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Ligand condensation of P(CH2OH)3: Synthesis and structure of [Ni3S2{(CH2OH)2PCH2OP(CH2OH)2}3][Mo6Cl14] · 0.8H2O

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Abstract

Reaction of NiCl2 · 6H2O and P(CH2OH)3 (THP) with H2S and (H7O3)2[Mo6Cl14] · 3H2O in ethanol produces new trinuclear nickel sulphide complex [Ni3(μ3-S)2{(HOCH2)2PCH2OP(CH2OH)2}3][Mo6Cl14] · 0.8H2O (I) with new bidentate phosphine-phosphinite ligand resulted from THP condensation. It was characterized by X-ray structure analysis.

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References

  1. Pinault, N. and Bruce, D.W., Coord. Chem. Rev., 2003, vol. 241, p. 1.

    Article  CAS  Google Scholar 

  2. Herrmann, W.A. and Kohlpaintner, C.W., Angew. Chem., Int. Ed. Engl., 1993, vol. 32, p. 1524.

    Article  Google Scholar 

  3. Kothari, K.K., Raghuraman, K., Pillarsetty, N.K., et al., Appl. Radiat. Isot., 2003, vol. 58, p. 543.

    Article  CAS  Google Scholar 

  4. Dilworth, J.R. and Parrott, S.J., Chem. Soc. Rev., 1998, vol. 27, p. 43.

    Article  CAS  Google Scholar 

  5. Blower, P.J., Transituin Met. Chem., 1998, vol. 23, p. 109.

    Article  CAS  Google Scholar 

  6. Katti, K.V., Gali, H., Smith, C.J., et al., Acc. Chem. Res., 1999, vol. 32, p. 9.

    Article  CAS  Google Scholar 

  7. Ellis, J.W., Harrison, K.N., Hoye, P.A.T., et al., Inorg. Chem., 1992, vol. 31, p. 3026.

    Article  CAS  Google Scholar 

  8. Chatt, J., Leigh, J.G., and Slade, R.M., J. Chem. Soc., Dalton Trans., 1973, p. 2021.

  9. Berning, D.E., Katti, K.V., Barbour, L.G., et al., Inorg. Chem., 1998, p. 334.

  10. Driessen-Holscher, B. and Heinen, J., J. Organomet. Chem., 1998, vol. 570, p. 141.

    Article  CAS  Google Scholar 

  11. Fukoka, A., Kosugi, W., Morishita, F., et al., Chem. Commun., 1999, p. 489.

  12. Algarra, A.G., Basallote, M.G., Fernandez-Trujillo, M.J., et al., Inorg. Chem., 2007, vol. 46, p. 7668.

    Article  CAS  Google Scholar 

  13. Sheldrick, G.M., SHELXTL. Programs for Structure Solution and Refinement, Bruker AXS, 1990–2007.

  14. Sheldrick, G.M., SADABAS. Program for Empirical X-Ray Absorption Correction, Bruker AXS, 1990–2007.

  15. Allen, F.H., Acta Crystallogr., Sect. B: Struct. Sci., 2002, vol. 58, p. 380.

    Article  Google Scholar 

  16. Gilardi, C.A., Midollini, S., and Sacconi, L., Inorg. Chim. Acta, 1978, vol. 31, p. L431.

    Article  Google Scholar 

  17. Nannelli, P. and Block, B.P., Inorg. Synth., 1970, vol. 12, p. 170.

    CAS  Google Scholar 

  18. Cordero, B., Gymez, V., Platero-Prats, A.E., et al., Dalton Trans., 2008, p. 2832.

  19. Sokolov, M.N., Anyushin, A.V., Virovets, A.V., et al., Inorg. Chem. Commun., 2011, vol. 14, p. 1659.

    Article  CAS  Google Scholar 

  20. Hoye, P.A.T., Pringle, P.G., and Smith, M.B., Dalton Trans., 1993, p. 269.

  21. Lorenzini, F., Patrick, B.O., and James, B.R., Inorg. Chem., 2007, vol. 6, p. 8998.

    Article  Google Scholar 

  22. Sellmann, D., Lauderbach, F., and Geipel, F., Angew. Chem., Int. Ed. Engl., 2004, vol. 43, p. 3141.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Novosibirsk, Russia

    A. V. Anyushin, P. A. Abramov, Nikolay B. Kompankov, M. N. Sokolov & V. P. Fedin

  2. Novosibirsk State University, Novosibirsk, Russia

    A. V. Anyushin, P. A. Abramov, M. N. Sokolov & V. P. Fedin

Authors
  1. A. V. Anyushin
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  2. P. A. Abramov
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  3. Nikolay B. Kompankov
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  4. M. N. Sokolov
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  5. V. P. Fedin
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Corresponding author

Correspondence to M. N. Sokolov.

Additional information

Original Russian Text © A.V. Anyushin, P.A. Abramov, Nikolay B. Kompankov, M.N. Sokolov, V.P. Fedin, 2012, published in Koordinatsionnaya Khimiya, 2012, Vol. 38, No. 10, pp. 729–733.

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Anyushin, A.V., Abramov, P.A., Kompankov, N.B. et al. Ligand condensation of P(CH2OH)3: Synthesis and structure of [Ni3S2{(CH2OH)2PCH2OP(CH2OH)2}3][Mo6Cl14] · 0.8H2O. Russ J Coord Chem 39, 77–81 (2013). https://doi.org/10.1134/S1070328412090011

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  • DOI: https://doi.org/10.1134/S1070328412090011

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