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High-temperature heat capacity of orthovanadates Ce1–x Bi x VO4

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Abstract

Orthovanadates Ce1–x Bi x VO4 (1 ≥ x ≥ 0) have been produced by solid-phase synthesis from initial oxides CeO2, Bi2O3, and V2O5 upon step-by-step burning. The high-temperature heat capacity of Ce1–x Bi x VO4 has been measured by differential scanning calorimetry. The experimental data on C p = f(T) were used to calculate the thermodynamic properties (the enthalpy changes, the entropy changes, and the Gibbs energy).

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Authors and Affiliations

  1. Institute of Nonferrous Metals and Materials Science, Siberian Federal University, pr. imeni Gazety “Krasnoyarskii rabochii” 95, Krasnoyarsk, 660025, Russia

    L. T. Denisova, L. G. Chumilina, N. V. Belousova & V. M. Denisov

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  1. L. T. Denisova
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  2. L. G. Chumilina
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  3. N. V. Belousova
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  4. V. M. Denisov
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Correspondence to L. T. Denisova.

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Original Russian Text © L.T. Denisova, L.G. Chumilina, N.V. Belousova, V.M. Denisov, 2016, published in Fizika Tverdogo Tela, 2016, Vol. 58, No. 9, pp. 1867–1870.

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Denisova, L.T., Chumilina, L.G., Belousova, N.V. et al. High-temperature heat capacity of orthovanadates Ce1–x Bi x VO4 . Phys. Solid State 58, 1933–1937 (2016). https://doi.org/10.1134/S1063783416090122

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  • DOI: https://doi.org/10.1134/S1063783416090122

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