Abstract
The thermophysical characteristics of the SrAlF5 crystal have been investigated on samples differing in quality. The results of studying the thermal expansion and birefringence in heating-cooling cycles in the temperature range of 100–800 K have been analyzed. Specific heat anomalies are found whose position on the temperature scale depends on the sample quality and thermal history. An X-ray diffraction analysis of SrAlF5 showed the absence of structural phase transitions in the temperature range under study. It is suggested that the specific heat anomalies are related to the peculiarity of transport properties of this crystal.
Similar content being viewed by others
References
S. C. Abrahams, J. Ravez, A. Simon, and J. P. Chaminade, J. Appl. Phys. 52, 4740 (1981).
K. Shimamura, E. G. Villora, K. Muramatsu, and N. Ichinose, J. Cryst. Growth 275, 128 (2005).
S. Canouet, J. Ravez, and P. Hagenmuller, J. Fluorine Chem. 27, 241 (1985).
F. Kubel, Z. Anorg. Allg. Chem. 642, 1481 (1998).
E. N. Silva, A. P. Ayala, J. Filho Mendes, et al., J. Phys.: Condens. Matter 16, 7511 (2004).
E. N. Silva, A. P. Ayala, R. L. Moreira, and J-Y. Gesland, J. Phys.: Condens. Matter 18, 2511 (2006).
S. V. Mel’nikova, L. I. Isaenko, M. V. Gorev, et al., Fiz. Tverd. Tela 52, 474 (2010) [Phys. Solid State 52, 509 (2010)].
A. Savitzky and M. J. Galay, Anal. Chem. 36, 1627 (1964).
M. V. Gorev, I. N. Flerov, V. S. Bondarev, and Ph. Sciau, Zh. Eksp. Teor. Fiz. 123(3), 599 (2003) [JETP 96 (3), (2003)].
M. Gorev, V. Bondarev, Ph. Sciau, and J-M. Savariault, J. Phys.: Condens. Matter 18, 4407 (2006).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.S. Bondarev, A.D. Vasil’ev, M.V. Gorev, S.V. Mel’nikova, L.I. Isaenko, 2011, published in Kristallografiya, 2011, Vol. 56, No. 1, pp. 33–38.
Rights and permissions
About this article
Cite this article
Bondarev, V.S., Vasil’ev, A.D., Gorev, M.V. et al. New data on the phase transition in SrAlF5 . Crystallogr. Rep. 56, 29–34 (2011). https://doi.org/10.1134/S1063774511010068
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063774511010068