Skip to main content
SpringerLink
Log in

Cu UPD at Pt(100) and stepped faces Pt(610), Pt(410) of platinum single crystal electrodes

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

The processes of adsorption/desorption of copper adatoms on the basal Pt(100) face and stepped Pt(610), Pt(410) surfaces have been studied in perchloric acid solution by cyclic voltammetry. It has been shown that the positions of the Cu stripping peaks are determined by perfection of the adlayer. The “island” model is suggested to describe electrochemical behavior of the Pt(hkl)+Cuad system. Obtained results are important for target modification of shape-controlled nanoparticles that are used in electrocatalysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Adzic, R., Advances in Electrochemistry and Electrochemical Engineering, Gerischer, H., Ed., N.Y.: Wiley and Sons, 1984, vol. 13, p. 159.

  2. Petrii, O.A. and Tsirlina, G.A., Itogi Nauki I Tekhmiki. Elektrokhimiya. Moscow: VINITI. 1988, vol. 27, p. 3.

    CAS  Google Scholar 

  3. De Groot, M.T. and Koper, M.T.M., J. Electroanal. Chem., 2004, vol. 562, p. 81.

    Article  Google Scholar 

  4. Petrii, O.A. and Safonova, T.Ya., J. Electroanal. Chem., 1992, vol. 331, p. 897.

    Article  CAS  Google Scholar 

  5. Safonova, T.Ya. and Petrii, O.A., J. Electroanal. Chem., 1998, vol. 448, p. 211.

    Article  CAS  Google Scholar 

  6. Gootzen, J.F.E., Peeters, P.G.J.M., Dukers, J.M.B., Lefferts, L., Visscher, W., and van Veen, J.A.R., J. Electroanal. Chem., 1997, vol. 434, p. 171.

    Article  CAS  Google Scholar 

  7. Gootzen, J.F.E., Lefferts, L., and van Veen, J.A.R., Appl. Catal. A: General, 1999, vol. 188, p. 127.

    Article  CAS  Google Scholar 

  8. De Vooys, A.C.A., van Santen, R.A., and van Veen, J.A.R., J. Mol. Catal., 2000, vol. 154, p. 203.

    Article  Google Scholar 

  9. Da Cunha, M.C.P.M., Weber, V., and Nart, F.C., J. Electroanal. Chem., 1996, vol. 414, p. 163.

    Google Scholar 

  10. Da Cunha, M.C.P.M., De Souza, J.P.I., and Nart, F.C., Langmuir, 2000, vol. 16, p. 771.

    Article  Google Scholar 

  11. Dima, G.E., de Vooys, A.C.A., and Koper, M.T.M., J. Electroanal. Chem., 2003, vols. 554–555, p. 15.

    Article  Google Scholar 

  12. Pletcher, D. and Poorabedi, Z., Electrochim. Acta, 1979, vol. 24, p. 1253.

    Article  CAS  Google Scholar 

  13. Dima, G.E., Rosca, V., and Koper, M.T.M., J. Electroanal. Chem., 2007, vol. 599, p. 167.

    Article  CAS  Google Scholar 

  14. Shimazu, K., Kawaguchi, T., and Tada, K., J. Electroanal. Chem., 2002, vol. 529, p. 20.

    Article  CAS  Google Scholar 

  15. Tada, K. and Shimazu, K., J. Electroanal. Chem., 2005, vol. 577, p. 303.

    Article  CAS  Google Scholar 

  16. Kerkeni, S., Lamy-Pitara, E., and Barbier, J., Catalysis Today, 2002, vol. 75, p. 35.

    Article  CAS  Google Scholar 

  17. El Omar, F. and Durand, R., J. Electroanal. Chem., 1984, vol. 178, p. 343.

    Article  Google Scholar 

  18. Markovic, N., Hanson, M., McDougall, G., and Yeager, E., J. Electroanal. Chem., 1986, vol. 214, p. 555.

    Article  CAS  Google Scholar 

  19. Dima, G.E., Beltramo, G.L., and Koper, M.T.M., Electrochim. Acta, 2005, vol. 50, p. 4318.

    Article  CAS  Google Scholar 

  20. Taguchi, S. and Feliu, J.M., Electrochim. Acta, 2007, vol. 52, p. 6023.

    Article  CAS  Google Scholar 

  21. Taguchi, S. and Feliu, J.M., Electrochim. Acta, 2008, vol. 53, p. 3626.

    Article  CAS  Google Scholar 

  22. Molodkina, E.B., Ehrenburg, M.R., Polukarov, Yu.M., Danilov, A.I., Souza-Garcia, J., and Feliu, J.M., Electrochim. Acta, 2010, vol. 56, p. 154.

