Abstract
The vibrational structure of the spectra of fluorescence of anthracene obtained upon resonance excitation of vibronic states is calculated and analyzed by the parametric method of the theory of the vibronic spectra of complex molecules. The theoretical and experimental spectra agree qualitatively with each other, which indicates that this method of modeling such spectra is efficient. The parameterization of molecular models obtained upon calculation of the ordinary fluorescence and absorption spectra is completely applicable to the calculation of the fluorescence spectra considered. A total interpretation of the spectra is presented.
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Original Russian Text © V.I. Baranov, A.N. Solov’ev, 2006, published in Optika i Spektroskopiya, 2006, Vol. 100, No. 2, pp. 226–233.
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Baranov, V.I., Solov’ev, A.N. Calculation and interpretation of the fine structure fluorescence spectra of anthracene upon resonance excitation of vibronic states. Opt. Spectrosc. 100, 192–199 (2006). https://doi.org/10.1134/S0030400X0602007X
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DOI: https://doi.org/10.1134/S0030400X0602007X