Abstract
In the present study the solubility of glycine in aqueous sodium chloride and potassium chloride solution was determined under different experimental conditions using ‘formol titrimetry’ method. The thermodynamic parameters like standard transfer Gibbs energies and entropies have been evaluated at 298.15 K. Other important parameters like molar volume, densities, solvent diameter, etc., of the experimental solutions have also been determined in this study. The above mentioned parameters have been used to determine ∆ 0 t,ch (i)i.e., chemical effects of the transfer Gibbs energies and T∆ 0 t,ch (i)i.e., chemical effects of the transfer entropy. The solvation of glycine is influenced by different factors such as nature of the solute, interactions between solute and solvents, etc., which has been explained by different physical and analytical approach.
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References
V. Hippel et al., Structure of Stability of Biological Macromolecules (Marcel Dekker, New York, 1969).
C. B. Anfinsen and H. A. Seheraga, Adv. Protein. Chem. 29, 205 (1978).
J. F. Reading, I. D. Watson, and R. H. Gavin, J. Chem. Thermodyn. 22, 159 (1990).
S. Lapamje, in Physico-Chemical Aspects of Proteins Denaturation (Wiley Interscience, New York, 1978).
P. Das, S. Chatterjee, and I. N. Mallick, J. Chin. Chem. Soc. 51, 1 (2004).
T. S. Banipal, G. Singh, and B. S. Lark, J. Solution Chem. 30, 657 (2001).
M. N. Islam and R. K. Wadi, Phys. Chem. Liq. 39, 77 (2001).
K. Koseoglu, K. Esma, and H. C. Hang, Anal. Biochem. 277, 243 (2000).
K. Mahali, S. Roy, and B. K. Dolui, J. Biophys. Chem. 2, 185 (2011).
Y. Nozaki and C. Tanford, J. Boil. Chem. 238, 4074 (1963).
M. Abu-Hamdlyyah and A. Shehabuddin, J. Chem. Eng. Data 27, 74 (1982).
S. Roy, K. Mahali, and B. K. Dolui, Biochem. Ind. J. 3, 63 (2009).
S. Roy, K. Mahali, and B. K. Dolui, Biochem. Ind. J. 4, 71 (2010).
S. Roy, K. Mahali, S. Akhter, and B. K. Dolui, Asian J. Chem. 25, 6661 (2013).
S. Roy, K. Mahali, and B. K. Dolui, Asian J. Chem. 25, 8037 (2013).
K. Mahali, S. Roy, and B. K. Dolui, J. Solution Chem. 42, 1096 (2013).
S. Roy, K. Mahali, and B. K. Dolui, J. Solution Chem. 42, 1472 (2013).
R. G. Bates and S. F. Coetzee, Solute-Solvent Interactions (Marcel Dekker, New York, 1969).
R. Sinha, S. K. Bhattacharya, and K. K. Kundu, J. Mol. Liq. 122, 95 (2005).
S. C. Dutta and S. C. Lahiri, J. Ind. Chem. Soc. 72, 315 (1995).
J. I. Kim, A. Cocal, H. Born, and E. A. Comma, Phys. Chem. Neue Folge 110, 209 (1978).
Y. Marcus, Ion Solvation (Wiley, New York, 1985).
A. Bhattacharyya and S. K. Bhattacharyya, J. Solution Chem. 42, 2149 (2013).
http://en.wikipedia.org/wiki/Sodium_chlorid.
R. Sinha, S. K. Bhattacharya, and K. K. Kundu, J. Mol. Liq. 122, 95 (2005).
M. Hein, L. R. Best, S. Pattison, and S. Arena, College Chemistry: An Introduction to General, Organic and Biochemistry, 5th ed. (Brooks/Cole, Pacific Grove, 1993).
R. D. Lide, CRC Handbook of Chemistry and Physics, 85th ed. (CRC Press, Boca Raton, FL, 2004).
R. Carta, J. Chem. Thermodyn. 30, 379 (1998).
R. Carta and G. Tola, J. Chem. Eng. Data 41, 414 (1996).
M. K. Khoshkbarchi and J. H. Vera, Ind. Eng. Chem. Res. 36, 2445 (1997).
V. I. Smirnov and V. J. Badelin, Russ. J. Phys. Chem. A 87, 1793 (2013.
G. G. Gorboletova and A. A. Metlin, Russ. J. Phys. Chem. A 88, 1514 (2014).
T. R. Usacheva, K. I. Kuz’mina, Pham Thi Lan, I. A. Kuz’mina, and V. A. Sharnin, Russ. J. Phys. Chem. A 88, 1357 (2014).
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Roy, S., Hossain, A., Mahali, K. et al. Thermodynamics and mechanisms of glycine solvation in aqueous NaCl and KCl solutions at 298.15 K. Russ. J. Phys. Chem. 89, 2111–2119 (2015). https://doi.org/10.1134/S0036024415110151
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DOI: https://doi.org/10.1134/S0036024415110151