Skip to main content
SpringerLink
Log in

Extraction of platinum with Astrafloxin FF from aqueous-organic solutions: Separative extraction-spectrophotometric determination of platinum(II) and platinum(IV) species

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

The optimum conditions of the extraction of the ion associates of platinum with the thiocyanate ions and the polymethine basic dye Astrafloxin FF by aromatic hydrocarbons and acetic acid esters from aqueous and aqueous-organic solutions were studied. The introduction of water-soluble donor-active solvents (hexamethylphosphoric triamide, N,N-diethylacetamide, N,N-dimethylformamide, and N,N-diethylformamide) leads to a considerable increase in the extraction of the ion associates of platinum and the simultaneous suppression of the extraction of the simple dye salt. The molar absorption coefficients of the extracts of ion associates are as high as (8.1–13.3) × 104. 84–96% platinum is extracted in the form of ion associates by a single extraction. The conversion of platinum into ion associates makes it possible to separate platinum from many elements, including Cu, Cd, Ni, Co, Cr, Pb, In, Ag, Pd, Ir, Rh, and Ru, by extraction. In this case, platinum(II) is extracted in the form of ion associates under standard conditions, whereas platinum(IV) is extracted only after the preliminary thermal treatment of the test sample. A new procedure was developed for the extraction-spectrophotometric determination of the trace amounts of platinum(II) and platinum(IV), in particular, in their mixtures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ginzburg, S.I., Ezerskaya, N.A., Prokof’eva, I.V., Fedorenko, N.V., Shlenskaya, V.I., and Bel’skii, N.K., Analiticheskaya khimiya platinovykh metallov (Analytical Chemistry of Platinum Group Metals), Moscow: Nauka, 1972.

    Google Scholar 

  2. Analiticheskaya khimiya metallov platinovoi gruppy (Analytical Chemistry of Platinum Group Metals), Zolotov, Yu.A., Varshal, G.M., and Ivanov, V.M., Ed., Moscow: KomKniga, 2005.

    Google Scholar 

  3. Pyrzynska, K., Talanta, 1998, vol. 47, no. 4, p. 841.

    Article  CAS  Google Scholar 

  4. Djingova, R., Heidenreich, H., Kovacheva, P., and Markert, B., Anal. Chim. Acta, 2003, vol. 489, no. 2, p. 245.

    Article  CAS  Google Scholar 

  5. Kozlowski, H. and Pettit, L.D., in Chemistry of the Platinum Group Metals: Recent Developments, Hartly, F.R., Ed., Amsterdam: Elsevier, 1991.

    Google Scholar 

  6. Hamáček, J. and Havel, J., J. Chromatogr., A, 1999, no. 334, p. 321.

  7. Barefoot, R.R. and Van Loon, J.C., Talanta, 1999, vol. 49, no. 1, p. 1.

    Article  CAS  Google Scholar 

  8. Vasilyeva, A.A., Yudelevich, I.G., Gindin, L.M., Lanbina, T.V., Shulman, R.S., Kotlarevsky, I.L., and Andrievsky, V.N., Talanta, 1975, vol. 22, no. 9, p. 745.

