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Gas chromatographic determination of admixtures of permanent gases, CO, CO2, and hydrocarbons in methylsilane

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Abstract

A procedure is developed for the gas chromatographic determination of admixtures of permanent gases, CO, CO2, and hydrocarbons in methylsilane with detection limits of 0.02–0.8 ppm. The procedure was applied to the analysis of methylsilane obtained by reducing methyltrichlorosilane with sodium tetrahydrob-orate in an organic solvent. Admixtures of permanent gases and C1–C5 hydrocarbons the in synthesized methylsilane were detected.

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Authors and Affiliations

  1. Nizhni Novgorod State Technical University, ul. Minina 24, Nizhni Novgorod, 603600, Russia

    V. M. Vorotyntsev, G. M. Mochalov & I. V. Baranova

Authors
  1. V. M. Vorotyntsev
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  2. G. M. Mochalov
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  3. I. V. Baranova
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Additional information

Original Russian Text © V.M. Vorotyntsev, G.M. Mochalov, I.V. Baranova, 2013, published in Zhurnal Analiticheskoi Khimii, 2013, Vol. 68, No. 2, pp. 165–169.

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Vorotyntsev, V.M., Mochalov, G.M. & Baranova, I.V. Gas chromatographic determination of admixtures of permanent gases, CO, CO2, and hydrocarbons in methylsilane. J Anal Chem 68, 152–155 (2013). https://doi.org/10.1134/S1061934813020202

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  • DOI: https://doi.org/10.1134/S1061934813020202

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