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Systems based on the hydrophobically modified poly(ethylene imines) and surfactants: Aggregation and catalysis

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Abstract

The aggregation in aqueous systems of hydrophobically modified poly(ethylene imines) and their mixtures with cationic surfactants, as well as the catalytic activity of these compositions in the hydrolysis of O-4-nitrophenyl-O-ethylchloromethylphosphonate, are studied by conductometry, tensiometry, light-scattering, and viscometry methods. Critical association concentration, hydrodynamic radii of polymer and polymer-colloid aggregates formed in such systems, as well as kinetic parameters of hydrolysis are determined.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Akademika Arbuzova 8, Kazan, 420088, Tatarstan, Russia

    S. S. Lukashenko, A. V. Yurina, T. N. Pashirova, D. B. Kudryavtsev, E. M. Kosacheva, L. A. Kudryavtseva & A. I. Konovalov

Authors
  1. S. S. Lukashenko
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  2. A. V. Yurina
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  3. T. N. Pashirova
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  4. D. B. Kudryavtsev
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  5. E. M. Kosacheva
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  6. L. A. Kudryavtseva
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  7. A. I. Konovalov
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Original Russian Text © S.S. Lukashenko, A.V. Yurina, T.N. Pashirova, D.B. Kudryavtsev, E.M. Kosacheva, L.A. Kudryavtseva, A.I. Konovalov, 2008, published in Kolloidnyi Zhurnal, 2008, Vol. 70, No. 3, pp. 351–361.

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Lukashenko, S.S., Yurina, A.V., Pashirova, T.N. et al. Systems based on the hydrophobically modified poly(ethylene imines) and surfactants: Aggregation and catalysis. Colloid J 70, 317–326 (2008). https://doi.org/10.1134/S1061933X08030095

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  • DOI: https://doi.org/10.1134/S1061933X08030095

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