Shcherbakov, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 10, pp. 592–597.

Deceased.

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Levchenkov, S.I., Popov, L.D., Tupolova, Y.P. et al. Structure of the Planar Acetate-Bridged Binuclear Copper(II) Complex Based on 1,3-Bis(3-Formyl-5-tert-Butylsalicylidenimino)propanol-2. Russ J Coord Chem 43, 630–634 (2017). https://doi.org/10.1134/S1070328417100049

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  • DOI: https://doi.org/10.1134/S1070328417100049

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