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Magnetic properties and structure of nanocrystalline FINEMET alloys with various iron contents

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Abstract

The effect of the composition and annealing temperature on the structure and magnetic properties of soft magnetic nanocrystalline Fe-Cu-Nb-Mo-Si-B alloys has been studied. An increase in the iron content compared to that in the traditional FINEMET alloy is shown to allow one to increase the magnetic induction by 18% at a coercive force of no less than 6 A/m. It has been found that, along with the amorphous phase, rapidly quenched ribbons of alloys enriched in Fe contain crystalline α-Fe-based phase precipitates, the (100) crystallographic directions of which are perpendicular to the ribbon plane. Thermomagnetic analysis and differential scanning calorimetry were used to determine the temperatures of structural and magnetic phase transformations of the alloys with different iron contents. It was found that the separation of amorphous phase into areas of different compositions precedes the precipitation of nano-sized soft magnetic Fe-Si phase grains in the rapidly quenched iron-enriched ribbons.

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References

  1. Y. Yoshizawa, S. Oguma, and Y. Yamaguchi, “New Fe-based soft magnetic alloys composed of ultrafine grain structure,” J. Appl. Phys. 64, 6044–6046 (1988).

    Article  Google Scholar 

  2. Y. Yoshizawa, “Magnetic properties and microstructure of nanocrystalline Fe-based alloys,” Mater. Sci. Forum 307, 51–62 (1999).

    Article  Google Scholar 

  3. G. Herzer, “Modern soft magnets: Amorphous and nanocrystalline materials,” Acta Mater. 61, 718–734 (2013).

    Article  Google Scholar 

  4. K. Suzuki and G. Herzer, “Magnetic-field-induced anisotropies and exchange softening in Fe-rich nanocrystalline soft magnetic alloys,” Scr. Mater. 67, 548–553 (2012).

    Article  Google Scholar 

  5. M. Ohta and Y. Yoshizawa, “Magnetic properties of nanocrystalline Fe82.65Cu1.35SixB16 − x alloys (x =0–7),” Appl. Phys. Lett. 91, 062517–062518 (2007).

    Article  Google Scholar 

  6. V. V. Serikov, N. M. Kleinerman, E. G. Volkova, V. A. Lukshina, A. P. Potapov, and A. V. Svalov, “Structure and magnetic properties of nanocrystalline FeCuNbSiB alloys after a thermomechanical treatment,” Phys. Met. Metallogr. 102, 268–273 (2006).

    Article  Google Scholar 

  7. N. I. Noskova, V. V. Shulika, and A. P. Potapov, “Nanocrystalline alloys with high magnetic properties and high temperature stability,” Funct. Mater. 17, 171–176 (2010).

    Google Scholar 

  8. B. N. Filippov, V. V. Shulika, A. P. Potapov, and N. F. Vil’danova, “Magnetic properties and temperature stability of a molybdenum-doped Finemet-type alloy,” Tech. Phys. 59, 373–377 (2014).

    Article  Google Scholar 

  9. N. V. Dmitrieva, V. A. Lukshina, E. G. Volkova, A. P. Potapov, V. S. Gaviko, and B. N. Filippov, “Fe- and Co-based nanocrystalline soft magnetic alloys modified with Hf, Mo, and Zr: Magnetic properties, thermal stability, and structure. Alloys (Fe0.6Co0.4)86Hf7B6Cu1 and (Fe0.7Co0.3)88Hf7B4Cu1,” Phys. Met. Metallogr. 114, 129–137 (2013).

    Article  Google Scholar 

  10. N. V. Dmitrieva, V. A. Lukshina, E. G. Volkova, A. P. Potapov, B. N. Filippov, and D. A. Shishkin, “Magnetic properties, thermal stability, and structure of the nanocrystalline soft magnetic (Fe0.7Co0.3)88Hf2W2Mo2Zr1B4Cu1 alloy with induced magnetic anisotropy,” Phys. Met. Metallogr. 115, 326–334 (2014).

    Article  Google Scholar 

  11. Y. R. Zhang and R. V. Ramanujan, “A study of the crystallization behavior of an amorphous Fe77.5Si13.5B9 alloy,” Mater. Sci. Eng., A 416, 161–168 (2006).

    Article  Google Scholar 

  12. H. Okumura, D. E. Laughlin, and M. E. McHenry, “Magnetic and structural properties and crystallization behavior of Si-rich FINEMET materials,” J. Magn. Magn. Mater. 267, 347–356 (2003).

    Article  Google Scholar 

  13. J. Chen, J. Hu, H. Quin, Z. Zhang, Z. Zhao, and B. Li, “Magnetic properties of Fe77.5 − x Si13.5B9Cux as-cast ribbons,” Mater. Trans. 51, 58–61 (2010).

    Article  Google Scholar 

  14. M. Ohta and Y. Yoshizawa, “New High-B, Fe-based nanocrystalline soft magnetic alloys,” Jpn. J. Appl. Phys. 46, L477–L479 (2007).

    Article  Google Scholar 

  15. G. Bertotti and F. Fiorillo, 7.1.2.3.1 Saturation Magnetization and Curie Temperature, Ed. by H. P. J. Wijn (Springer-Verlag, Landolt-Börnstein Database. DOI:10.1007/10065028-15. http://www.springermaterials.com

  16. T. Nakajima, E. Kita, and H. Ino, “Crystallization process and magnetic properties of Fel00 − x Bx (10 < x < 35) amorphous alloys and supersaturated state of boron in α-Fe,” J. Mater. Sci. 23, 1279–1288 (1988).

    Article  Google Scholar 

  17. G. E. Abrosimova, “Evolution of the structure of amorphous alloys,” Phys.-Usp. 54, 1227–1242 (2011).

    Article  Google Scholar 

  18. V. V. Serikov, N. M. Kleinerman, A. V. Vershinin, N. V. Mushnikov, A. V. Protasov, L. A. Stashkova, O. I. Gorbatov, A. V. Ruban, and Yu. N. Gornostyrev, “Formation of solid solutions of gallium in Fe-Cr and Fe-Co alloys: Mössbauer studies and first-principles calculations,” J. Alloys Compd. 614, 297–304 (2014).

    Article  Google Scholar 

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Correspondence to N. V. Mushnikov.

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Original Russian Text © N.V. Mushnikov, A.P. Potapov, D.A. Shishkin, A.V. Protasov, O.A. Golovnya, N.N. Shchegoleva, V.S. Gaviko, K.Yu. Shunyaev, V.A. Bykov, Yu.N. Starodubtsev, V.Ya. Belozerov, 2015, published in Fizika Metallov i Metallovedenie, 2015, Vol. 116, No. 7, pp. 701–708.

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Mushnikov, N.V., Potapov, A.P., Shishkin, D.A. et al. Magnetic properties and structure of nanocrystalline FINEMET alloys with various iron contents. Phys. Metals Metallogr. 116, 663–670 (2015). https://doi.org/10.1134/S0031918X15070108

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  • DOI: https://doi.org/10.1134/S0031918X15070108

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