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An NMR study of the structures of lanthanide diethylenetriaminepentaacetates

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Abstract

The paramagnetic chemical shifts in the 1H and 13C NMR spectra of lanthanide complexes (Ln = Eu, Yb, and Pr) with diethylenetriaminepentaacetic acid were analyzed. It was demonstrated that Eu+3 in aqueous solution can coordinate to one of the carboxylate groups in a chelating bidendate fashion through two O atoms.

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References

  1. Anderegg, G., Pure Appl. Chem., 2005, vol. 77, p. 1445.

    Article  CAS  Google Scholar 

  2. Armige, F.E., Richardson, D.E., and King, C.P., Bioconjugate Chem., 1990, vol. 1, p. 365.

    Article  Google Scholar 

  3. Kulakov, V., Grigorjeva, E., Koldaeva, E., et al., Advances in Cancer Therapy, Gali-Muhtasib, H., Ed., InTech, 2011, Ch. 6, p. 123.

  4. Kulakov, V.N., Grigor’eva, E.Yu., Lipengol’ts, A.A., et al., Yadernaya fizika i inzhiniring (Nuclear Physics and Engineering), 2011, no. 11, p. 47.

    Google Scholar 

  5. Kulakov, V.N., Lipengol’ts, A.A., and Shimanovskii, N.L., Ross. Khim. Zh., 2012, vol. 56, nos. 3–4, p. 53.

    CAS  Google Scholar 

  6. Tokumitsu, H., Ichikawa, H., Furumori, Y., and Block, I.H., Chem. Pharm. Bull., 1999, vol. 47, p. 838.

    Article  CAS  Google Scholar 

  7. Hermann, P., Kotek, J., Kubiček, V., and Lukeš, I., Dalton Trans., 2008, p. 3027.

    Google Scholar 

  8. Stezowski, J.J. and Hoard, J.L., Isr. J. Chem., 1984, vol. 24, p. 323.

    Article  CAS  Google Scholar 

  9. Summers, S.P., About, K.A., Farrah, S.R., et al., Inorg. Chem., 1994, vol. 33, p. 88.

    Article  CAS  Google Scholar 

  10. Jenkins, B.G. and Lauffer, R.B., Inorg. Chem., 1988, vol. 27, p. 4730.

    Article  CAS  Google Scholar 

  11. Aime, S. and Botta, M., Inorg. Chim. Acta, 1990, vol. 177, p. 101.

    Article  CAS  Google Scholar 

  12. Peters, J.A., Inorg. Chem., 1988, vol. 27, p. 4686.

    Article  CAS  Google Scholar 

  13. Dudev, T. and Lim, C., Acc. Chem. Res., 2007, vol. 40, p. 85.

    Article  CAS  Google Scholar 

  14. Ye, B.-H., Li, X.-Y., Williams, I.D., and Chen, X.-M., Inorg. Chem., 2002, vol. 41, p. 6426.

    Article  CAS  Google Scholar 

  15. Kulakov, V.N., Gol’tyapin, Yu.V., Nikitin, S.M., et al., Sb. nauch. tr. (Collection of Works), Moscow: Mosk. Gos. Inzh.-Fiz. In-t, 1998, part 1, p. 75.

    Google Scholar 

  16. Babushkina, T.A., Zolin, V.F., and Koreneva, L.G., J. Magn. Res., 1983, vol. 52, p. 169.

    CAS  Google Scholar 

  17. Zolin, V.F. and Koreneva, L.G., Redkozemel’nyi zond v khimii i biologii (Rare Earth Probe in Chemistry and Biology), Moscow: Nauka, 1980.

    Google Scholar 

  18. Bleaney, B., J. Magn. Res., 1972, vol. 8, p. 91.

    CAS  Google Scholar 

  19. Kulakov, V.N., Klimova, T.P., Gol’tyapin, Yu.V., et al., Russ. J. Coord. Chem., 2010, vol. 36, no. 5, p. 333.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, Russia

    T. A. Babushkina, T. P. Klimova & A. S. Peregudov

  2. Burnasyan Federal Medical Biophysical Center, Moscow, Russia

    Yu. V. Gol’tyapin, A. A. Lipengolts, A. A. Cherepanov & V. N. Kulakov

  3. Blokhin Cancer Research Center, Russian Academy of Medical Sciences, Moscow, Russia

    A. A. Lipengolts & A. A. Cherepanov

  4. National Nuclear Research University MIFI, Moscow, Russia

    A. A. Lipengolts & A. A. Cherepanov

  5. Moscow State University, Moscow, Russia

    V. N. Kulakov

Authors
  1. T. A. Babushkina
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  2. T. P. Klimova
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  3. A. S. Peregudov
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  4. Yu. V. Gol’tyapin
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  5. A. A. Lipengolts
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  6. A. A. Cherepanov
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  7. V. N. Kulakov
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Corresponding author

Correspondence to T. A. Babushkina.

Additional information

Original Russian Text © T.A. Babushkina, T.P. Klimova, A.S. Peregudov, Yu.V. Gol’tyapin, A.A. Lipengolts, A.A. Cherepanov, V.N. Kulakov, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 1, pp. 46–49.

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Babushkina, T.A., Klimova, T.P., Peregudov, A.S. et al. An NMR study of the structures of lanthanide diethylenetriaminepentaacetates. Russ J Coord Chem 41, 43–46 (2015). https://doi.org/10.1134/S1070328415010017

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  • DOI: https://doi.org/10.1134/S1070328415010017

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