Skip to main content
SpringerLink
Log in

Reactivity of two MeCp-cobalt complexes containing 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolate (S2C2B10H10)2– units toward alkynes

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Treatment of o-carborane, n-butyllithium, sulfur, and MeCpCo(CO)I2 under argon leads to twoMeCp-cobalt complexes MeCpCoS2C2B10H10 (I) and (MeCp)2Co2S2C2B10H10 (II). Complex I reacts with phenylacetylene or dimethyl acetylene dicarboxylate to afford B–H activitied complex (MeCpCoS2C2B10H9)(Ph–C–CH2) (III) and addition complex (MeCpCoS2C2B10H10)(MeO2C–C=C–CO2Me) (IV), respectively. Complex II reacts neither with phenylacetylene nor with dimethyl acetylene dicarboxylate. Complexes II–IV have been characterized by elemental analysis, mass, NMR spectroscopy, IR, and X-ray structural analyses (CIF files CCDC nos. 1045892 (II), 1045893 (III) and 1045894 (IV)).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Pleek, J., Chem. Rev., 1992, vol. 92, no. 2, p. 269.

    Article  Google Scholar 

  2. Grimes, R.N., Chem. Rev., 1992, vol. 92, no. 2, p. 251.

    Article  CAS  Google Scholar 

  3. Deng, L. and Xie, Z.W., Coord. Chem. Rev., 2007, vol. 251, nos. 17–20, p. 2452.

    Article  CAS  Google Scholar 

  4. Bregadze, V.I., Chem. Rev., 1992, vol. 92, no. 2, p. 209.

    Article  CAS  Google Scholar 

  5. Larsen, A.S., Holbrey, J.D., Tham, F.S., et al., J. Am. Chem. Soc., 2000, vol. 122, no. 30, p. 7264.

    Article  CAS  Google Scholar 

  6. Hawthorne, M.F. and Maderna, A., Chem. Rev., 1999, vol. 99, no. 12, p. 3421.

    Article  CAS  Google Scholar 

  7. Ivanova, S.M., Ivanov, S.V., Miller, S.M., et al., Inorg. Chem., 1999, vol. 38, no. 17, p. 3756.

    Article  CAS  Google Scholar 

  8. Westerhausen, M., Gückel, C., Schneiderbauer, S., et al., Angew. Chem. Int. Ed., 2001, vol. 40, no. 10, p. 1902.

    Article  CAS  Google Scholar 

  9. Fox, M.A. and Hughes, A.K., Coord. Chem. Rev., 2004, vol. 248, nos. 5–6, p. 457.

    Article  CAS  Google Scholar 

  10. Valliant, J.F., Guenther, K.J., and King, A.S., Coord. Chem. Rev., 2002, vol. 232, nos. 1–2, p. 173.

    Article  CAS  Google Scholar 

  11. Jin, G.X., Wang, J.Q., Zhang, C., et al., Angew. Chem. Int. Ed., 2005, vol. 44, no. 2, p. 259.

    Article  CAS  Google Scholar 

  12. Meng, X., Wang, F., and Jin, G.X., Coord. Chem. Rev., 2010, vol. 254, nos. 11–12, p. 1260.

    Article  CAS  Google Scholar 

  13. Wang, J.Q, Ren, C.X., Weng, L.H., et al., Chem. Commun., 2006, no. 2, p. 162.

    Article  Google Scholar 

  14. Zhang, R., Zhu, L., Liu, G.F., et al., J. Am. Chem. Soc., 2012, vol. 134, no. 25, p. 10341.

    Article  CAS  Google Scholar 

  15. Xu, B.H., Wu, D.H., Li, Y.Z., et al., Organometallics, 2007, vol. 26, no. 17, p. 4344.

    Article  CAS  Google Scholar 

  16. Won, J.H., Kim, D.H., Kim, B.Y., et al., Organometallics, 2002, vol. 21, no. 7, p. 1443.

    Article  CAS  Google Scholar 

  17. Hu, J.R., Ye, H.D., Wang, Y.H., et al., Russ. J. Coord. Chem., 2014, vol. 40, no. 6, p. 413.

    Article  CAS  Google Scholar 

  18. Ye, H.D., Xu, B.H., Xie, M.S., et al., Dalton Trans., 2011, vol. 40, no. 24, p. 6541.

    Article  CAS  Google Scholar 

  19. Li, Y.G., Jiang, Q.B., Li, Y.Z., et al., Inorg. Chem., 2010, vol. 49, no. 12, p. 5584.

    Article  CAS  Google Scholar 

  20. Hu, J.R., Liu, G.F., Jiang, Q.B., et al., Inorg. Chem., 2010, vol. 49, no. 23, p. 11199.

    Article  CAS  Google Scholar 

  21. Xu, B.H., Peng, X.Q., Xu, Z.W., et al., Inorg. Chem., 2008, vol. 47, no. 17, p. 7928.

    Article  CAS  Google Scholar 

  22. Kim, D.H., Ko, J., Park, K., et al., Organometallics, 1999, vol. 18, no. 15, p. 2738.

    Article  CAS  Google Scholar 

  23. Sheldrick, G.M., SHELXS-97, Program for the Solution of Crystal Structures, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  24. Sheldrick, G.M., SHELXL-97, Program for the Refinement of Crystal Structures, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  25. Xu, B.H., Peng, X.Q., Li, Y.Z., et al., Chem. Eur. J., 2008, vol. 14, no. 30, p. 9347.

    Article  CAS  Google Scholar 

  26. Ye, H.D., Ding, G.Y., Xie, M.S., et al., Dalton Trans., 2011, vol. 40, no. 10, p. 2306.

    Article  CAS  Google Scholar 

  27. Ye, H.D., Bai, W.J., Xie, M.S., et al., Eur. J. Inorg. Chem., 2011, vol. 2011, no. 17, p. 2763.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Jiangxi, 334001, P.R. China

    H. D. Ye, J. R. Hu, H. N. Peng, J. L. Xie, Q. Ye, Y. H. Li & Z. S. Xing

Authors
  1. H. D. Ye
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. R. Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. N. Peng
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. L. Xie
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Q. Ye
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Y. H. Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Z. S. Xing
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to H. D. Ye.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ye, H.D., Hu, J.R., Peng, H.N. et al. Reactivity of two MeCp-cobalt complexes containing 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolate (S2C2B10H10)2– units toward alkynes. Russ J Coord Chem 41, 585–591 (2015). https://doi.org/10.1134/S1070328415090092

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328415090092

Keywords

Search

Navigation