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Determination of the surface potential for adsorption layers of polyelectrolytes by the streaming potential method

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Abstract

A physicochemical model is proposed to describe electrokinetic phenomena in capillaries and pores the surface of which is coated with a charged porous adsorption layer. The use of this model makes it possible to explain experimental data on the surface potentials of polyelectrolyte adsorption layers upon their deformation resulting from solution flow. The commonly used Smoluchowski equation is shown to lead to large errors in the determination of the potential and charge of the surface of an adsorption layer.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    V. D. Sobolev, I. P. Sergeeva & O. A. Kiseleva

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  1. V. D. Sobolev
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  2. I. P. Sergeeva
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  3. O. A. Kiseleva
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Additional information

Original Russian Text © V.D. Sobolev, I.P. Sergeeva, O.A. Kiseleva, 2012, published in Kolloidnyi Zhurnal, 2012, Vol. 74, No. 6, pp. 758–763.

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Sobolev, V.D., Sergeeva, I.P. & Kiseleva, O.A. Determination of the surface potential for adsorption layers of polyelectrolytes by the streaming potential method. Colloid J 74, 721–725 (2012). https://doi.org/10.1134/S1061933X12060130

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  • DOI: https://doi.org/10.1134/S1061933X12060130

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