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Crystal structure and magnetic properties of the binuclear copper(II) complex with 2,6-diformyl-4-tert-butylphenol bis(imidazolinylhydrazone)

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Abstract

The binuclear copper(II) complex with 2,6-diformyl-4-tert-butylphenol bis(imidazolinylhydrazone) (H3L), [Cu2(H2L)Br2]ClO4 (I), was synthesized. The structure of complex I was determined by X-ray diffraction analysis. The antiferromagnetic exchange interaction (2J = −108 cm−1) translated through the phenoxide oxygen atom is observed between the copper(II) ions. The exchange parameter was calculated by the quantum-chemical “broken symmetry” method.

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Authors and Affiliations

  1. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    S. I. Levchenkov

  2. Southern Federal University, Rostov-on-Don, 344104, Russia

    L. D. Popov, I. N. Shcherbakov, A. A. Tsaturyan, S. S. Beloborodov, O. V. Maevskii & V. A. Kogan

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    G. G. Aleksandrov

Authors
  1. S. I. Levchenkov
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  2. L. D. Popov
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  3. I. N. Shcherbakov
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  4. G. G. Aleksandrov
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  5. A. A. Tsaturyan
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  6. S. S. Beloborodov
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  7. O. V. Maevskii
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  8. V. A. Kogan
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Correspondence to S. I. Levchenkov.

Additional information

Original Russian Text © S.I. Levchenkov, L.D. Popov, I.N. Shcherbakov, G.G. Aleksandrov, A.A. Tsaturyan, S.S. Beloborodov, O.V. Maevskii, V.A. Kogan, 2013, published in Koordinatsionnaya Khimiya, 2013, Vol. 39, No. 7, pp. 393–399.

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Levchenkov, S.I., Popov, L.D., Shcherbakov, I.N. et al. Crystal structure and magnetic properties of the binuclear copper(II) complex with 2,6-diformyl-4-tert-butylphenol bis(imidazolinylhydrazone). Russ J Coord Chem 39, 493–499 (2013). https://doi.org/10.1134/S107032841307004X

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  • DOI: https://doi.org/10.1134/S107032841307004X

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