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Structural, EPR spectroscopic, and magnetochemical study of hydrogen-bonded dimeric copper(II) complexes with hetaryl hydrazones

  • Physical Methods of Investigation
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Abstract

The copper(II) complexes [CuL1(NO3)] · CH3OH and [CuL2Cl] · CH3OH (L1 is 3,5-di-tert-butylsalicylal 1′-phthalazinyl hydrazone, and L2 is 2-N-tosylaminobenzal 2-imidazolinyl hydrazone) forming hydrogen-bonded dimers in a crystal were synthesized. A weak antiferromagnetic exchange interaction transmitted through extensive linkers incorporating the N–H···O hydrogen bond (2J is–3.0 and–2.6 cm–1, respectively) was recognized by EPR spectroscopy and low-temperature magnetochemistry.

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References

  1. L. D. Popov, I. N. Shcherbakov, Yu. P. Tupolova, et al., Usp. Khim. 78, 697 (2009).

    Article  Google Scholar 

  2. A.-M. Stadler and J. Harrowfild, Inorg. Chim. Acta 362, 4298 (2009).

    Article  CAS  Google Scholar 

  3. V. I. Ovcharenko and R. Z. Sagdeev, Usp. Khim. 68, 381 (1999).

    Article  Google Scholar 

  4. O. Kahn, Acc. Chem. Res. 33, 647 (2000).

    Article  CAS  Google Scholar 

  5. M. N. Leuenberger and D. Loss, Nature 410, 789 (2001).

    Article  CAS  Google Scholar 

  6. V. A. Kogan, V. V. Lukov, and I. N. Shcherbakov, Koord. Khim. 36, 401 (2010).

    Article  CAS  Google Scholar 

  7. Yu. E. Alexeev, B. I. Kharisov, Garcia T. C. Hernandez, et al., Coord Chem. Rev. 254, 794 (2010).

    Article  CAS  Google Scholar 

  8. S. Shit, S. K. Dey, C. Rizzoli, et al., Inorg. Chim. Acta 370 (1), 18 (2011).

    Article  CAS  Google Scholar 

  9. W. Plass, A. Pohlmann, and J. Rautengarten, Angew. Chem., Int. Ed. Engl. 40, 4207 (2001).

    Article  CAS  Google Scholar 

  10. S. Vaskova, J. Moncol, M. Korabik, et al., Polyhedron 29 (1), 154 (2010).

    Article  CAS  Google Scholar 

  11. J. S. Costa N. A. G. Bandeira, B. Le Guennic, et al., Inorg. Chem. 50, 5696 (2011).

    Article  CAS  Google Scholar 

  12. S. I. Levchenkov, I. N. Shcherbakov, L. D. Popov, et al., Inorg. Chim. Acta 405, 169 (2013).

    Article  CAS  Google Scholar 

  13. S. I. Levchenkov, L. D. Popov, I. N. Shcherbakov, et al., Zh. Strukt. Khim. 54, 914 (2013).

    Google Scholar 

  14. L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, et al., Zh. Obshch. Khim. 84, 596 (2014).

    Google Scholar 

  15. Bruker APEX2 Software Package AXS (Bruker, 2005).

  16. G. M. Sheldrik, SADABS: Program for Scanning and Correction of Area Detector Data (Göttingen Univ. Göttingen, 2004).

    Google Scholar 

  17. G. M. Sheldrick, Acta Crystallogr., Sect. A 64, 112 (2008).

    Article  CAS  Google Scholar 

  18. A. L. Spek, J. Appl. Crystallogr. 36, 7 (2003).

    Article  CAS  Google Scholar 

  19. L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, et al., Koord. Khim. 39, 259 (2013).

    Google Scholar 

  20. D. A. Garnovskii, A. S. Antsyshkina, A. V. Churakov, et al., Russ. J. Inorg. Chem. 59, 431 (2014).

    Article  CAS  Google Scholar 

  21. Yu. V. Rakitin, G. M. Larin, and V. V. Minin, The Interpretation of EPR Spectra of Coordination Compounds (Nauka, Moscow, 1993) [in Russian].

    Google Scholar 

  22. Ya. S. Lebedev and V. I. Muromtsev, EPR and Relaxation of Stabilized Radicals (Khimiya, Moscow, 1972) [in Russian].

    Google Scholar 

  23. V. F. Shul’gin, Yu. V. Trush, and O. V. Konnik, et al., Russ. J. Inorg. Chem. 56, 707 (2011).

    Article  Google Scholar 

  24. G. M. Larin, V. V. Minin, and V. F. Shul’gin, Usp. Khim. 77, 476 (2008).

    Article  Google Scholar 

  25. O. Kahn, Molecular Magnetism (VCH Publishers, New York, 1993).

    Google Scholar 

  26. B. Bleaney and K. D. Bowers, Proc. R. Soc. London A 214, 451, (1952).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Southern Scientific Center, Russian Academy of Sciences, ul. Chekhova 41, Rostov-on-Don, 344006, Russia

    S. I. Levchenkov

  2. Southern Federal University, ul. Bolshaya Sadovaya 105/42, Rostov-on-Don, 344006, Russia

    L. D. Popov, I. N. Shcherbakov, A. M. Ionov & V. A. Kogan

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    N. N. Efimov, V. V. Minin, E. A. Ugolkova & G. G. Aleksandrov

  4. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    Z. A. Starikova

Authors
  1. S. I. Levchenkov
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  2. L. D. Popov
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  3. N. N. Efimov
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  4. V. V. Minin
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  5. E. A. Ugolkova
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  6. G. G. Aleksandrov
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  7. Z. A. Starikova
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  8. I. N. Shcherbakov
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  9. A. M. Ionov
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  10. V. A. Kogan
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Corresponding author

Correspondence to S. I. Levchenkov.

Additional information

Original Russian Text © S.I. Levchenkov, L.D. Popov, N.N. Efimov, V.V. Minin, E.A. Ugolkova, G.G. Aleksandrov, Z.A. Starikova, I.N. Shcherbakov, A.M. Ionov, V.A. Kogan, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 9, pp. 1238–1246.

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Levchenkov, S.I., Popov, L.D., Efimov, N.N. et al. Structural, EPR spectroscopic, and magnetochemical study of hydrogen-bonded dimeric copper(II) complexes with hetaryl hydrazones. Russ. J. Inorg. Chem. 60, 1129–1136 (2015). https://doi.org/10.1134/S0036023615040129

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  • DOI: https://doi.org/10.1134/S0036023615040129

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