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The hydrogeochemistry of thermal springs on Mutnovskii Volcano, southern Kamchatka

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Abstract

This paper reports results from a hydrogeochemical study of thermal springs on Mutnovskii Volcano. The solutions of boiling pots and the pore water of thermal localities in the Donnoe Field were found to have an anomalous composition over a wide range of chemical elements, including rare earth elements (REE) and platinum-group elements (PGEs). The solutions of different springs exhibit considerable variations in their major and minor element compositions, indicating differences in the generation and upward transport of solutions. Physicochemical modeling showed that the mud pots studied could have been formed when the separate was ascending along an open fissure channel from the secondary zone of mixed boiling fluids. The high concentrations of titanium, vanadium, chromium, nickel, cobalt, REEs, and PGMs suggest a deep-seated source for these. The chemical forms of the elements in the solutions (primarily free aquaions) and the acidic environment favor high mobility of these elements. Deposition and concentration of these elements under near-surface conditions is unlikely.

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References

  1. Bessonova, E.P., Modeling the Dynamics of Heat and Mass Transfer and the physicochemical Processes in the Hydrothermal System of Ebeko Volcano, Kuril Is., Extended Abstract of Cand Sci. (Geol.-Miner.) Dissertation, Novosibirsk: Institute of Geology, Siberian Branch, Russian Academy of Sciences, 2004, p. 21.

    Google Scholar 

  2. Bortnikova, S.B., Bessonova, E.P., Trofimova, L.B., et al., The Hydrology and Geochemistry of Gas-Hydrothermal Springs on Ebeko Volcano, Paramushir I., Vulkanol. Seismol., 2006, no. 1, pp. 39–51.

  3. Bortnikova, S.B., Sharapov, V.N., and Bessonova, E.P., The Hydrologic and Geochemical Composition of Springs in the Donnoe Field of Mutnovskii Volcano, Southern Kamchatka: Their Relationships to Overcritical Magma Fluids, Dokl. RAN, 2007, vol. 413, no. 4, pp. 530–534.

    Google Scholar 

  4. Vakin, E.A., Kirsanov, I.T., and Pronin, A.A., The Active Crater of Mutnovskii Volcano, Byul. Vulkanol. Stantsii, 1966, no. 40, pp. 25–36.

  5. Vinogradov, A.P., The Average Concentrations of Chemical Elements in the Principal Igneous Rock Types of the Earth’s Crust, Geokhimiya, 1962, no. 7, pp. 555–571.

  6. Gavrilenko, G.M. and Gavrilenko, M.G., The Hydrologic and Geochemical Precursors of the March 2000 Eruption of Mutnovskii Volcano, Kamchatka, Vestnik MGU, Ser. Geol., 2004, no. 4, pp. 25–34.

  7. Gavrilenko, G.M., Mel’nikov, D.V., Zelenskii, M.E., and Tavin’o, L., A Long-Term Hydrological and Geochemical Monitoring of Mutnovskii Volcano, Kamchatka and the April 2007 Phreatic Eruption, Vestnik KRAUNTs, Nauki o Zemle, 2007, issue 9, no. 1, pp. 125–130.

  8. Zelenov, K.K., Aluminum and Titanium in the Crater Lake of Kawah Ijen Volcano, Indonesia, Izv. AN SSSR, Ser. Geol., 1965, no. 5, pp. 32–45.

  9. Zelenov, K.K., Volcanogenic Titanium in a Zone of Hypergenesis, Izv. AN SSSR, Ser. Geol., 1965, no. 10, pp. 63–74.

  10. Zelenov, K.K., The Geochemistry of Aluminum and Titanium in Volcanic Areas of Island Arcs, Sovetskaya Geologiya, 1963, no. 3, pp. 61–81.

  11. Zelenskii, M.E., The Transport of Elements and the Conditions for Mineralization in the Discharge Zones of High Temperature Fumaroles on Mutnovskii Volcano, Kamchatka, Extended Abstract of Cand. Sci. (Geol.-Miner.) Dissertation, Novosibirsk: Institute of Geology, Siberian Branch, Russian Academy of Sciences, 2003, p. 20.

    Google Scholar 

  12. Zelenskii, M.E., Ovsyannikov, A.A., Gavrilenko, G.M., and Senyukov, S.L., The March 2000 Eruption of Mutnovskii Volcano, Kamchatka, Vulkanol. Seismol., 2002, no. 6, pp. 25–28.

  13. Ivanov, V.V., The Basic Geological Conditions and Geochemical Processes in the Formation of Thermal Waters in Present-Day Volcanic Areas, Tr. Laboratorii Vulkanologii AN SSSR, 1961, issue 19, pp. 58–68.

