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Nickel-tungsten sulfide polyaromatic hydrocarbon hydrogenation nanocatalysts prepared in an ionic liquid

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Abstract

Nickel-tungsten sulfide nanocatalysts for the hydrogenation of aromatic hydrocarbons (HCs) have been prepared by the in situ decomposition of nickel thiotungstate precursors in an ionic liquid (IL) using the [BMPip]2Ni(WS4)2 nickel thiotungstate complex as a precursor and the thermally stable IL 1-butyl-1-methylpiperidinium trifluoromethanesulfonate BMPipCF3SO3 as a solvent for the precursor. The Ni-W-S particles in situ synthesized in the IL have been characterized by X-ray photoelectron spectroscopy and TEM. It has been shown that the particles are 0.5-nm-wide nanoplates associated in agglomerates with a diameter of 100–150 nm. Catalytic activity has been studied using the example of naphthalene hydrogenation in various solvents in a batch reactor at a temperature of 350°C and a pressure of 5.0 MPa. It has been shown that the IL can be used for the selective hydrogenation of aromatic HCs in a mixture with olefins.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    I. A. Sizova, S. I. Serdyukov & A. L. Maksimov

  2. Faculty of Chemistry, Moscow State University, Moscow, Russia

    S. I. Serdyukov, A. L. Maksimov & N. A. Sinikova

Authors
  1. I. A. Sizova
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  2. S. I. Serdyukov
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  3. A. L. Maksimov
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  4. N. A. Sinikova
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Correspondence to I. A. Sizova.

Additional information

Original Russian Text © I.A. Sizova, S.I. Serdyukov, A.L. Maksimov, N.A. Sinikova, 2015, published in Neftekhimiya, 2015, Vol. 55, No. 1, pp. 41–47.

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Sizova, I.A., Serdyukov, S.I., Maksimov, A.L. et al. Nickel-tungsten sulfide polyaromatic hydrocarbon hydrogenation nanocatalysts prepared in an ionic liquid. Pet. Chem. 55, 38–44 (2015). https://doi.org/10.1134/S0965544115010120

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  • DOI: https://doi.org/10.1134/S0965544115010120

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