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Extraction of rare earth elements(III) from HNO3 and HCl solutions with mixtures of carbamoylmethylphosphine oxides and picrolonic acid

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Abstract

Extraction of REE(III) microamounts from HNO3 and HCl solutions with mixtures of mono- and bis-carbamoylmethylphosphine oxides with picrolonic acid in 1,2-dichloroethane was studied. The strong synergistic effect observed is due to increased hydrophobicity of the extractable complexes. The influence of the structure of carbamoylmethylphosphine oxides on the REE(III) extraction efficiency was considered, and the stoichiometry of the extractable complexes was determined. The possibility of REE(III) recovery and preconcentration from nitric acid solutions with a complexing sorbent prepared by noncovalent immobilization of the reagent mixture on the surface of a macroporous polymeric sorbent was demonstrated.

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References

  1. Chmutova, M.K., Litvina, M.N., Pribylova, G.A., et al., Radiokhimiya, 1999, vol. 41, no. 4, pp. 331–335.

    Google Scholar 

  2. Artyushin, O.I., Sharova, E.V., Odinets, I.L., et al., Izv. Ross. Akad. Nauk, Ser. Khim., 2004, no. 11, pp. 2394–2402.

    Google Scholar 

  3. Turanov, A.N., Karandashev, V.K., Yarkevich, A.N., and Safronova, Z.V., Radiokhimiuya, 2007, vol. 49, no. 2, pp. 148–152.

    Google Scholar 

  4. Yagodin, G.A., Kagan, S.Z., Sergievskii, V.V., et al., Osnovy zhidkostnoi ekstraktsii (Principles of Liquid Extraction), Moscow: Khimiya, 1981.

    Google Scholar 

  5. Romanovskiy, V.N., Smirnov, V.I., Babain, V.A., et al., Solvent Extr. Ion Exch., 2001, vol. 19, no. 1, pp. 1–21.

    Article  CAS  Google Scholar 

  6. Nakashima, K., Kubota, F., Maruyama, T., and Goto, M., Anal. Sci., 2003, vol. 19, pp. 1097–1098.

    Article  CAS  Google Scholar 

  7. Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Radiokhimiya, 2008, vol. 50, no. 3, pp. 229–235.

    Google Scholar 

  8. Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Zh. Neorg. Khim., 2008, vol. 53, no. 6, pp. 1045–1051.

    CAS  Google Scholar 

  9. Naganawa, H., Suzuki, H., Tachimori, S., et al., Phys. Chem. Chem. Phys., 2001, vol. 3, pp. 2509–2517.

    Article  CAS  Google Scholar 

  10. Kuvatov, Yu.G., Nikitin, Yu.E., and Murinov, Yu.I., Radiokhimiya, 1980, vol. 22, no. 3, pp. 358–362.

    CAS  Google Scholar 

  11. Murinov, Yu.I., Nikitin, Yu.E., Kuvatov, Yu.G., et al., in Khimiya i tekhnologiya ekstraktsii (Chemistry and Technology of Extraction), Moscow, 2001, vol. 1, pp. 147–155.

    Google Scholar 

  12. Artyushin, O.I., Sharova, E.V., Odinets, I.L., et al., Izv. Ross. Akad. Nauk, Ser. Khim., 2006, no. 8, pp. 1387–1394.

    Google Scholar 

  13. Turanov, A.N., Karandashev, V.K., Sharova, E.V., et al., Solvent Extr. Ion Exch., 2010, vol. 28, pp. 579–595.

    Article  CAS  Google Scholar 

  14. Turanov, A.N., Karandashev, V.K., Sharova, E.V., et al., Solvent Extr. Ion Exch., 2012, vol. 30, pp. 604–622.

    Article  CAS  Google Scholar 

  15. Kul’berg, L.M., Sintezy organicheskikh reaktivov dlya neorganicheskogo analiza (Synthesis of Organic Reagents for Inorganic Analysis), Moscow: Goskhimizdat, 1947, pp. 110–111.

    Google Scholar 

  16. Horwitz, E.P., Dietz, M.L., Nelson, D.M., et al., Anal. Chim. Acta, 1990, vol. 238, pp. 263–271.

    Article  CAS  Google Scholar 

  17. Turanov, A.N., Karandashev, V.k., Baulin, V.E., and Tsvetkov, E.N., Zh. Neorg. Khim., 1995, vol. 40, no. 11, pp. 1926–1930.

    CAS  Google Scholar 

  18. Litvina, M.N., Chmutova, M.K., Kulyako, Yu.M., and Myasoedov, B.F., Radiokhimiya, 2004, vol. 46, no. 1, pp. 38–40.

    Google Scholar 

  19. Horwitz, E.P., Martin, K.A., Diamond, H., and Kaplan, L., Solvent Extr. Ion Exch., 1986, vol. 4, no. 3, pp. 449–494.

    Article  CAS  Google Scholar 

  20. Turanov, A.N., Karandashev, V.K., and Bondarenko, N.A., Radiokhimiya, 2007, vol. 49, no. 1, pp. 50–57.

    Google Scholar 

  21. Yatsimirskii, K.B., Kostromina, N.A., Sheka, Z.A., et al., Khimiya kompleksnykh soedinenii redkozemel’nykh metallov (Chemistry of Coordination Compounds of Rare Earth Metals), Kiev: Naukova Dumka, 1966.

    Google Scholar 

  22. Turanov, A.N., Karandashev, V.K., Sharova, E.V., et al., Tsvetn. Met., 2012, no. 3, pp. 51–55.

    Google Scholar 

  23. Turanov, A.N., Karandashev, V.K., Sharova, E.V., et al., Radiokhimiya, 2012, vol. 54, no. 1, pp. 47–52.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Solid State Physics, Russian Academy of Sciences, ul. Akad. Osip’yana 2, Chernogolovka, Moscow oblast, 142432, Russia

    A. N. Turanov

  2. Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences, Chernogolovka, Moscow oblas, Russia

    V. K. Karandashev

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    E. V. Sharova, O. I. Artyushin & I. L. Odinets

Authors
  1. A. N. Turanov
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  2. V. K. Karandashev
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  3. E. V. Sharova
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  4. O. I. Artyushin
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  5. I. L. Odinets
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Correspondence to A. N. Turanov.

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Original Russian Text © A.N. Turanov, V.K. Karandashev, E.V. Sharova, O.I. Artyushin, I.L. Odinets, 2013, published in Radiokhimiya, 2013, Vol. 55, No. 2, pp. 156–160.

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Turanov, A.N., Karandashev, V.K., Sharova, E.V. et al. Extraction of rare earth elements(III) from HNO3 and HCl solutions with mixtures of carbamoylmethylphosphine oxides and picrolonic acid. Radiochemistry 55, 203–207 (2013). https://doi.org/10.1134/S1066362213020100

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  • DOI: https://doi.org/10.1134/S1066362213020100

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