Abstract
The cluster complex of the composition trans-[{Re6S8}(pyz)4I2]· 2pyz (pyz is pyrazine) is obtained by the reaction of Cs4[{Re6S8}I6] with molten pyrazine. The compound crystallizes in the triclinic space group \(P\bar 1\) with the following unit cell parameters: a = 9.0562(7) Å, b = 10.2502(7) Å, c = 12.6783(9) Å, α = 98.537(3)°, β = 107.573(2)°, γ = 106.943(3)°, V = 1036.6(1) Å3, Z = 1, d calc = 3.377 g/cm3. The crystal structure is built of trans-[{Re6S8}(pyz)4I2] cluster complexes and uncoordinated pyrazine molecules.
This is a preview of subscription content, log in via an institution to check access.
References
T. Yoshimura, K. Umakoshi, Y. Sasaki, et al., Inorg. Chem., 38, No. 24, 5557–5564 (1999).
J.-C. P. Gabriel, K. Boubekeur, S. Uriel, et al., Chem. Rev., 101, No. 7, 2037–2066 (2001).
T. Yoshimura, C. Suo, K. Tsuge, et al., Inorg. Chem., 49, No. 2, 531–540 (2010).
APEX2 (Version 1.08), SAINT (Version 7.03), SADABS (Version 2.11), SHELXTL (Version 6.12), Bruker AXS Inc., Madison, Wisconsin, USA (2004).
T. Yoshimura, K. Umakoshi, Y. Sasaki, et al., Inorg. Chem., 39, No. 8, 1765–1772 (2000).
M. A. Shestopalov, S. Cordier, O. Hernandez, et al., Inorg. Chem., 48, No. 4, 1482–1489 (2009).
M. A. Shestopalov, Y. V. Mironov, K. A. Brylev, et al., J. Am. Chem. Soc., 129, No. 12, 3714–3721 (2007).
M. A. Shestopalov, Yu. V. Mironov, K. A. Brylev, et al., Russ. Chem. Bull., 57, No. 8, 1614–1619 (2008).
M. W. Willer, J. R. Long, C. C. McLauchlan, et al., Inorg. Chem., 37, No. 2, 328–333 (1998).
Z. Zheng, J. R. Long, and R. H. Holm, J. Am. Chem. Soc., 119, No. 9, 2163–2171 (1997).
Z.-N. Chen, T. Yoshimura, M. Abe, et al., Chem. Eur. J., 7, No. 20, 4447–4455 (2001).
F. Dorson, Y. Molard, S. Cordier, et al., Dalton Trans., No. 8, 1297–1299 (2009).
Y. V. Mironov, K. A. Brylev, S.-J. Kim, et al., Inorg. Chim. Acta, 370, No. 1, 363–368 (2011).
A. Yu. Ledneva, N. G. Naumov, A. V. Virovets, et al., J. Struct. Chem., 53, No. 1, 132–137 (2012).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2014 M. A. Shestopalov, A. A. Ivanov, A. I. Smolentsev, Yu. V. Mironov.
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 1, pp. 144–146, January–February, 2014.
Rights and permissions
About this article
Cite this article
Shestopalov, M.A., Ivanov, A.A., Smolentsev, A.I. et al. Crystal structure of the octahedral cluster complex trans-[{Re6S8}(pyz)4I2]·2pyz. J Struct Chem 55, 139–141 (2014). https://doi.org/10.1134/S0022476614010235
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476614010235