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Synthesis and structure of cobalt(II) complexes with nitrilotris(methylenephosphonic) acid [Co(H2O)3{NH(CH2PO3H)3}] and Na4[Co{N(CH2PO3)3}] ·13H2O

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Abstract

Nitrilotris(methylenephosphonato)triaquacobaltum(II) and tetrasodium nitrilotris(methylenephosphonato)cobaltate(II) tridecahydrate were synthesized and studied. The crystals of [Co(H2O)3{NH(CH2PO3H)3}] (I) are monoclinic, space group P21/c, Z = 4, a = 9.2092(2), b = 16.0540(2), c = 9.7445(2) Å, β = 115.778(3)°. The coordination polyhedron of cobalt is a distorted octahedron formed by oxygen atoms. The organophosphorus ligand bridges the neighboring cobalt atoms. The crystals of Na4[Co{N(CH2PO3)3}] · 13H2O (II) are triclinic, space group, P \(\overline 1 \), Z = 2, a = 11.2240(8), b = 11.2663(8), c = 12.3296(8) Å, α = 108.513(6)°, β = 97.261(6)°, γ = 117.056(7)°. The cobalt atom is coordinated to form a distorted trigonal bipyramid. Complex II is a chelate in which the cobalt atom closes three five-membered N-C-P-O-Co rings sharing the Co-N bond. The Co atom is incorporated in the Co-O-Co-O ring. Upon dissolution in water, this ring is opened and cobalt(II) atom is hydrolyzed.

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Authors and Affiliations

  1. Lobachevsky State University of Nizhny Novgorod, pr. Gagarina 23, Nizhny Novgorod, 630600, Russia

    N. V. Somov

  2. Udmurt State University, ul. Krasnoarmeiskaya 71, Izhevsk, 426034, Russia

    F. F. Chausov, R. M. Zakirova & I. V. Fedotova

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  1. N. V. Somov
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  2. F. F. Chausov
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  3. R. M. Zakirova
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  4. I. V. Fedotova
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Correspondence to N. V. Somov.

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Original Russian Text © N.V. Somov, F.F. Chausov, R.M. Zakirova, I.V. Fedotova, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 12, pp. 729–735.

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Somov, N.V., Chausov, F.F., Zakirova, R.M. et al. Synthesis and structure of cobalt(II) complexes with nitrilotris(methylenephosphonic) acid [Co(H2O)3{NH(CH2PO3H)3}] and Na4[Co{N(CH2PO3)3}] ·13H2O. Russ J Coord Chem 41, 798–804 (2015). https://doi.org/10.1134/S1070328415110081

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