Skip to main content
SpringerLink
Log in

Thermodynamics of specific interactions of pyridines in aliphatic alcohols: Gibbs energy, entropy, and degree of binding

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The activity coefficients at infinite dilution (T = 298.15 K) and Gibbs energy of solvation of pyridines in aliphatic alcohols were determined. The thermodynamic functions of specific interactions in these systems were calculated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Prins, L.J., Reinhoudt, D.N., and Timmerman, P., Angew. Chem. Int. Ed., 2001, vol. 40, p. 2382.

    Article  CAS  Google Scholar 

  2. Joesten, M.D. and Schaad, L.J., Hydrogen Bonding, New York: Marcel Dekker, 1974.

    Google Scholar 

  3. Lomas, J.S. and Maurel, F., J. Phys. Org. Chem., 2008, vol. 21, no. 6, p. 464.

    Article  CAS  Google Scholar 

  4. Solomonov, B.N., Novikov, V.B., Varfolomeev, M.A., and Mileshko, N.M., J. Phys. Org. Chem., 2005, vol. 18, no. 4, p. 49.

    Article  CAS  Google Scholar 

  5. Rao, C.N.R., Dwivedi, P.C., Ratajczak, H., and Orville-Thomas, W.J.-J., J. Chem. Soc., Faraday Trans. 2, 1975, vol. 71, p. 955.

    Article  CAS  Google Scholar 

  6. Kolev, S.K., Petkov, P.S., Rangelov, M.A., and Vayssilov, G.N., Phys. Chem. (A), 2011, vol. 115, p. 14054.

    Article  CAS  Google Scholar 

  7. Kone, M., Illien, B., Laurence, C., and Graton, J., J. Phys. Chem. (A), 2011, vol. 115, p. 13975.

    Article  CAS  Google Scholar 

  8. Hydrogen Bonding — New Insights, Grabowski, S.J., Ed., New York: Springer, 2006.

    Google Scholar 

  9. Laurence, C. and Berthelot, M., Perspect. Drug Discovery Des., 2000, vol. 18, p. 39.

    Article  CAS  Google Scholar 

  10. Abraham, M.H., Grellier, P.L., Prior, D.V., Morris, J.J., and Taylor, P.J., J. Chem. Soc., Perkin Trans. 2, 1990, vol. 4, p. 521.

    Article  Google Scholar 

  11. Abraham, M.H., Grellier, P.L., Prior, D.V., Duce, P.P., Morris, J.J., and Taylor, P.J., J. Chem. Soc., Perkin Trans. 2, 1989, vol. 6, p. 699.

    Article  Google Scholar 

  12. Iogansen, A.V., Spectrochim. Acta (A), 1999, vol. 55, nos. 7–8, p. 1585.

    Google Scholar 

  13. Badger, R.M. and Bauer, S.H., J. Chem. Phys., 1937, vol. 59, no. 2, p. 839.

    Article  Google Scholar 

  14. Drago, R.S., O’Bryan, N., and Vogel, G.C., J. Am. Chem. Soc., 1970, vol. 92, p. 3924.

    Article  CAS  Google Scholar 

  15. Raevsky, O.A., Grigor’ev, V.Y., Kireev, D.B., and Zefirov, N.S., Quant. Struct. Act. Relat., 1992, vol. 11, no. 1, p. 49.

    Article  Google Scholar 

  16. Marco, J., Orza, J.M., Notario, R., and Abboud, J.-L.M., J. Am. Chem. Soc., 1994, vol. 116, no., 19, p. 8841.

    Article  CAS  Google Scholar 

  17. Hunter, C.A., Angew. Chem. Int. Ed., 2004, vol. 43, p. 5310.

    Article  CAS  Google Scholar 

  18. Apelblat, A., J. Mol. Liq., 2006, vol. 128, nos. 1–3, p. 1.

    Article  CAS  Google Scholar 

  19. Marczak, W., Heintz, A., and Bucek, M., J. Chem. Thermodyn., 2004, vol. 36, no. 7, p. 575.

    Article  CAS  Google Scholar 

  20. Solomonov, B.N., Varfolomeev, M.A., and Novikov, V.B., J. Phys. Org. Chem., 2006, vol. 19, no. 4, p. 263.

    Article  CAS  Google Scholar 

  21. Kontogeorgis, G.M., Tsivintzelis, I., von Solms, N., Grenner, A., Biiigh, D., Frost, M., Knage-Rasmussen, A., and Economou, I.G., Fluid Phase Equilib., 2010, vol. 296, no. 2, p. 219.

    Article  CAS  Google Scholar 

  22. Borisover, M.D., Solomonov, B.N., and Konovalov, A.I., Zh. Obshch. Khim., 1991, vol. 61, no. 2, p. 329.

    CAS  Google Scholar 

  23. Symons, M.C.R., Thomas, V.K., Fletcher, N.J., and Pay, N.G., J. Chem. Soc., Faraday Trans. 1, 1981, vol. 77, no. 8, p. 1899.

