Abstract
The stable tetrahedra LiF–KBr–LiKMoO4–LiKWO4 and LiF–KBr–K2MoO4–K2WO4 of the quinary reciprocal system Li,K||F,Br,MoO4,WO4 were studied by differential thermal and X-ray powder diffraction analyses. It was determined that the tetrahedra contain no invariant points. Continuous series of solid solutions LiKMo x W1–x O4 and K2Mo x W1–x O4 do not decompose.
Similar content being viewed by others
References
Yu. M. Lakhtin and V. P. Leonova, Materials Science: A College Textbook (OOO Izdatel’stvo Al’yans, Moscow, 2011) [in Russian].
I. K. Garkushin, M. A. Sukharenko, and M. A. Demina, Physicochemical Analysis in Materials Science: A Textbook (SamGTU, Samara, 2014) [in Russian].
M. A. Radzikhovskaya (Sukharenko), I. K. Garkushin, and E. G. Danilushkina, Proceedings of the 19th Mendeleev Congress on General and Applied Chemistry, Volgograd, Russia, September 25–30, 2011 (VolgGTU, Volgograd, 2011), Vol. 4, p.93.
M. A. Radzikhovskaya (Sukharenko), I. K. Garkushin, and E. G. Danilushkina, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 56 (1), 55 (2013).
M. A. Radzikhovskaya (Sukharenko), I. K. Garkushin, and E. G. Danilushkina, Proceedings of the All-Russian Youth Conference “Chemistry under the Sigma Sign: Research, Innovation, Technology,” Kazan, Russia, July 2–4, 2012 (KNITU, Kazan, 2012), p.96.
M. A. Radzikhovskaya (Sukharenko), I. K. Garkushin, and E. G. Danilushkina, Kondens. Sredy Mezhfaz. Granitsy, 15, 34 (2013).
M. A. Radzikhovskaya (Sukharenko), I. K. Garkushin, and E. G. Danilushkina, Butlerov. Soobshch. 31 (8), 132 (2012).
I. K. Garkushin, M. A. Radzikhovskaia, and E. G. Danilushkina, Russ. J. Inorg. Chem. 59, 866 (2014).
E. G. Egortsev, I. K. Garkushin, and M. A. Istomova, Phase Equilibria and Chemical Interaction in Systems Containing Alkali Metal Fluorides and Bromides (UrO RAN, Yekaterinburg, 2008), p. 106 [in Russian].
M. A. Radzikhovskaya (Sukharenko), I. K. Garkushin, and E. G. Danilushkina, Izv. Saratov. Univ. Nov. Ser.: Khim. Biol. Ekol. 13 (1), 25 (2013).
I. K. Garkushin, M. A. Radzikhovskaya (Sukharenko), V. V. Molchanov, and T. A. Fedorova, Butlerov. Soobshch. 30 (4), 113 (2012).
M. A. Radzikhovskaya (Sukharenko), I. K. Garkushin, and E. G. Danilushkina, Izv. Saratov. Univ. Nov. Ser.: Khim. Biol. Ekol. 12 (2), 20 (2012).
O. Ore, Theory of Graphs (American Mathematical Society, Providence, RI, 1962).
I. K. Garkushin, M. V. Chugunova, and S. N. Milov, Formation of Continuous Series of Solid Solutions in Ternary and More-Component Salt Systems (UrO RAN, Yekaterinburg, 2011) [in Russian].
V. P. Egunov, Introduction to Thermal Analysis (Sam-Ven, Samara, 1997) [in Russian].
Thermal Constants of Substances: Handbook, Issue X, part 1: Tables of Accepted Values: Li, Na, Ed. by V. P. Glushko (VINITI, Moscow, 1981) [in Russian].
Thermal Constants of Substances: Handbook, Issue X, part 2: Tables of Accepted Values: K, Rb, Cs, Fr, Ed. by V. P. Glushko (VINITI, Moscow, 1981) [in Russian].
L. M. Kovba, X-ray Diffraction Analysis in Inorganic Chemistry (MGU, Moscow, 1991) [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.A. Sukharenko, I.K. Garkushin, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 4, pp. 541–548.
Rights and permissions
About this article
Cite this article
Sukharenko, M.A., Garkushin, I.K. Study of the stable tetrahedra LiF–KBr–LiKMoO4–LiKWO4 and LiF–KBr–K2MoO4–K2WO4 of the quinary reciprocal system Li,K∥F,Br,MoO4,WO4 . Russ. J. Inorg. Chem. 61, 518–525 (2016). https://doi.org/10.1134/S0036023616040197
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023616040197