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Destruction of molybdenum nanocluster polyoxometallates in aqueous solutions

  • Physical Chemistry of Nanoclusters and Nanomaterials
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Abstract

The kinetics of the decomposition of nanocluster polyoxomolybdate (POM) with a keplerate structure Mo72Fe30 and toroidal POMs Mo138 in aqueous solutions was studied. The POM concentration was determined by spectrophotometry. The limiting stage of the destruction was concluded to be the decomposition of free keplerate molecules (ions) or the keplerates of aggregates (globules).

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Authors and Affiliations

  1. Research Institute of Physics and Applied Mathematics, Ural Federal University, Yekaterinburg, Russia

    A. A. Ostroushko & M. O. Tonkushina

  2. Institute of Immunology and Physiology, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    A. A. Ostroushko & M. O. Tonkushina

Authors
  1. A. A. Ostroushko
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  2. M. O. Tonkushina
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Correspondence to A. A. Ostroushko.

Additional information

Original Russian Text © A.A. Ostroushko, M.O. Tonkushina, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 3, pp. 440–443.

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Ostroushko, A.A., Tonkushina, M.O. Destruction of molybdenum nanocluster polyoxometallates in aqueous solutions. Russ. J. Phys. Chem. 89, 443–446 (2015). https://doi.org/10.1134/S003602441503022X

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  • DOI: https://doi.org/10.1134/S003602441503022X

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