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Synthesis and crystal structure of 3-ammonium-4-hydroxyphenyl sulfonate hemihydrate

  • Structure of Organic Compounds
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Abstract

The crystal structure of 3-ammonium-4-hydroxyphenyl sulfonate hemihydrate C6H3(NH3)(OH)SO3 · 0.5H2O is determined by single-crystal X-ray diffraction. The unit cell parameters are as follows: a = 11.2395(3), b = 10.3814(3), c = 13.7509(4) Å, β = 100.326(1)°, V = 1578.49(8) Å3, space group P21/n, Z = 4. The crystal structure can be described us a succession of infinite corrugated layers parallel to ab plane. These layers consist of rings formed by four sulfonate molecules located around a center of symmetry. The rings are connected to each other and to water molecules via O-H...O hydrogen bonds. The structure is further stabilized by π-π interactions between phenyl rings of organic entities of successive layers.

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Authors and Affiliations

  1. Solid State Laboratory, Sfax Faculty of Science, University of Sfax, BP 1171, 3000, Sfax, Tunisia

    M. Belhouchet & T. Mhiri

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  1. M. Belhouchet
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  2. T. Mhiri
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Correspondence to M. Belhouchet.

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Belhouchet, M., Mhiri, T. Synthesis and crystal structure of 3-ammonium-4-hydroxyphenyl sulfonate hemihydrate. Crystallogr. Rep. 58, 115–118 (2013). https://doi.org/10.1134/S106377451301015X

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  • DOI: https://doi.org/10.1134/S106377451301015X

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