Abstract
The results of the neutron diffraction study of liquid gallium on the DIN-2PI spectrometer (IBR-2 reactor, JINR, Dubna) have been discussed. The analysis of the experimental data has provided temperature dependences of diffusion and relaxation characteristics of liquid gallium in the temperature range of 313–793 K. It has been found that an increase in the temperature is accompanied by the gradual deviation of the temperature dependence of the self-diffusion coefficient from the known dependences obtained from the data on viscosity. Such a behavior is explained by the beginning clustering of liquid gallium induced by the prevailing covalent character of interatomic bonds.
Similar content being viewed by others
References
Yu. A. Kurachenko, N. K. Voznesenskii, A. A. Goverdovskii, and V. I. Rachkov, Med. Fiz. 2, 29 (2012).
M. C. Bellissent-Funel, P. Chieux, D. Levesque, and J. Weis, Phys. Rev. A 12, 6310 (1989).
I. Padureanu, A. Radulescu, A. Novikov, V. V. Savostin, and Zh. A. Kozlov, J. Rom. Phys. 48, 97 (2003).
S. Hosokawa, W.-C. Pilgrim, H. Sinn, and E. Alp, J. Phys.: Condens. Matter 20, 114107 (2008).
X. Gong, G. Chiarotti, M. Parrinello, and E. Tosatti, Europhys. Lett. 21, 469 (1993).
K. H. Tsai, T.-M. Wu, and Sh.-F. Tsay, J. Chem. Phys. 132, 034502 (2010).
L. Bove, F. Formisano, F. Sacchetti, C. Petrillo, A. Ivanov, B. Dorner, and F. Barocchi, Phys. Rev. B 71, 014207 (2005).
L. Bove, F. Sacchetti, and C. Petrillo, Philos. Mag. 84, 1609 (2004).
F. J. Bermejo, I. Bustinduy, S. J. Levett, J. W. Taylor, R. Fernandez-Perea, and C. Cabrillo, Phys. Rev. B 72, 104103 (2005).
User Guide. Neutron Experimental Facilities for Condensed Matter Investigation at JINR, Ed. by V. Sikolenko (JINR Press, Dubna, 1997) p. 25.
A. Novikov, Yu. Lisichkin, and N. Fomichev, Zh. Fiz. Khim. 60, 1337 (1986).
E. G. D. Cohen, P. Westerhuijs, and I. M. de Schepper, Phys. Rev. Lett. 59, 2872 (1987).
J. J. Erpenbeck and W. W. Wood, Phys. Rev. A 43, 4254 (1991).
T. Scopigno, R. di Leonardo, L. Gomez, A. Q. R. Baron, D. Fioretto, and G. Ruocco, Phys. Rev. Lett. 94, 155301 (2005).
F. J. Bermejo, I. Bustinduy, S. J. Levett, J. W. Taylor, R. Fernandez-Perea, and C. Cabrillo, Phys. Rev. B 72, 104103 (2005).
F. Demmel, D. Szubrin, W.-C. Pilgrim, and C. Morkel, Phys. Rev. B 84, 014307 (2011).
N. M. Blagoveschenskii, A. G. Novikov, and V. V. Savostin, Physica B 407, 4567 (2012).
S. Chen, P. Gallo, F. Sciortino, and P. Tartaglia, Phys. Rev. E 56, 4231 (1997).
V. Grupi, D. Majolino, P. Migliardo, and V. Venuti, J. Chem. Phys. B 106, 10884 (2002).
F. Demmel and C. Morkel, Phys. Rev. E 85, 051204 (2012).
P. Protopapas, H. C. Andersen, and N. A. D. Parlee, J. Chem. Phys. 59, 15 (1973).
J. Petit and N. Nachtrieb, J. Chem. Phys. 24, 1027 (1956).
Handbook of Chemistry and Physics, 79th ed. (CRC Press, Boca Raton, 1999).
T. Iida, N. Tripathi, M. Isac, and R. Guthrie, Mater. Sci. Forum 539–543, 2509 (2007).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.M. Blagoveshchenskii, A.G. Novikov, A.V. Puchkov, V.V. Savostin, 2014, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2014, Vol. 100, No. 5, pp. 379–384.
Rights and permissions
About this article
Cite this article
Blagoveshchenskii, N.M., Novikov, A.G., Puchkov, A.V. et al. Microscopic properties of liquid gallium from quasi-elastic neutron scattering experiments. Jetp Lett. 100, 340–345 (2014). https://doi.org/10.1134/S0021364014170020
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0021364014170020