    Article  CAS  Google Scholar 

  9. Belova, V.V. and Kholkin, A.I., J. Mol. Liq., 1999, vol. 82, nos. 1–2, p. 131.

    Google Scholar 

  10. Belova, V.V. and Kholkin, A.I., Solvent Extr. Ion Exch., 1998, vol. 16, no. 5, p. 1233.

    Article  CAS  Google Scholar 

  11. Belova, V.V., Kholkin, A.I., and Zhidkova, T.I., Theor. Found. Chem. Eng., 2007, vol. 41, no. 5, p. 743.

    Article  CAS  Google Scholar 

  12. Rao, C.R.M. and Reddi, G.S., Trends Anal. Chem., 2001, vol. 9, p. 565.

    Google Scholar 

  13. Bencs, L., Khaiwal Ravindra, and Rene Van Grieken, Spectrochim. Acta, B, 2003, vol. 58, no. 10, p. 1723.

    Article  Google Scholar 

  14. Wildhagen, D. and Krivan, V., Anal. Chim. Acta, 1993, vol. 274, no. 2, p. 257.

    Article  CAS  Google Scholar 

  15. Rietz, B., Heydorm, K., and Krapur-Hansen, A., Trace Elem. Electrol., 2002, no. 19, p. 38.

  16. Khuhawar, M.Y. and Arain, G.M., Talanta, 2005, vol. 66, no. 1, p. 34.

    Article  CAS  Google Scholar 

  17. Suwaru Hoshi, Koki Higashihara, Mamiko Suzuki, Yasutoshi Sakurada, Kazuharu Sugawara, Masayuki Uto, and Kunihiko Akatsuka, Talanta, 1997, vol. 44, no. 4, p. 571.

    Article  CAS  Google Scholar 

  18. Da Costa, J.A.C., Vieira, M.A., Luna, A.S., and De Campos, R.C., Talanta, 2010, vol. 82, no. 5, p. 1647.

    Article  Google Scholar 

  19. Bukhbinder, G.L., Korda, T.M., Demidova, M.G., Guskova, E.A., and Torgov, V.G., J. Anal. Chem., 2009, vol. 64, no. 6, p. 593.

    Article  CAS  Google Scholar 

  20. Torgov, V.G., Korda, T.M., Demidova, M.G., Gus’kova, E.A., and Bukhbinder, G.L., J. Anal. Atom. Spectrom., 2009, vol. 24, no. 11, p. 1551.

    Article  CAS  Google Scholar 

  21. Beamish, F.E., The Analytical Chemistry of the Noble Metals, New York: Pergamon, 1966.

    Google Scholar 

  22. Thimme Gowda, A., Made Gowda, N.M., and Sanke Gowda, H., Microchem. J., 1985, vol. 32, no. 2, p. 211.

    Article  Google Scholar 

  23. Mojski, M. and Kalinowski, K., Microchem. J., 1980, vol. 25, no. 4, p. 507.

    Article  CAS  Google Scholar 

  24. Sanke Gowda, H. and Jagadeesh, K.S., Talanta, 1978, vol. 25, no. 7, p. 416.

    Article  Google Scholar 

  25. Uttarwar, R.M. and Joshi, A.P., Microchem. J., 1978, vol. 23, no. 2, p. 151.

    Article  CAS  Google Scholar 

  26. Edward D. Golla and Gilbert H. Ayres, Talanta, 1973, vol. 20, no. 2, p. 199.

    Article  CAS  Google Scholar 

  27. Sen Gupta, J.G., Anal. Chim. Acta, 1960, vol. 23, p. 462.

    Article  CAS  Google Scholar 

  28. Sur, K. and Shome, S.C., Anal. Chim. Acta, 1971, vol. 57, no. 1, p. 201.

    Article  CAS  Google Scholar 

  29. Manku, G.S., Bhat, A.N., and Jain, B.D., Talanta, 1969, vol. 16, no. 10, p. 1421.

    Article  CAS  Google Scholar 

  30. Donglan Ma, Ying Li, Kuangbiao Ma, Jianping Li, Jianguo Chen, Jiawei Yan, and Yulu Wang, Talanta, 2001, vol. 53, no. 5, p. 937.

    Article  CAS  Google Scholar 

  31. Ivanov, V.M., Geterotsiklicheskie azotsoderzhashchie azosoedineniya (Heterocyclic Nitrogen-Containing Azo Compounds), Moscow: Nauka, 1982.

