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Thermodynamics of complexation of yttrium-family lanthanide ethylenediamine disuccinates at 298.15 K

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Abstract

Complexation between ethylenediamine-N,N'-disuccinic acid (Н4Y, EDDS) and Er3+, Yb3+, and Lu3+ ions in aqueous solutions is studied by calorimetry and pH measurements. The thermodynamic parameters (logK, ΔrG, ΔrH, and Δr S) of formation of LnY–and LnHY complexes at 298.15 K and ionic strength I = 0.5(KNO3) are determined. Changes in the thermodynamic parameters of reactions while moving along the lanthanide series are discussed.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, Ivanovo, Russia

    A. I. Lytkin, N. V. Chernyavskaya, A. S. Chernov & O. N. Krutova

  2. Kostroma State University, Kostroma, Russia

    V. E. Litvinenko

Authors
  1. A. I. Lytkin
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  2. N. V. Chernyavskaya
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  3. A. S. Chernov
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  4. O. N. Krutova
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  5. V. E. Litvinenko
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Correspondence to A. I. Lytkin.

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Original Russian Text © A.I. Lytkin, N.V. Chernyavskaya, A.S. Chernov, O.N. Krutova, V.E. Litvinenko, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 12, pp. 1683–1686.

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Lytkin, A.I., Chernyavskaya, N.V., Chernov, A.S. et al. Thermodynamics of complexation of yttrium-family lanthanide ethylenediamine disuccinates at 298.15 K. Russ. J. Inorg. Chem. 61, 1620–1623 (2016). https://doi.org/10.1134/S0036023616120111

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  • DOI: https://doi.org/10.1134/S0036023616120111

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