  14. Ivanov, V.V., Ekologicheskaya geokhimiya elementov. Kn. 6. Rare Elements (An Ecologic Geochemistry of Elements. Book 6: Rare Elements), Moscow: Ekologiya, 1997.

    Google Scholar 

  15. Karpov, I.K., Chudnenko, K.V., Bychinskii, V.A., et al., Minimizing the Free Energy in Calculations of Heterogeneous Equilibria, Geologiya i Geofizika, 1995, vol. 36, pp. 3–21.

    Google Scholar 

  16. Kiryukhin, A.V., Leonov, V.L., Slovtsov, I.B., et al., Modeling the Exploitation of the Dachnyi Area in the Mutnovskii Geothermal Field in Connection with the Supply of Heat Carrier to the 50 MW Mutnovskii Geothermal Power Station, Vulkanol. Seismol., 2005, no. 5, pp. 19–44.

  17. Krainov, S.R., Geokhimiya redkikh elementov v podzemnykh vodakh (The Geochemistry of Rare Elements in Ground Water), Moscow: Nedra, 1973.

    Google Scholar 

  18. Melekestsev, I.V., Braitseva, O.A., and Ponomareva, V.V., The Dynamics of Activity of Mutnovskii and Gorelyi Volcanoes in the Holocene and Volcanic Hazard for Adjacent Areas: Tephrochronologic Evidence, Vulkanol. Seismol., 1987, no. 3, pp. 3–18.

  19. Nekrasov, B.V., Osnovy obshchei khimii (Principles of General Chemistry), vol. 1, Moscow: Khimiya, 1965.

    Google Scholar 

  20. Nekrasov, B.V., Osnovy obshchei khimii (Principles of General Chemistry), vol. 2, Moscow: Khimiya, 1967.

    Google Scholar 

  21. Organicheskie reaktivy dlya opredeleniya neorganicheskikh ionov (Organic Reagents for Determining Inorganic Ions), Moscow: NIITEKhIM, 1971.

  22. Polyak, B.G., Geotermicheskie osobennosti oblasti sovremennogo vulkanizma (na primere Kamchatki) (Geothermal Features Peculiar to an Area of Present-Day Volcanism: Kamchatka), Moscow: Nauka, 1966.

    Google Scholar 

  23. Popolitov, E.I. and Volynets, O.N., Geokhimicheskie osobennosti chetvertichnogo vulkanizma Kurilo-Kamchatskoi ostrovnoi dugi i nekotorye voprosy petrogenezisa (The Geochemical Features Peculiar to the Quaternary Volcanism of the Kuril-Kamchatka Island Arc and Certain Issues of Petrogenesis), Novosibirsk: Nauka, 1981.

    Google Scholar 

  24. Reznikov, A.A., Mulikovskaya, E.P., and Sokolov, I.Yu., Metody analiza prirodnykh vod (Techniques for the Analysis of Naturally Occurring Water), Moscow: Nedra, 1970.

    Google Scholar 

  25. Selyangin, O.B., New Evidence concerning Mutnovskii Volcano: Structure, Evolution, Prediction, Vulkanol. Seismol., 1993, no. 1, pp. 17–35.

  26. Serafimova, E.K., The Chemical Composition of Fumarole Gas on Mutnovskii Volcano, Byul. Vulkanol. Stantsii, 1966, no. 2, pp. 56–65.

  27. Taran, Yu.A., Vakin, E.A., Pilipenko, V.P., and Rozhkov, A.M., Geochemical Surveys in the Crater of Mutnovskii Volcano, Vulkanol. Seismol., 1991, no. 5, pp. 37–55.

  28. Sharapov, V.N., The Evolutionary Dynamics of Supra-Asthenospheric Fluid Systems, Geologiya i Geofizika, 2005, vol. 46, no. 5, pp. 459–470.

    Google Scholar 

  29. Aiuppa, A., Dongara, G., Capasso, G., and Allard, P, Trace Elements in the Thermal Groundwaters of Vulcano Island (Sicily), J. Volcanol. Geotherm. Res., 2000, vol. 98, pp. 189–207.

    Article  Google Scholar 

  30. Aiuppa, A., Allard, P., d’Alessandro, W., et al., Mobility and Fluxes of Major, Minor and Trace Elements during Basalt Weathering and Groundwater Transport at Mt. Etna Volcano (Sicily), Geochem. Cosmochim. Acta, 2000, vol. 64, no. 11, pp. 1827–1841.

    Article  Google Scholar 

  31. Bau, M., Rare-Earth Element Mobility during Hydrothermal and Metamorphic Fluid-Rock Interaction and the Significance of the Oxidation State of Europium, Chemical Geology, 1991, vol. 93, pp. 219–230.

