Abstract
We have studied the IR transmission of the EuLnCuS3 (Ln = La, Pr, Sm, Gd) compounds in the spectral range 400 to 4000 cm–1 and their thermal expansion in the temperature range 300–1450 K. The compounds have high IR transmission in the range 1800–3000 cm–1. The observed sharp changes in their thermal expansion coefficients are caused by phase transitions.
Similar content being viewed by others
References
Wakeshima, M., Furuuchi, F., and Hinatsu, Y., Crystal structures and magnetic properties of novel rare-earth copper sulfides EuRCuS3 (R = Y, Gd–Lu), J. Phys.: Condens. Matter, 2004, vol. 16, pp. 5503–5518.
Brennan, T.D. and Ibers, J.A., LaPbCuS3: Cu(I) insertion into the a-La2S3 framework, J. Solid State Chem., 1992, vol. 97, pp. 377–382.
Christuk, A.E., Wu Ping, and Ibers, J.A., New quaternary chalcogenides BaLnMQ3 (Ln = rare earth; M = Cu, Ag; Q = S, Se). Structures and grinding-induced phase transition in BaLaCuQ3, J. Solid State Chem., 1994, vol. 110, pp. 330–336.
Solov’eva, A.V., General aspects of phase equilibria in the AIIS–FeS, AIIS–FeS–Ln2S3, and AIIS–Cu2S–Ln2S3 (AII = Mg, Ca, Sr, Ba; Ln = La–Lu) systems, Extended Abstract of Cand. Sci. (Chem.) Dissertation, Tyumen, 2012.
Sikerina, N.V., General aspects of phase equilibria in the SrS–Cu2S–Ln2S3 (Ln = La–Lu) systems and preparation and structure of SrLnCuS3 compounds, Extended Abstract of Cand. Sci. (Chem.) Dissertation, Tyumen, 2005.
Andreev, O.V. and Ruseikina, A.V., Synthesis, melting points, and heats of fusion of EuLnCuS3 (Ln = La–Nd) compounds, Vestn. Tyumensk. Gos. Univ., 2010, no. 3, pp. 221–227.
Ruseikina, A.V., Solov’ev, L.A., Molokeev, M.S., and Andreev, O.V., Crystal structures of EuLnCuS3 (Ln = Nd and Sm), Russ. J. Inorg. Chem., 2012, vol. 57, no. 1, pp. 79–83.
Ruseikina, A.V., Solov’ev, L.A., and Andreev, O.V., Crystal structure of EuLaCuS3, Russ. J. Inorg. Chem., 2012, vol. 57, no. 4, pp. 574–578.
Ruseikina, A.V., Solov’ev, L.A., and Andreev, O.V., Crystal structures of aand ß-EuPrCuS3, Russ. J. Inorg. Chem., 2013, vol. 58, no. 10, pp. 1231–1236.
Ruseikina, A.V., Solov’ev, L.A., Andreev, O.V., and Kislitsyn, A.A., EuNdCuS3: crystal structure of the high-temperature polymorph and properties, Russ. J. Inorg. Chem., 2014, vol. 59, no. 10, pp. 1109–1114.
Pokhodun, A.I. and Sharkov, A.V., Eksperimental’nye metody issledovanii. Izmereniya teplofizicheskikh velichin (Experimental Characterization Techniques: Thermophysical Measurements), St. Petersburg: SPb GUITMO, 2006.
Ruseikina, A.V., Demchuk, Zh.A., and Kislitsyn, A.A., Heats of phase transformations of the EuGdCuS3 compound, Vestn. Tyumensk. Gos. Univ., 2012, no. 5, pp. 19–25.
Visser, J.W., A fully automatic program for finding the unit cell from powder data, J. Appl. Crystallogr., 1969, vol. 2, pp. 89–95.
Solovyov, L.A., Dinnebier, R.E., and Billinge, S.J.L., The derivative difference minimization method, in Powder Diffraction Theory and Practice, 2008, pp. 282–297.
Egorov, N.B. and Shagalov, V.V., Infrakrasnaya spektroskopiya redkikh i rasseyannykh elementov (Infrared Spectroscopy of Rare and Dispersed Elements), Tomsk: TPU, 2008.
Yurchenko, E.N., Kustova, G.N., and Batsanov, S.S., Kolebatel’nye spektry neorganicheskikh soedinenii (Vibrational Spectra of Inorganic Compounds), Novosibirsk: Nauka, 1981.
L’vovskii, E.N., Statisticheskie metody postroeniya empiricheskikh formul (Statistical Methods of Deriving Empirical Formulas), Moscow: Vysshaya Shkola, 1988.
Kislitsyn, A.A. and Fadeev, A.M., Dielectric relaxation in high-viscosity oils, Zh. Fiz. Khim., 1994, vol. 68, no. 2, pp. 340–343.
Vasil’ev, F.P., Chislennye metody resheniya ekstremal’nykh zadach (Numerical Methods of Solving Extremum Problems), Moscow: Nauka, 1980.
Klopotov, A.A., Chekalkin, T.L., and Gyunter, V.E., Effect of preliminary deformation on the fine structure of a TiNi-based alloy in the premartensitic region, Tech. Phys., 2001, vol. 46, no. 6, pp. 770–772.
Dzhurinskii, B.F. and Bandurkin, G.A., Crystal chemistry of rare-earth compounds, in Spektroskopiya kristallov (Spectroscopy of Crystals), Leningrad: Nauka, 1978, pp. 7–11.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Yu.A. Murashko, A.V. Ruseikina, A.A. Kislitsyn, O.V. Andreev, 2015, published in Neorganicheskie Materialy, 2015, Vol. 51, No. 12, pp. 1307–1312.
Rights and permissions
About this article
Cite this article
Murashko, Y.A., Ruseikina, A.V., Kislitsyn, A.A. et al. Optical and thermal properties of the EuLnCuS3 (Ln = La, Pr, Sm, Gd) compounds. Inorg Mater 51, 1213–1218 (2015). https://doi.org/10.1134/S0020168515120079
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168515120079