    Article  CAS  Google Scholar 

  24. Sedov, I.A., Stolov, M.A., and Solomonov, B.N., J. Phys. Org. Chem., 2011, vol. 24, no. 11, p. 1088.

    Article  CAS  Google Scholar 

  25. Ruelle, P. and Kesselring, U.W., J. Pharm. Sci., 1998, vol. 87, no. 8, p. 987.

    Article  CAS  Google Scholar 

  26. Zaitseva, K.V., Varfolomeev, M.A., Novikov, V.B., and Solomonov, B.N., J. Chem. Thermodyn., 2011, vol. 43, no. 7, p. 1083.

    Article  CAS  Google Scholar 

  27. Solomonov, B.N., Zaitseva, K.V., Varfolomeev, M.A., and Sedov, I.A., Russ. J. Phys. Chem. A, 2011, vol. 85, no. 5, p. 811.

    Article  CAS  Google Scholar 

  28. Zaitseva, K.V., Varfolomeev, M.A., and Solomonov, B.N., J. Mol. Struct., 2012, vol. 1018, p. 14.

    Article  CAS  Google Scholar 

  29. Abraham, M.H. and McGowan, J.C., Chromatographia, 1987, vol. 23, no. 4, p. 243.

    Article  CAS  Google Scholar 

  30. Sprunger, L.M., Achi, S.S., Pointer, R., Blake-Taylor, B.H., Acree, W.E., Jr, and Abraham, M.H., Fluid Phase Equilib., 2009, vol. 286, no. 2, p. 170.

    Article  CAS  Google Scholar 

  31. Sedov, I.A. and Solomonov, B.N., Fluid Phase Equilib., 2009, vol. 276, no. 2, p. 108.

    Article  CAS  Google Scholar 

  32. Abraham, M.H., Le, J., Acree, W.E., Jr., Carr, P.W., and Dallas, A.J., Chemosphere, 2001, vol. 44, no. 4, p. 855.

    Article  CAS  Google Scholar 

  33. Abraham, M.H., Nasezadeh, A., and Acree, W.E., Jr., Ind. Eng. Chem. Res., 2008, vol. 47, p. 3990.

    Article  CAS  Google Scholar 

  34. Abraham, M.H., Andonianhaftvan, J., Whiting, G.S., Leo, A., and Taft, R.S., J. Chem. Soc., Perkin Trans. 2, 1994, no. 8, p. 1777.

    Google Scholar 

  35. Solomonov, B.N., Sedov, I.A., and Akhamadiyarov, A.A., J. Phys. Org. Chem., 2009, vol. 22, p. 1142.

    Article  CAS  Google Scholar 

  36. Pribble, R.N., Hagemeister, F.C., and Zwier, T.S., J. Chem. Phys., 1997, vol. 106, no. 6, p. 2145.

    Article  CAS  Google Scholar 

  37. Siegel, G.G., Huyskens, P.L., and Vanderheyden, L., J. Phys. Chem., 1990, vol. 94, no. 2, p. 549.

    CAS  Google Scholar 

  38. Bich, E., Dzida, M., Vasiltsova, T., and Heintz, A., J. Mol. Liq., 2007, vol. 136, nos. 1–2, p. 94.

    Article  CAS  Google Scholar 

  39. Perrin, D.D., Armarego, L.F., and Perrin, D.R., Purification of Laboratory Chemicals, Oxford: Pergamon Press, 1980.

    Google Scholar 

  40. Gorbatchuk, V.V., Tsifarkin, A.G., Antipin, I.S., Solomonov, B.N., Konovalov, A.I., Seidel, J., and Baitalov, F., J. Chem. Soc., Perkin Trans. 2, 2000, vol. 11, p. 2287.

    Article  Google Scholar 

  41. Thomas, E.R., Newman, B.A., and Long, T.C., J. Chem. Eng. Data, 1982, vol. 27, p. 399.

    Article  CAS  Google Scholar 

  42. Abraham, M.H., Whiting, G.S., Fuchs, R., and Chambers, E.J., J. Chem. Soc., Perkin Trans. 2, 1990, p. 291.

    Google Scholar 

  43. EPI Suite, Version 3.20 2007. US Environment Protection Agency. http://www.epa.gov/oppt/exposure/pubs/episuite.htm.

Download references

Author information

Authors and Affiliations

  1. Butlerov Chemical Institute, Kazan (Volga) Federal University, ul. Kremlyevskaya 18, Kazan, Tatarstan, 420008, Russia

    K. V. Zaitseva, M. A. Varfolomeev & B. N. Solomonov

Authors
  1. K. V. Zaitseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. A. Varfolomeev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. N. Solomonov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to K. V. Zaitseva.

Additional information

Original Russian Text © K.V. Zaitseva, M.A. Varfolomeev, B.N. Solomonov, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 3, pp. 383–390.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zaitseva, K.V., Varfolomeev, M.A. & Solomonov, B.N. Thermodynamics of specific interactions of pyridines in aliphatic alcohols: Gibbs energy, entropy, and degree of binding. Russ J Gen Chem 83, 438–444 (2013). https://doi.org/10.1134/S1070363213030067

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363213030067

Keywords

Search

Navigation