    Article  Google Scholar 

  32. Giammanco, S., Ottavian, M., Valenza, M., et al., Major and Trace Elements Geochemistry in the Ground Waters of a Volcanic Area: Mount Etna (Sicily, Italy), Water Resource, 1998, vol. 32, no. 1, pp. 19–30.

    Google Scholar 

  33. Hanley, J.J., The Aqueous Geochemistry of the Platinum-Group Elements (PGE) in Surficial, Low-T Hydrothermal and High-T Magmatic-Hydrothermal Environments, in Exploration for Platinum-Group Element Deposits, Mungall, J.E., Ed., Short Course Series, Canada, 2005, vol. 35, pp. 35–56.

  34. Lewis, A.J., Palmer, M.R., and Kemp, A.J., Variations of the Rare Earth Element Abundances in the Hydrothermal Waters from the Yellowstone Hydrothermal System, Wyoming, USA, Mineral. Mag., 1994, vol. 58A, pp. 525–526.

    Article  Google Scholar 

  35. Lewis, A.J., Palmer, M.R., Sturchio, N.C., and Kemp, A.J., The Rare Earth Element Geochemistry of Acid-Sulfate and Acid-Sulfate-Chloride Geothermal System from Yellowstone National Park, Wyoming, USA, Geochem. Cosmochim. Acta, 1997, vol. 61, no. 4, pp. 695–706.

    Article  Google Scholar 

  36. Marcos, N., Low-Temperature Mobility of Rare Earth Elements (REE), K, and Th at the Okliluoto Site, SW Finland, Materials Res. Society, Symposium Proc., 2002, vol. 713, pp. 825–832.

    Google Scholar 

  37. Reid, R., Prausnitz, J., and Sherwood, T., The Properties of Gases and Liquids, 3rd ed., New York: McGraw-Hill, 1977.

    Google Scholar 

  38. Rollinson, H.R., Using Geochemical Data: Evaluation, Presentation, Interpretation, Essex: London Group UK Ltd., 1994.

    Google Scholar 

  39. Shennon, W.M., Wood, S.A., Brown, K., and Arehart, G., REE Contents and Speciation in Geothermal Fluids from New Zealand, in Water-Rock Interaction 2001, Symp. Proc., Cidu, R., Ed., 2001, vol. 2, pp. 1001–1004.

  40. Sverjensky, D.A., Europium Redox Equilibria in Aqueous Solution, Earth Planet. Sci. Lett., 1984, vol. 67, pp. 70–78.

    Article  Google Scholar 

  41. Taran, Y., Fischer, T.P., Pokrovsky, B., et al., Geochemistry of the Volcano-Hydrothermal System of El Chichon Volcano, Chiapas, Mexico, Bull. Volcanol., 2003, vol. 59, pp. 445–459.

    Google Scholar 

  42. Wehrli, B. and Stumm, W., Vanadium in Natural Waters: Adsorption and Hydrolysis Promote Oxygenation, Geochim. Cosmochim. Acta, 1989, vol. 53, pp. 69–77.

    Article  Google Scholar 

  43. Wood, S.A., The Aqueous Geochemistry of the Rare-Earth Elements and Yttrium. Part 1. Review of Available Low-Temperature Data for Inorganic Complexes and the Inorganic Speciation of Natural Waters, Chemical Geology, 1990, vol. 82, pp. 159–186.

    Article  Google Scholar 

  44. Wood, S.A., The Aqueous Geochemistry of the Platinum-Group Elements with Applications to Ore Deposit, in The Geology, Geochemistry, Mineralogy and Mineral Beneficiation of Platinum-Group Elements, Cabri, L.J., Ed., CIM Special Volume 54, Montreal, 2002, pp. 211–249.

  45. Woods, T.L., and Garrels, R.M., Thermodynamic Values at Low Temperature for Natural Inorganic Materials: An Uncritical Summary, Oxford Univ. Press, 1987.

  46. Yokokawa, H., Tables of Thermodynamic Properties of Inorganic Compounds, J. National Chemical Laboratory for Industry, Tsukuba Ibaraki 305, Japan, 1988, vol. 83, pp. 27–118.

    Google Scholar 

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Original Russian Text © S.B. Bortnikova, G.M. Gavrilenko, E.P. Bessonova, A.S. Lapukhov, 2009, published in Vulkanologiya i Seismologiya, 2009, No. 6, pp. 26–43.

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Bortnikova, S.B., Gavrilenko, G.M., Bessonova, E.P. et al. The hydrogeochemistry of thermal springs on Mutnovskii Volcano, southern Kamchatka. J. Volcanolog. Seismol. 3, 388–404 (2009). https://doi.org/10.1134/S0742046309060025

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