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Intermolecular hydrogen bonding of polyiminosulfone

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Abstract

Molecular dynamics calculations were made of the distance from the hydrogen atom of the imino group to the oxygen atom of the sulfone group of polyiminosulfone (PIS). The results showed that theoretically there was hydrogen bond formation between the imino group and the sulfone group of PIS. The existence of the hydrogen bonding between the polymer chains of PIS was confirmed by infrared spectrum analysis. Due to the existence of the hydrogen bonding, PIS showed strong molecular interaction with a large cohesive energy density (CED), and a high glass transition temperature (282°C).

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Authors and Affiliations

  1. State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials & School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang, 621010, China

    Guanjun Chang, Li Yang & Xianpan Shi

  2. Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang, 621900, China

    Lin Zhang

  3. Engineering Research Center of High Performance Polymer and Molding Technology, Ministry of Education, Qingdao University of Science and Technology, Qingdao, 266042, China

    Runxiong Lin

Authors
  1. Guanjun Chang
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  2. Li Yang
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  3. Xianpan Shi
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  4. Lin Zhang
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  5. Runxiong Lin
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Correspondence to Guanjun Chang.

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Chang, G., Yang, L., Shi, X. et al. Intermolecular hydrogen bonding of polyiminosulfone. Polym. Sci. Ser. A 57, 251–255 (2015). https://doi.org/10.1134/S0965545X15020030

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  • DOI: https://doi.org/10.1134/S0965545X15020030

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