Abstract
Luminescent properties of magnesium tungstate monocrystals grown by two different methods are studied. Only the exciton luminescence of these crystals themselves is observed. Temperature dependence of the low-energy range in the luminescence excitation spectra is described by the Urbach rule. Slope coefficient σ0 = 0.74 obtained from this dependence implies autolocalization of the excitons in MgWO4. The processes of electronic excitations relaxation are considered depending on the structure of valence band in MgWO4 and in other wolframites, ZnWO4 and CdWO4. In contrast to ZnWO4 and CdWO4, the d-states of the cation do not participate in formation of the MgWO4 valence band. Using the excitation spectra measured in the range of the fundamental absorption (4–20 eV), it is shown that this difference manifests itself in relaxation of electronic excitations and may be the cause of the relatively low light yield of MgWO4.
Similar content being viewed by others
References
Phosphor Handbook, Ed. under the Auspices of the Phosphor Res. Soc. (CRC, Boca Raton, FL, 1999).
Chr. C. Vlam, Physica 15, 609 (1949).
C. E. Tyner and H. G. Drickamer, J. Chem. Phys. 67, 4103 (1977).
F. A. Danevich, D. M. Chernyak, A. M. Dubovik, B. V. Grinyov, S. Henry, H. Kraus, V. M. Kudovbenko, V. B. Mikhailik, L. L. Nagornaya, R. B. Podviyanuk, O. G. Polischuk, I. A. Tupitsyna, and Yu. Ya. Vostretsov, Nucl. Instrum. Methods Phys. Res. A 608, 107 (2009).
V. B. Mikhailik, H. Kraus, V. Kapustyanyk, M. Panasyuk, Yu. Prots, V. Tsybulskyi, and L. Vasylechko, J. Phys.: Condens. Matter 20, 365219 (2008).
L. Y. Chang Luke, M. G. Scroger, and B. Phillips, J. Am. Ceram. Soc. 49, 385 (1966).
L. L. Nagornaya, F. A. Danevich, A. M. Dubovik, B. V. Grinyov, S. Henry, V. Kapustyanyk, H. Kraus, D. V. Poda, V. M. Kudovbenko, V. B. Mikhailik, M. Panasyuk, O. G. Polischuk, V. Rudyk, V. Tsybulskyi, I. A. Tupitsyna, and Yu. Ya. Vostretsov, IEEE Trans. Nucl. Sci. 56, 2513 (2009).
V. B. Mikhailik and H. Kraus, Phys. Status Solidi B 247, 1583 (2010).
G. Zimmerer, Rad. Meas 42, 859 (2007).
V. N. Kolobanov, I. A. Kamenskikh, V. V. Mikhailin, I. N. Shpinkov, D. A. Spassky, B. I. Zadneprovsky, L. I. Potkin, and G. Zimmerer, Nucl. Instrum. Methods Phys. Res. A 486, 496 (2002).
A. E. Ovechkin, V. D. Ryzhikov, G. Tamulaitis, and A. Žukauskas, Phys. Status Solidi A 103, 285 (1987).
G. Blasse, G. J. Dirksen, M. Hazenkamp, and J. R. Gunter, Mater. Res. Bull. 22, 813 (1987).
D. Spassky, A. Vasil’ev, I. Kamenskikh, V. Kolobanov, V. Mikhailin, A. Savon, L. Ivleva, I. Voronina, and L. Berezovskaya, Phys. Status Solidi A 206, 1579 (2009).
K. S. Song and R. T. Williams, Self-Trapped Excitons (Springer, Berlin, 1996).
V. Nagirnyi, M. Kirm, A. Kotlov, A. Lushchik, and L. Jonsson, J. Lumin. 102–103, 597 (2003).
V. Nagirnyi, P. Dorenbos, E. Feldbach, L. Jonsson, M. Kerikmae, M. Kirm, E. van der Kolk, A. Kotlov, H. Kraus, A. Lushchik, V. Mikhailik, R. Sarakvasha, and A. Watterich, in Proceedings of the 8th International Conference on Inorganic Scintillators and Their Use in Scientific and Industrial Applications, SCINT 2005, Alushta, Ukraine, 2005, p. 36.
N. R. Krutyak, V. V. Mikhailin, D. A. Spassky, V. N. Kolobanov, M. B. Kosmyna, B. P. Nazarenko, V. M. Puzikov, and A. N. Shekhovtsov, J. Appl. Spectrosc. 79, 211 (2012).
N. R. Krutyak, V. V. Mikhailin, A. N. Vasil’ev, D. A. Spassky, I. A. Tupitsyna, E. N. Galashov, V. N. Shlegel, and A. N. Belsky, J. Lumin. 144, 105 (2013).
A. Watterich, L. Kovacs, R. Wurz, F. Schon, A. Hofstaetter, and A. Scharmann, J. Phys.: Condens. Matter 13, 1595 (2001).
D. W. Kim, In-Sun. Cho, S. S. Shin, S. Lee, T. H. Noh, D. H. Kim, H. S. Jung, and K. S. Hong, J. Solid State Chem. 184, 2103 (2011).
M. Nikl, Meas. Sci. Technol. 17, R37 (2006).
A. N. Vasil’ev and V. V. Mikhailin, Introduction to Spectroscopy of Dielectrics. Pt. II: Secondary Processes (KDU, Moscow, 2010) [in Russian].
O. V. Rzhevskaya, D. A. Spassky, V. N. Kolobanov, V. V. Mikhailin, L. L. Nagornaya, I. A. Tupitsyna, and B. I. Zadneprovskii, Opt. Spectrosc. 104, 366 (2008).
F. P. Emmenegger and H. Roetschi, J. Phys. Chem. Solids 32, 787 (1971).
J. Ruiz-Fuertes, S. López-Moreno, J. López-Solano, D. Errandonea, A. Segura, R. Lacomba-Perales, A. Munoz, S. Radescu, P. Rodriguez-Hernandez, M. Gospodinov, L. L. Nagornaya, and C. Y. Tu, Phys. Rev. B 86, 125202 (2012).
O. Y. Khyzhun, V. L. Bekenev, V. V. Atuchin, E. N. Galashov, and V. N. Shlegel, Mater. Chem. Phys. 140, 588 (2013).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.R. Krutyak, D.A. Spassky, I.A. Tupitsyna, A.M. Dubovik, 2016, published in Optika i Spektroskopiya, 2016, Vol. 121, No. 1, pp. 50–57.
Rights and permissions
About this article
Cite this article
Krutyak, N.R., Spassky, D.A., Tupitsyna, I.A. et al. Influence of peculiarities of electronic excitation relaxation on luminescent properties of MgWO4 . Opt. Spectrosc. 121, 45–51 (2016). https://doi.org/10.1134/S0030400X16070122
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0030400X16070122