    Google Scholar 

  32. Pilipenko, A.T., Khvatkova, Z.M., and Golovina, V.V., Zh. Anal. Khim., 1986, vol. 41, no. 11, p. 2045.

    CAS  Google Scholar 

  33. Marczenko, Z. and Kalinowski, K., Anal. Chim. Acta, 1983, vol. 153, p. 219.

    Article  CAS  Google Scholar 

  34. Evaldo L. Kothny, J. Geochem. Explor., 1974, vol. 3, p. 291.

    Article  CAS  Google Scholar 

  35. Aleksenko, S.S., Gumenyuk, A.P., and Mushtakova, S.P., J. Anal. Chem., 2004, vol. 59, no. 2, p. 185.

    Article  CAS  Google Scholar 

  36. Bazel, Ya. and Andruch, V., Chem. Listy, 2006, vol. 100, no. 9, p. 784.

    CAS  Google Scholar 

  37. Bazel, Ya.R., Studenyak, Ya.I., and Tolmachev, A.A., J. Anal. Chem., 1997, vol. 52, no. 6, p. 536.

    CAS  Google Scholar 

  38. Kish, P.P., Bazel, Ya.R., and Studenyak, Ya.I., Zh. Anal. Khim., 1992, vol. 47, no. 7, p. 1233.

    CAS  Google Scholar 

  39. Kish, P.P., Studenyak, Ya.I., and Bazel, Ya.R., Zavod. Lab., 1992, vol. 58, no. 12, p. 9.

    CAS  Google Scholar 

  40. Bazel, Ya.R., Kushnir, L.N., Korzhova, E.P., Studenyak, Ya.I., and Tolmachev, A.A., Zh. Anal. Khim., 1994, vol. 49, no. 7, p. 686.

    CAS  Google Scholar 

  41. Kocúrová, L., Balogh, I.S., Skrlíková, J., Postssa, J., and Andruch, V., Talanta, 2010, vol. 82, p. 1958.

    Article  Google Scholar 

  42. Serbin, R., Bazel, Ya.R., Andruch, V., and Balog, I.S., J. Anal. Chem., 2011, vol. 66, no. 9, p. 800.

    Article  CAS  Google Scholar 

  43. Balog, I.S., Kish, P.P., Ishchenko, A.A., Mushkalo, I.A., and Andruch, V.A., Zh. Anal. Khim., 1990, vol. 45, no. 3, p. 481.

    CAS  Google Scholar 

  44. Bazel, Ya.R., Kormosh, Zh.A., and Tolmachev, A.A., J. Anal. Chem., 2002, vol. 57, no. 2, p. 118.

    Article  CAS  Google Scholar 

  45. Vishnikin, A.B., Mohammed Khair, E.A., Al-Shwaiyat, Bazel, Y.R., and Andruch, V., Microchim. Acta, 2007, nos. 3–4, p. 371.

  46. Kormosh, Zh.A. and Bazel, Ya.R., J. Anal. Chem., 1999, vol. 54, no. 7, p. 607.

    CAS  Google Scholar 

  47. Balogh, I.S., Andruch, V., and Kovács, M., Anal. Bioanal. Chem., 2003, vol. 37, no. 4, p. 709.

    Article  Google Scholar 

  48. Khimiya psevdogalogenidov (Chemistry of Pseudohalides), Golub, A.M., Keller, H., Skopenko, V.V., et al., Eds., Kiev: Vishcha Shkola, 1981.

    Google Scholar 

  49. Zolotov, Yu.A., Iofa, B.Z., and Chuchalin, L.K., Ekstraktsiya galogenidnykh kompleksov metallov (Extraction of Halide Complexes of Metals), Moscow: Nauka, 1973.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Uzhgorod State University, ul. Pidgirna 46, Uzhgorod, 88000, Ukraine

    Ya. R. Bazel, T. A. Kulakova, Ya. I. Studenyak & S. Rednik

  2. Pavol Jozef Safarik University, Moyzesova 11, Kosice, SK 04154, Slovakia

    Ya. R. Bazel, R. Serbin & V. Andruch

Authors
  1. Ya. R. Bazel
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. A. Kulakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ya. I. Studenyak
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. Serbin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. Rednik
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. Andruch
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © Ya.R. Bazel, T.A. Kulakova, Ya.I. Studenyak, R. Serbin, S. Rednik, V. Andruch, 2012, published in Zhurnal Analiticheskoi Khimii, 2012, Vol. 67, No. 6, pp. 577–584.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bazel, Y.R., Kulakova, T.A., Studenyak, Y.I. et al. Extraction of platinum with Astrafloxin FF from aqueous-organic solutions: Separative extraction-spectrophotometric determination of platinum(II) and platinum(IV) species. J Anal Chem 67, 519–526 (2012). https://doi.org/10.1134/S1061934812040077

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934812040077

Keywords

Search

Navigation