Skip to main content
SpringerLink
Log in

Crystal structure of nitrate tris(4-allylthiosemicarbazide)-chromium(III) hydrate

  • Brief Communications
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The crystal structure of nitrate tris(4-allylthiosemicarbazide)chromium(III) hydrate [CrL3](NO3)3(H2O)1.05 (I), where L is 4-allylthiosemicarbazide, is determined. The asymmetric unit of the cell of the crystal structure of I contains a complex of a chromium ion with three bidentate coordinated molecules L. The outer coordination sphere of the central atom contains a disordered water molecule and three nitrate ions. The coordination polyhedron of the chromium atom in complex I is an octahedron. In the crystal, the complexes of the compound under study are joined with each other by the outer-sphere nitrato groups into a three-dimensional branched net of hydrogen bonds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. M. Leovac, L. S. Jovanovic, V. Divjakovic, et al., Polyhedron, 26, 49 (2007).

    Article  CAS  Google Scholar 

  2. P. F. Rapheal, E. Manoj, M. R. Prathapachandra Kurup, and E. Suresh, Polyhedron, 26, 607 (2007).

    Article  CAS  Google Scholar 

  3. C.-Y. Duan, Y.-P. Tian, C.-Y. Zhao, X.-Z. You, and T. C. W. Mak, Polyhedron, 16, 2857 (1997).

    Article  CAS  Google Scholar 

  4. V. Vrdoljak, M. Cindric, D. Milic, D. Matkovic-Calogovic, P. Novak, and B. Kamenar, Polyhedron, 24, 1717 (2005).

    Article  CAS  Google Scholar 

  5. CrysAlisPro, Version 1.171.33.52 (release 06-11-2009 CrysAlis171.NET), Oxford Diffraction Ltd.

  6. G. M. Sheldrich, Acta Crystallogr., Sect. A, 64, 112 (2008).

    Article  Google Scholar 

  7. A. L. Spek, J. Appl. Crystallogr., 36, 7 (2003).

    Article  CAS  Google Scholar 

  8. I. J. Bruno, J. C. Cole, P. R. Edginton, et al., Acta Crystallogr., Sect. B, 58, 389 (2002).

    Article  Google Scholar 

  9. F. H. Allen, Acta Crystallogr., Sect. B, 58, 380 (2002).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Applied Physics of Academy of Sciences of Moldova, Chisinau, Moldova

    Yu. M. Chumakov & P. A. Petrenko

  2. Moldova State University, Chisinau, Moldova

    V. O. Graur, V. I. Tsapkov & A. P. Gulea

  3. Gebze Institute of Technology, Cayirova, Kocaeli, Turkey

    Yu. M. Chumakov

Authors
  1. Yu. M. Chumakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. A. Petrenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. O. Graur
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. I. Tsapkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. P. Gulea
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. I. Tsapkov.

Additional information

Original Russian Text © 2016 Yu. M. Chumakov, P. A. Petrenko, V. O. Graur, V. I. Tsapkov, A. P. Gulea.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chumakov, Y.M., Petrenko, P.A., Graur, V.O. et al. Crystal structure of nitrate tris(4-allylthiosemicarbazide)-chromium(III) hydrate. J Struct Chem 57, 202–205 (2016). https://doi.org/10.1134/S0022476616010261

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476616010261

Keywords

Search

Navigation