Skip to main content
Log in

Some general relations of the development of complex molecular objects at early stages of biosphere formation as a consequence of the physical properties of condensed medium

  • Short Communications
  • Published:
Geochemistry International Aims and scope Submit manuscript

Abstract

We analyzed the character of molecular transformations under conditions of condensed media, in which intermolecular interactions always occur. It was shown that, instead of discrete transfer of external energy into the molecule, the energy characteristics of the condensed medium (appearance of zones) could result in gradual accumulation of internal energy in reaction centers owing to sequential thermal collisions with particles of the medium initiating the chemical reaction. This does not require high temperatures. The established physical properties related to the energy characteristics of condensed media could play an important role in molecular transformations and, consequently, formation of complex molecular objects at early stages of biosphere formation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

References

  • V. I. Baranov, L. A. Gribov, and M. E. Elyashberg, “Structural isomerization and the evolution of the molecular world during the early universe evolution,” Geochem. Int. 51 (3), 231–236 (2013).

    Article  Google Scholar 

  • V. I. Baranov, L. A. Gribov, and I. V. Mikhailov, “Processes of the development of the molecular world at early stages of its formation: evidence from the investigation of the behavior of the vibrational entropy of molecules,” Geochem. Int. 54 (11), 929–935 (2016).

    Article  Google Scholar 

  • B. P. Belousov, “Intermittently operating reaction and its mechanism,” in Collection of Abstracts on Radiation Medicine for 1958, Ed. by A. V. Lebedinskii (Medgiz, Moscow, 1959) [in Russian].

    Google Scholar 

  • S. J. Benkovic and S. Hammes–Schiffer, “A perspective on enzyme catalysis,” Science 301 (5637), 1196–1202 (2003).

    Article  Google Scholar 

  • I. V. Berezin, Study in Enzyme Catalysis and Engineering Etymology (Nauka, Moscow, 1990) [in Russian].

    Google Scholar 

  • M. Chaplin, (2016) http://www1.lsbu.ac.uk/water/index.html

  • M. Dixon and E. Webb, Enzymes (Academic Press, New York, 1979).

    Google Scholar 

  • D. Eisenberg and W. Kauzmann, The Structure and Properties of Water (Oxford University Press, Oxford, 1969).

    Google Scholar 

  • A. Fersht, Enzyme Structure and Mechanism (W.H. Freeman & Co., San Francisco, 1985).

    Google Scholar 

  • A. Fersht, Structure and Mechanism in Protein Science: A Guide to Enzyme Catalysis and Protein Folding (W.H. Freeman & Co., San Francisco, 1998).

    Google Scholar 

  • L. A. Gribov, “A simple first-principles model of reduplication,” Biophysics 51 (4), 671–674 (2006a).

    Article  Google Scholar 

  • L. A. Gribov, “Simple model of the state of a real gas and liquid connecting micro- and macrodescriptions,” J. Struct. Chem. 47 (2), 285–288 (2006b).

    Article  Google Scholar 

  • L. A. Gribov, “Some principles in the formation of organic matter during the early stages of chemical evolution,” Geochem. Int. 45 (1), 80–83 (2007).

    Article  Google Scholar 

  • L. A. Gribov, Molecular Vibrations (KomKniga, Moscow, 2009) [in Russian].

    Google Scholar 

  • L. A. Gribov, and V. I. Baranov, “Molecules and life,” in Problems of the Origin and Evolution of the Biosphere, Ed. by E.M. Galimov (Knizhnyi Dom “Librokom”, Moscow, 2008), pp. 33–56.

    Google Scholar 

  • L. A. Gribov, and V. I. Baranov, From Molecules to Life (Krasand, Moscow, 2012) [in Russian].

    Google Scholar 

  • L. A. Gribov, and V. I. Baranov, “Chemical space and biospheric space,” Geochem. Int. 52 (9), 783–787 (2014).

    Article  Google Scholar 

  • L. A. Gribov and V. I. Baranov, Theory and Methods of the Calculation of Molecular Processes: Spectra, Chemical Transformations, and Molecular Logic (KomKniga, Moscow, 2006) [in Russian].

    Google Scholar 

  • L. A. Gribov and V. A. Dement’ev, “Wave motion in molecular nanostructures: results of computer experiments,” J. Struct. Chem. 51 (2). 316–321 (2010).

    Article  Google Scholar 

  • L. A. Gribov and I. V. Mikhailov, “Evolution arrow in the origin of the biosphere,” Geochem. Int. 48 (6), 606–610 (2010).

    Article  Google Scholar 

  • L. A. Gribov, V. I. Baranov, and I. V. Mikhailov, “The arrow of time at the early stages of biosphere evolution. Determinism and pluralism,” Geochem. Int. 50 (5), 393–408 (2012).

    Article  Google Scholar 

  • W. P. Jencks, Catalysis in Chemistry and Enzymology (Dover, Mineola, New York, 1987).

    Google Scholar 

  • M. H. M. Olsson, W. W. Parson, and A. Warshel, “Dynamical contributions to enzyme catalysis: critical tests of a popular hypothesis,” Chem. Rev. 106 (5), 1737–1756 (2006).

    Article  Google Scholar 

  • H. Suzuki, How Enzymes Work: From Structure to Function (CRC, Boca Raton, 2015).

    Book  Google Scholar 

  • G. V. Yukhnevich, Infrared Spectroscopy of Water (Nauka, Moscow, 1973) [in Russian].

    Google Scholar 

  • G. N. Zatsepina, Physical Properties and Structure of Water (Mosk. Gos. Univ., Moscow, 1998) [in Russian].

    Google Scholar 

  • A. M. Zhabotinskii, “Oscillations and waves in homogenous chemical systems,” in Physical Chemistry. Modern Problems. 1987. Yearbook, Ed. by Ya. M. Kolotyrkin (Khimiya, Moscow, 1987), pp. 6–47 [in Russian].

    Google Scholar 

  • A. M. Zhabotinskii, Concentration Autooscillations (Nauka, Moscow, 1974) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. A. Gribov.

Additional information

Original Russian Text © V.I. Baranov, L.A. Gribov, V.A. Dement’ev, I.V. Mikhailov, 2016, published in Geokhimiya, 2016, No. 11, pp. 1046–1054.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Baranov, V.I., Gribov, L.A., Dement’ev, V.A. et al. Some general relations of the development of complex molecular objects at early stages of biosphere formation as a consequence of the physical properties of condensed medium. Geochem. Int. 54, 1011–1018 (2016). https://doi.org/10.1134/S0016702916110033

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0016702916110033

Keywords

Navigation