    Article  CAS  Google Scholar 

  23. Gomez, R., Yee, H.S., Bommarito, G.M., Feliu, J.M., and Abruna, H.D., Surf. Sci., 1995, vol. 335, p. 101.

    Article  CAS  Google Scholar 

  24. Molodkina, E.B., Botryakova, I.G., Danilov, A.I., Souza-Garcia, J., and Feliu, J.M., Rus. J. Electrochem., 2012, vol. 48, p. 302.

    Article  CAS  Google Scholar 

  25. Molodkina, E.B., Botryakova, I.G., Danilov, A.I., Souza-Garcia, J., and Feliu, J.M., Rus. J. Electrochem., 2013, vol. 49, p. 285.

    Article  CAS  Google Scholar 

  26. Vidal-Iglesias, F.J., Solla-Gullon, J., Rodríguez, P., Herrero, E, Montiel, V., Feliu, J.M., and Aldaz, A., Electrochem. Commun., 2004, vol. 6, p. 1080.

    Article  CAS  Google Scholar 

  27. Vidal-Iglesias, F.J., Lopez-Cudero, A., Solla-Gullon, J., Aldaz, A., and Feliu, J.M., Electrocatal., 2012, vol. 3, p. 313.

    Article  CAS  Google Scholar 

  28. Solla-Gullon, J., Vidal-Iglesias, F.J., and Feliu, J.M., Annu. Rep. Prog. Chem., Sect. C, 2011, vol. 107, p. 263.

    Article  CAS  Google Scholar 

  29. Rudnev, A.V., Molodkina, E.B., Ehrenburg, M.R., Fedorov, R.G., Danilov, A.I., Polukarov, Yu.M., and Feliu, J.M., Rus. J. Electrochem., 2009, vol. 45, p. 1052.

    Article  CAS  Google Scholar 

  30. Gisbert, R., Climent, V., Herrero, E., and Feliu, J.M., J. Electrochem., 2012, vol. 18, p. 410.

    CAS  Google Scholar 

  31. Francke, R., Climent, V., Baltruschat, H., and Feliu, J.M., J. Electroanal. Chem., 2008, vol. 624, p. 228.

    Article  CAS  Google Scholar 

  32. Danilov, A.I., Molodkina, E.B., Rudnev, A.V., Polukarov, Yu. M., and Feliu, J.M., Electrochim. Acta, 2005, vol. 50, p. 5032.

    Article  CAS  Google Scholar 

  33. Danilov, A.I., Molodkina, E.B., Rudnev, A.V., Polukarov, Yu.M., Nazmutdinov, R.R., Zinkicheva, T.T., and Feliu, J.M., Rus. J. Electrochem., 2008, vol. 44, p. 697.

    Article  CAS  Google Scholar 

  34. Clavilier, J., Interfacial Electrochemistry. Theory, Experimental, and Applications, Wieckowski, A., Ed., N.Y.: Marcel Dekker, Inc., 1999, p. 231.

  35. Clavilier, J., Faure, R., Guinet, G., and Durand, R., J. Electroanal. Chem., 1980, vol. 107, p. 205.

    Article  CAS  Google Scholar 

  36. Clavilier, J., J. Electroanal. Chem., 1980, vol. 107, p. 211.

    Article  CAS  Google Scholar 

  37. Domke, K., Herrero, E., Rodes, A., and Feliu, J.M., J. Electroanal. Chem., 2003, vol. 552, p. 115.

    Article  CAS  Google Scholar 

  38. Kibler, L.A., Cuesta, A., Kleinert, M., and Kolb, D.M., J. Electroanal. Chem., 2000, vol. 484, p. 73.

    Article  CAS  Google Scholar 

  39. Danilov, A.I., Molodkina, E.B., Polukarov, Yu.M., Climent, V., and Feliu, J.M., Electrochim. Acta, 2001, vol. 46, p. 3137.

    Article  CAS  Google Scholar 

  40. Vidal-Iglesias, F.J., Solla-Gullon, J., Campina, J.M., Herrero, E., Aldaz, A., and Feliu, J.M., Electrochim. Acta, 2009, vol. 54, p. 4459.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    E. B. Molodkina & A. I. Danilov

  2. Institute of Electrochemistry, University of Alicante, Alicante, Spain

    J. M. Feliu

Authors
  1. E. B. Molodkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Danilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. M. Feliu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. I. Danilov.

Additional information

Published in Russian in Elektrokhimiya, 2016, Vol. 52, No. 9, pp. 999–1010.

The article was translated by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Molodkina, E.B., Danilov, A.I. & Feliu, J.M. Cu UPD at Pt(100) and stepped faces Pt(610), Pt(410) of platinum single crystal electrodes. Russ J Electrochem 52, 890–900 (2016). https://doi.org/10.1134/S1023193515110117

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193515110117

Keywords

Search

Navigation