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Hydrothermal synthesis, crystal structure, and photoluminescence of a new 2D cadmium(II) complex: {Cd(C8H5O3Cl2)2(C10H8N2)} n

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Abstract

One new cadmium coordination polymer, [Cd(2,4-Dcp)2(4,4-Bipy)] n (I) (2,4-HDcp = 2,4-dichlorophenoxyacetic acid, 4,4′-Bipy = 4,4′-bipyridine) with 2D layer structure, has been prepared by the hydrothermal synthesis and characterized by elemental analysis, IR, TGA and single-crystal X-ray diffraction. Complex I crystallizes belong to monoclinic system and has C2/c space group. Each Cd2+ ion is six-coordinated and located at an octahedral geometry. The Cd2+ ions are linked by bidentate 2,4-Dcp groups into a linear chain in which the benzene rings of 2,4-Dcp ligands point alternately up and down. These chains are further connected into a sandwich-like layer though 4,4′-Bipy ligands. Furthermore, the photoluminescence and life-time of I in the solid state have been studied.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, 526061, P.R. China

    H. F. Guo, D. Y. Ma, L. Qin & P. Yan

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  1. H. F. Guo
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  2. D. Y. Ma
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  3. L. Qin
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  4. P. Yan
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Correspondence to H. F. Guo.

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Guo, H.F., Ma, D.Y., Qin, L. et al. Hydrothermal synthesis, crystal structure, and photoluminescence of a new 2D cadmium(II) complex: {Cd(C8H5O3Cl2)2(C10H8N2)} n . Russ J Coord Chem 39, 58–62 (2013). https://doi.org/10.1134/S1070328412090035

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  • DOI: https://doi.org/10.1134/S1070328412090035

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