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The effect of constant electric field on the oxidation rate of massive zinc in supercritical water and the formation of zinc oxide nanocrystals

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Abstract

It is established that the rate of oxidation of a massive zinc plate by supercritical water (SCW) at 673 K and 23 MPa increases and the morphology of obtained ZnO nanocrystals changes when strength E of the constant electric field applied perpendicular to the plate increases from 0 to 286 kV/m. A decrease in the SCW density at the same temperature results in the formation of a more compact nanostructured ZnO layer, while the increase in E leads to loosening of structure in the inner part of the ZnO layer.

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Authors and Affiliations

  1. Kutateladze Institute of Thermophysics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    A. V. Shishkin & M. Ya. Sokol

Authors
  1. A. V. Shishkin
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  2. M. Ya. Sokol
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Correspondence to A. V. Shishkin.

Additional information

Original Russian Text © A.V. Shishkin, M.Ya. Sokol, 2014, published in Pis’ma v Zhurnal Tekhnicheskoi Fiziki, 2014, Vol. 40, No. 12, pp. 44–51.

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Shishkin, A.V., Sokol, M.Y. The effect of constant electric field on the oxidation rate of massive zinc in supercritical water and the formation of zinc oxide nanocrystals. Tech. Phys. Lett. 40, 516–519 (2014). https://doi.org/10.1134/S106378501406025X

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  • DOI: https://doi.org/10.1134/S106378501406025X

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