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Assistant effect on modulating the two Mn(II) complexes

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Abstract

Two Mn-based complexes with chemical formulae {[Mn(L1)2(H2O)(4,4'-Bipy)] · 3H2O} (I) and [Mn(L2)2(H2O)2(4,4'-Bipy)] (II) (HL1 = 3-(4-hydroxyphenyl)propanoic acid, HL2 = p-hydroxy phenylacetic acid, 4,4'-Bipy = 4,4'-bipyridine), have been synthesized and are characterized by single crystal X-ray diffraction (CIF files CCDC nos. 1045594 (I), 1045595 (II)). Compounds I has 1D zigzag chain constructed by bridging bisdentated 4,4'-Bipy linkers, whereas II shows mononuclear motif due to the monodentated 4,4'-Bipy mode. The assistant effect of the flexibility of carboxylate may play an important to modulate on the resulting motif.

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Authors and Affiliations

  1. School of Chemistry and Pharmaceutical Engineering, Sichuan University of Science & Engineering, Zigong, 643000, P.R. China

    J. Wang, L. Lu, W. P. Wu, B. Xie & Y. Wu

  2. School of Pharmacy, Guangdong Medical University, Dongguan, 523808, P.R. China

    A. Q. Ma

Authors
  1. J. Wang
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  2. L. Lu
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  3. A. Q. Ma
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  4. W. P. Wu
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  5. B. Xie
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  6. Y. Wu
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Corresponding authors

Correspondence to J. Wang or A. Q. Ma.

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Wang, J., Lu, L., Ma, A.Q. et al. Assistant effect on modulating the two Mn(II) complexes. Russ J Coord Chem 41, 618–623 (2015). https://doi.org/10.1134/S1070328415090055

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  • DOI: https://doi.org/10.1134/S1070328415090055

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