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Tetranuclear copper(II) complex with the µ4-1,6-hexadicarboxylate linker: crystal structure and magnetic properties

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Abstract

Tetranuclear copper(II) complex [Cu4L2(OOC(CH2)6COO)] (I) based on bis(azomethine), condensation product of 1-phenyl-3-methyl-4-formylpyrazolone-5 with 1,3-diaminopropanol-2, is synthesized. The structure of its DMSO-adduct (Ia) is determined by X-ray diffraction analysis (CIF file CCDC 1447891). The complexes contain two binuclear fragments bonded by the µ4-1,6-hexadicarboxylate linker. The magnetic exchange interaction in complex I is antiferromagnetic (2J =–155 cm–1), whereas that in complex Ia is ferromagnetic (2J = 129 cm–1), which is due to different conformations of the metallochelate cycles.

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Authors and Affiliations

  1. Southern Federal University, Rostov-on-Don, 344104, Russia

    L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, E. A. Raspopova, Yu. P. Tupolova & V. V. Lukov

  2. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    S. I. Levchenkov

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    G. G. Aleksandrov

Authors
  1. L. D. Popov
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  2. S. I. Levchenkov
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  3. I. N. Shcherbakov
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  4. G. G. Aleksandrov
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  5. E. A. Raspopova
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  6. Yu. P. Tupolova
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  7. V. V. Lukov
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Corresponding author

Correspondence to S. I. Levchenkov.

Additional information

Original Russian Text © L.D. Popov, S.I. Levchenkov, I.N. Shcherbakov, G.G. Aleksandrov, E.A. Raspopova, Yu.P. Tupolova, V.V. Lukov, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 9, pp. 515–520.

† Deceased.

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Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N. et al. Tetranuclear copper(II) complex with the µ4-1,6-hexadicarboxylate linker: crystal structure and magnetic properties. Russ J Coord Chem 43, 559–564 (2017). https://doi.org/10.1134/S107032841709007X

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  • DOI: https://doi.org/10.1134/S107032841709007X

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