Abstract
The study of “productive” intervals of the Gremyachinsk potash deposit showed that the precipitation of potassic and potassic–magnesium salts was accompanied by large-scale desalting of sodium chloride owing to the interaction of concentrated solutions from the given part of the saliferous basin with diluted solutions. The constant influx of diluted brine was characterized by the high content of sodium chloride, which led to the large-scale precipitation of halite as lenses, crusts, and accumulations of random morphology. Based on the ultramicrochemical analysis of the composition of brine inclusions in halites of different stages of densification, it is suggested that this process was accompanied by the growth of K ion concentrations in the brine and the subsequent desalting of potassium chloride in the carnallite stage brine with the formation of rocks of the carnallite–sylvinite paragenesis.
Similar content being viewed by others
References
Fiveg, M.P. and Banera, N.I., Paleogeography of the Kungurian salt accumulation in the eastern Russian Platform and Uralian foredeep, Litol. Polezn. Iskop., 1968, no. 1, pp. 33–43.
Kovalevich, V.M., Fiziko-khimicheskie usloviya formirovaniya solei Stebnikskogo kaliinogo mestorozhdeniya (Physicochemical Conditions of Salt Formation in the Stebnik Potassium Deposit), Kiev: Naukova Dumka, 1978.
Moskovskii, G.A. and Goncharenko, O.P., Osnovnye cherty geokhimii kungurskogo galogeneza v zapadnoi chasti Prikaspiiskoi vpadiny (po vklyucheniyam v mineralakh) (Main features of the geochemistry of the Kungurian halogenesis in the western Caspian depression: Evidence from fluid inclusions in minerals) Available from VINITI, 1989, Moscow, no. 4072.
Moskovskii, G.A. and Goncharenko, O.P., Permskii galogenez Prikaspiya (Permian Halogenesis in the Caspian Region), Saratov: Nauchn. Kniga, 2004, part 2 (Hydrochemistry of Final Stages and Conditions of the Postsedimentary Transformation of Salts).
Moskovskii, G.A., Goncharenko, O.P., Svidzinskii, S.A., and Pisarenko, Yu.A., Permskii galogenez Prikaspiya (The Permian Halogenesis in the Caspian Region), Saratov: Nauchn. Kniga, 2003, part 1 (Hydrochemistry of the Halite Stage).
Pauling, L., General Chemistry, London: Pitman, 1971. Published under the title Obshchaya khimiya, Karapet’yants, M.Kh, Ed., Moscow: Mir, 1974.
Petrichenko, O.I., Fluid inclusions in minerals as a source of information about the conditions of salt formation, in Geologiya i poleznye iskopaemye solenosnykh tolshch (Geology and fossil minerals in saliferous rocks), Kiev: Naukova Dumka, 1974, pp. 70–73.
Raup, O., Mixing of brines: one more mechanism of the deposition of sedimentary sulfates and chlorides, in Trudy Pervogo Mezhdunarodnogo geokhimicheskogo kongressa (Proc. First Int. Geochem. Congr.), Moscow, 1973, vol. 4, part 1, pp. 369–396.
Solovkin, A.S., Vysalivanie i kolichestvennoe opisanie ekstraktsionnykh ravnovesii (Desalting and Quantitative Description of Extraction Equilibriums), Moscow: Atomizdat, 1969.
Valyashko, M.G., Geokhimicheskie zakonomernosti formirovaniya mestorozhdenii kaliinykh solei (Geochemical Regularities of the Formation of Potassium Salt Deposits), Moscow: MGU, 1962.
Valyashko, M.G., Bromine in salt deposits and brines as geochemical indicator in the study of salt deposits, in Brom v solyanykh otlozheniyakh i rassolakh (Bromine in Salt Deposits and Brines), Moscow: MGU, 1976, pp. 5–9.
Zherebtsova, I.K., Zolotareva, V.A., and Panteleeva, O.D., Geochemical features of the formation of salt deposits in the northern Volga monocline, in Fiziko-khimicheskie zakonomernosti osadkonakopleniya v solerodnykh basseinakh (Physicochemical Regularities of Sedimentation in Halogenic Basins), Moscow: Nauka, 1986, pp. 21–34.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © G.A. Moskovskii, O.P. Goncharenko, K.K. Ilin, 2016, published in Litologiya i Poleznye Iskopaemye, 2016, No. 1, pp. 95–100.
Rights and permissions
About this article
Cite this article
Moskovskii, G.A., Goncharenko, O.P. & Ilin, K.K. Desalting of sodium and potassium chlorides at the final stages of halogenesis: Evidence from the Gremyachinsk potash deposit in the Caspian basin. Lithol Miner Resour 51, 86–91 (2016). https://doi.org/10.1134/S0024490216010041
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0024490216010041